scholarly journals Experimental Study of Gas Explosions in Hydrogen Sulfide-Natural Gas-Air Mixtures

2014 ◽  
Vol 2014 ◽  
pp. 1-12 ◽  
Author(s):  
André Vagner Gaathaug ◽  
Dag Bjerketvedt ◽  
Knut Vaagsaether ◽  
Sandra Hennie Nilsen

An experimental study of turbulent combustion of hydrogen sulfide (H2S) and natural gas was performed to provide reference data for verification of CFD codes and direct comparison. Hydrogen sulfide is present in most crude oil sources, and the explosion behaviour of pure H2S and mixtures with natural gas is important to address. The explosion behaviour was studied in a four-meter-long square pipe. The first two meters of the pipe had obstacles while the rest was smooth. Pressure transducers were used to measure the combustion in the pipe. The pure H2S gave slightly lower explosion pressure than pure natural gas for lean-to-stoichiometric mixtures. The rich H2S gave higher pressure than natural gas. Mixtures of H2S and natural gas were also studied and pressure spikes were observed when 5% and 10% H2S were added to natural gas and also when 5% and 10% natural gas were added to H2S. The addition of 5% H2S to natural gas resulted in higher pressure than pure H2S and pure natural gas. The 5% mixture gave much faster combustion than pure natural gas under fuel rich conditions.

CORROSION ◽  
1960 ◽  
Vol 16 (10) ◽  
pp. 503t-506t ◽  
Author(s):  
KENNETH L. MOORE

Abstract Various corrosion problems are described which have occurred in a large diethanolamine (DEA) system that removes hydrogen sulfide from refinery gas streams and a liquid propane-butane stream. These include reboiler corrosion, rich DEA corrosion, stress corrosion cracking, and corrosion-erosion. The effect of the problems on system operation is discussed, as well as the means of minimizing the problems. Electrical resistance measuring device data indicate the importance of keeping the solution loading below 0.34 mol of acid gas (H2S + CO2) per mol of DEA to minimize the corrosion in the rich DEA. Data from this source also show the relationship between general reboiler corrosion and solution contamination. 8.4.3


2012 ◽  
Vol 16 (4) ◽  
pp. 1055-1065 ◽  
Author(s):  
Babak Kashir ◽  
Sadegh Tabejamaat ◽  
Mohammadi Baig

Author(s):  
Arnab Roy ◽  
Donald Ferguson ◽  
Todd Sidwell ◽  
Peter Strakey

Operational characteristics of an air breathing Rotating Detonation Combustor (RDC) fueled by natural gas-hydrogen blends are discussed in this paper. Experiments were performed on a 152 mm diameter uncooled RDC with a combustor to inlet area ratio of 0.2 at elevated inlet temperature and combustor pressure while varying the fuel split between natural gas and hydrogen over a range of equivalence ratios. Experimental data from short-duration (∼6sec) tests are presented with an emphasis on identifying detonability limits and exploring detonation stability with the addition of natural gas. Although the nominal combustor used in this experiment was not specifically designed for natural gas-air mixtures, significant advances in understanding conditions necessary for sustaining a stable, continuous detonation wave in a natural gas-hydrogen blended fuel were achieved. Data from the experimental study suggests that at elevated combustor pressures (2–3bar), only a small amount of natural gas added to the hydrogen is needed to alter the detonation wave operational mode. Additional observations indicate that an increase in air inlet temperature (up to 204°C) at atmospheric conditions significantly affects RDC performance by increasing deflagration losses through an increase in the number of combustion (detonation/Deflagration) regions present in the combustor. At higher backpressure levels the RDC exhibited the ability to achieve stable detonation with increasing concentrations of natural gas (with natural gas / hydrogen-air blend). However, losses tend to increase at intermediate air preheat levels (∼120°C). It was observed that combustor pressure had a first order influence on RDC stability in the presence of natural gas. Combining the results from this limited experimental study with our theoretical understanding of detonation wave fundamentals provides a pathway for developing an advanced combustor capable of replacing conventional constant pressure combustors typical of most power generation processes with one that produces a pressure gain.


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