scholarly journals Interaction between Aqueous Solutions of Hydrophobically Associating Polyacrylamide and Dodecyl Dimethyl Betaine

2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
Zhongbin Ye ◽  
Guangfan Guo ◽  
Hong Chen ◽  
Zheng Shu
Keyword(s):  
Aqueous Solution ◽  
Surface Tension ◽  
Interfacial Tension ◽  
Apparent Viscosity ◽  
Mixed System ◽  
Radius Of Gyration ◽  
Network Structures ◽  
Hydrophobically Associating Polyacrylamide ◽  
Oil Water ◽  
Hydrophobically Associating

The interaction between hydrophobically associating polyacrylamide (HAPAM) and dodecyl dimethyl betaine (BS-12) is studied through surface tension, interfacial tension (IFT), apparent viscosity, aggregation behavior, and microscopic morphologies. Results show that surface and interface properties of BS-12 are largely affected by HAPAM. BS-12 critical micelle concentrations are increased with the increment of polymer concentrations. Abilities of reduced air-water surface tension and oil-water interfacial tension are dropped. The oil-water interfacial tension to reach minimum time is increased. HAPAM can form network structures in the aqueous solution. Mixed micelles are formed by the interaction between BS-12 micelles and hydrophobic groups of HAPAM in aqueous solution and self-assembly behavior of HAPAM is affected. With the increment of surfactant concentrations, the apparent viscosity, apparent weight average molecular weights (Mw, a), root mean square radius of gyration (〈Rg〉), and hydrodynamic radius of HAPAM increase first and then decline. Moreover, microscopic morphologies of the mixed system are formed from relatively loose network structures to dense network structures and then become looser network structures and the part of network structures fracture.

Self-assembly properties of a temperature- and salt-tolerant amphoteric hydrophobically associating polyacrylamide

RSC Advances ◽  
2016 ◽  
Vol 6 (54) ◽  
pp. 49281-49288 ◽  
Author(s):  
Hongping Quan ◽  
Zhuoke Li ◽  
Zhiyu Huang
Keyword(s):  
Polymer Solution ◽  
Apparent Viscosity ◽  
Self Assembly ◽  
Salt Tolerant ◽  
Hydrophobically Associating Polyacrylamide ◽  
Hydrophobically Associating

We prepared amphoteric hydrophobically associating polyacrylamides (AHAPAM) whose apparent viscosity of 0.5 wt% polymer solution can maintain 92 mPa s at 140 °C and 170 s−1 shearing for 1 h.

Synthesis and Properties of Novel Cashew-Based Sulfonate Gemini Surfactant

2014 ◽  
Vol 915-916 ◽  
pp. 927-932
Author(s):  
Wei Guang Shi ◽  
Peng Xiang Wang ◽  
Xiao Gang Ma ◽  
Cui Qin Li ◽  
Jun Wang
Keyword(s):  
Surface Tension ◽  
Critical Micelle Concentration ◽  
Interfacial Tension ◽  
Sodium Hydroxide ◽  
Gemini Surfactant ◽  
Chlorosulfonic Acid ◽  
Inorganic Salts ◽  
Foam Properties ◽  
Sulfonate Gemini Surfactant ◽  
Oil Water

A novel cashew-based gemini surfactant was synthesized from cashew phenol, 1, 3-dibromopropane and chlorosulfonic acid through etherification, sulfonation and neutralization. The critical micelle concentration (cmc) for cashew-based gemini surfactant was 6.2×10-2 mmol·L-1, the surface tension (γcmc) was 36.92 mN.m-1. Foam properties and emulsification properties were investigated including the affection of inorganic salts and sodium hydroxide. The oil / water interfacial tension can be decreased efficiently to 10-3mN / m.

Ozonation of pine kraft lignin in alkaline solution. Part 2: Surface active properties of the ozonated kraft lignins

Holzforschung ◽  
2004 ◽  
Vol 58 (6) ◽  
pp. 631-639 ◽  
Author(s):  
Rui Wang ◽  
Chen-Loung Chen ◽  
Josef S. Gratzl
Keyword(s):  
Aqueous Solution ◽  
Surface Tension ◽  
Sodium Chloride ◽  
Synergistic Effect ◽  
Interfacial Tension ◽  
Kraft Lignin ◽  
Average Molecular Mass ◽  
Adsorption Equation ◽  
Gibbs Adsorption Equation ◽  
Dilute Aqueous Solution

Abstract The surface tension and interfacial tension of the F-1000, F-1800, F-5000 and F-15000 fractions obtained by ultrafiltration of the Oz-25-KL, Oz-30-KL and Oz-40-KL preparations (ozonated kraft lignin, KL, preparations with ozone consumption of 25, 30 and 40% per KL) were determined with the concentration range of 1–30 g l-1 at pH of 6, 9 and 11. The surface tension of these ozonated KL preparations decreased with increasing concentration and pH according to the simplified Gibbs adsorption equation for dilute aqueous solution, ∂γ= -RTΓ∂(ln C). The results were discussed in term of functional group contents and weight average molecular mass (Mw) of the ozonated KL preparations. The surface tension of the ozonated KL preparations decreased with increasing carboxylic acid content and, to some extent, phenolic hydroxyl content, but increased with increasing Mw. The synergistic effect of the ozonated KL preparations with a commercial surfactant was then investigated. The oil-water interfacial tension was determined in the ozonated KL preparations in an aqueous solution containing 1.5% Petrostep B-120R and 1.5% sodium chloride with hexane as oil phase by spinning drop technique. The interfacial tension of the system also decreased with increasing the concentration of ozonated KL preparations in the range of 1–16 g l-1 according to the simplified Gibbs adsorption equation. Thus, the addition of a small amount of ozonated KL preparations to the aqueous solution containing 1.5% Petrostep B-120R and 1.5% sodium chloride showed a remarkable synergistic effect on reducing the interfacial tension.

Influence of ZrO2 Nanoparticles Including SDS and CTAB Surfactants Assembly on the Interfacial Properties of Liquid-Liquid, Liquid-Air and Liquid-Solid Surface Layers

2012 ◽  
Vol 21 ◽  
pp. 15-21 ◽  
Author(s):  
Pouriya Esmaeilzadeh ◽  
Zahra Fakhroueian ◽  
Alireza Bahramian ◽  
Sharareh Arya
Keyword(s):  
Surface Tension ◽  
Interfacial Tension ◽  
Carbonate Rock ◽  
Sodium Dodecyl ◽  
Ammonium Bromide ◽  
Minor Effect ◽  
Water Interface ◽  
Surface Layers ◽  
Oil Water ◽  
A Minor

This work investigates the effects of nanometric (5-8 nm) ZrO2 nanoparticles on adsorption of two surfactants, SDS (sodium dodecyl sulfate) and C12TAB (dodecyl trimethyl ammonium bromide) into oil/water, air/water and solid/water interfaces. Increasing the concentration of nanoparticles reduces the interfacial tension and surface tension of SDS at low surfactant concentration (< cmc) but it has a minor effect on interfacial and surface tension of C12TAB. Repulsive columbic interactions between SDS molecules and nanoparticles can cause the higher adsorption of surfactant at the oil/water interface. Adsorption of both surfactants on carbonate rock increases by adding nanoparticles to the system. This possibly happened because of the formation of surfactant-nanoparticle negatively charged aggregates that tend to adsorb on positively charged surface layer of carbonate rock. ZrO2 nanoparticles are surface active at the oil/water interface too, as the results of interfacial tension indicate they can decrease the n-heptane/water IFT about 14 units.

Perbandingan Karakteristik Surfaktan Metil Ester Sulfonat dan Sodium Lauril Sulfonat sebagai Bahan Emulsifier

2016 ◽  
Vol 9 (2) ◽  
pp. 167-176
Author(s):  
Eldha Sampepana ◽  
Paluphy Eka Yustini ◽  
Aditya Rinaldi ◽  
Amiroh Amiroh
Keyword(s):  
Fatty Acids ◽  
Surface Tension ◽  
Methyl Ester ◽  
Interfacial Tension ◽  
Palm Oil ◽  
Emulsion Stability ◽  
Raw Material ◽  
Enzymatic Method

Surfactant which is used as raw emulsifier in an industry activity such as Sodium Lauryl Sulfonate is a raw material import, it is petroleum derivative which is not renewable and may cause pollution to the environment, because it is not degraded and are carcinogenic. The purpose of the research is to compare the characteristics of the Quaternary methyl ester sulfonat (MES) and Sodium Lauryl Sulfonat (SLS) as emulsifier. First, make the MES by filtering and eliminating fatty acids of palm oil, then process the MES with enzymatic method become methyl ester, then react it in sulfonation and metanolization process, and also neutralized with NaOH. Next, the MES experiment is compared with SLS and existing MES in the market. The results show that surfactants MES experiment has value hidrofil lipofil balance (HLB) interfacial tension and emulsion stability greater than MES in the market and SLS. And the surface tension of MES experiment is larger than MES in the market, but smaller compared to SLS.ABSTRAKSurfaktan yang digunakan sebagai bahan baku emulsifer dalam aktivitas suatu industri pada saat ini seperti Sodium Lauril Sulfonat  merupakan bahan baku import yang merupakan turunan dari minyak bumi, dengan sifat tidak dapat diperbaharui dan dapat menimbulkan pencemaran terhadap lingkungan karena tidak mudah terdegradasi serta bersifat karsinogenik. Metil ester sulfonat dari bahan minyak sawit merupakan surfaktan dengan sifat mudah terdegradasi yang perlu diketahui karakteristiknya. Penelitian bertujuan untuk membandingkan karakteristik surfaktan metil ester sulfonat (MES) dan Sodium Lauril Sulfonat (SLS) sebagai bahan emulsifier. Mula-mula dilakukan pembuatan MES dengan cara menyaring dan menghilangkan asam lemak minyak sawit terlebih dahulu, kemudian diolah menjadi metil ester secara enzimatis, lalu direaksikan secara sulfonasi dan metanolisis, serta dinetralkan dengan NaOH. Selanjutnya MES hasil percobaan dibandingkan dengan SLS dan MES yang ada dipasaran. Hasil penelitian menunjukkan bahwa surfaktan MES memiliki nilai hidrofil lipofil balance (HLB) tegangan antar muka dan stabilitas emulsi lebih besar apabila dibandingkan dengan MES di pasaran dan SLS, kecuali nilai stabilitas emulsi antara MES dan SLS sama. Dan tegangan permukaan MES hasil percobaan, lebih besar dibandingkan dengan MES dipasaran, dan lebih kecil dibandingkan dengan SLS. Kata kunci :   Metil  ester sulfonat, hidrofil lipofil balance, emulsifier, sodium lauril sulfonat , stabilitas emulsi 

scholarly journals Mechanism of active silica nanofluids based on interface-regulated effect during spontaneous imbibition

2021 ◽  
Author(s):  
Xu-Guang Song ◽  
Ming-Wei Zhao ◽  
Cai-Li Dai ◽  
Xin-Ke Wang ◽  
Wen-Jiao Lv
Keyword(s):  
Contact Angle ◽  
Interfacial Tension ◽  
Oil Recovery ◽  
Dynamic Contact Angle ◽  
Liquid Interface ◽  
Spontaneous Imbibition ◽  
Wettability Alteration ◽  
Low Permeability ◽  
Oil Water ◽  
Solid Liquid

AbstractThe ultra-low permeability reservoir is regarded as an important energy source for oil and gas resource development and is attracting more and more attention. In this work, the active silica nanofluids were prepared by modified active silica nanoparticles and surfactant BSSB-12. The dispersion stability tests showed that the hydraulic radius of nanofluids was 58.59 nm and the zeta potential was − 48.39 mV. The active nanofluids can simultaneously regulate liquid–liquid interface and solid–liquid interface. The nanofluids can reduce the oil/water interfacial tension (IFT) from 23.5 to 6.7 mN/m, and the oil/water/solid contact angle was altered from 42° to 145°. The spontaneous imbibition tests showed that the oil recovery of 0.1 wt% active nanofluids was 20.5% and 8.5% higher than that of 3 wt% NaCl solution and 0.1 wt% BSSB-12 solution. Finally, the effects of nanofluids on dynamic contact angle, dynamic interfacial tension and moduli were studied from the adsorption behavior of nanofluids at solid–liquid and liquid–liquid interface. The oil detaching and transporting are completed by synergistic effect of wettability alteration and interfacial tension reduction. The findings of this study can help in better understanding of active nanofluids for EOR in ultra-low permeability reservoirs.

scholarly journals Synthesis of aminated polystyrene and its self-assembly with nanoparticles at oil/water interface

e-Polymers ◽  
2020 ◽  
Vol 20 (1) ◽  
pp. 317-327
Author(s):  
Chenliang Shi ◽  
Ling Lin ◽  
Yukun Yang ◽  
Wenjia Luo ◽  
Maoqing Deng ◽  
...  
Keyword(s):  
Interfacial Tension ◽  
Self Assembly ◽  
Carbon Dots ◽  
Chain Transfer ◽  
Functionalized Polymers ◽  
Amino Groups ◽  
One Dimensional ◽  
Reversible Addition ◽  
Oil Water ◽  
Chain Transfer Polymerization

AbstractThe influence of density of amino groups, nanoparticles dimension and pH on the interaction between end-functionalized polymers and nanoparticles was extensively investigated in this study. PS–NH2 and H2N–PS–NH2 were prepared using reversible addition–fragmentation chain transfer polymerization and atom transfer radical polymerization. Zero-dimensional carbon dots with sulfonate groups, one-dimensional cellulose nanocrystals with sulfate groups and two-dimensional graphene with sulfonate groups in the aqueous phase were added into the toluene phase containing the aminated PS. The results indicate that aminated PS exhibited the strongest interfacial activity after compounding with sulfonated nanoparticles at a pH of 3. PS ended with two amino groups performed better in reducing the water/toluene interfacial tension than PS ended with only one amino group. The dimension of sulfonated nanoparticles also contributed significantly to the reduction in the water/toluene interfacial tension. The minimal interfacial tension was 4.49 mN/m after compounding PS–NH2 with sulfonated zero-dimensional carbon dots.

Performance of alkali-free natural petroleum sulfonates: Ultra-low interfacial tension on oil/water interface

2015 ◽  
Vol 93 (8) ◽  
pp. 1410-1415 ◽  
Author(s):  
Zhan Weng ◽  
Peng-Yuan Zhang ◽  
Guang-Wen Chu ◽  
Wei Wang ◽  
Jimmy Yun ◽  
...  
Keyword(s):  
Interfacial Tension ◽  
Water Interface ◽  
Low Interfacial Tension ◽  
Oil Water
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