scholarly journals Fate and Distribution of Heavy Metals in Wastewater Irrigated Calcareous Soils

2014 ◽  
Vol 2014 ◽  
pp. 1-11 ◽  
Author(s):  
Mohammed Hashem Stietiya ◽  
Mohammad Duqqah ◽  
Theophilus Udeigwe ◽  
Ruba Zubi ◽  
Tarek Ammari
Keyword(s):  
Heavy Metals ◽  
Environmental Fate ◽  
Calcareous Soils ◽  
Treated Wastewater ◽  
Mn Oxide ◽  
Heavy Metal Remediation ◽  
Zarqa River ◽  
Metal Addition ◽  
The Impact

Accumulation of heavy metals in Jordanian soils irrigated with treated wastewater threatens agricultural sustainability. This study was carried out to investigate the environmental fate of Zn, Ni, and Cd in calcareous soils irrigated with treated wastewater and to elucidate the impact of hydrous ferric oxide (HFO) amendment on metal redistribution among soil fractions. Results showed that sorption capacity for Zarqa River (ZR1) soil was higher than Wadi Dhuleil (WD1) soil for all metals. The order of sorption affinity for WD1 was in the decreasing order of Ni > Zn > Cd, consistent with electrostatic attraction and indication of weak association with soil constituents. Following metal addition, Zn and Ni were distributed among the carbonate and Fe/Mn oxide fractions, while Cd was distributed among the exchangeable and carbonate fractions in both soils. Amending soils with 3% HFO did not increase the concentration of metals associated with the Fe/Mn oxide fraction or impact metal redistribution. The study suggests that carbonates control the mobility and bioavailability of Zn, Ni, and Cd in these calcareous soils, even in presence of a strong adsorbent such as HFO. Thus, it can be inferred that in situ heavy metal remediation of these highly calcareous soils using iron oxide compounds could be ineffective.

scholarly journals Immobilization Potential of Cow Manure for Heavy Metal Remediation from Refuse Dump Soil

2021 ◽  
pp. 44-55
Author(s):  
Ezeudu Emeka Christian ◽  
Oli Christian Chukwuemeka ◽  
. Enenche ◽  
Elaigwu Daniel ◽  
Anekwe Ozioma Juliana ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Ricinus Communis ◽  
Cow Manure ◽  
Industrial Chemistry ◽  
Refuse Dump ◽  
Anambra State ◽  
Mn Oxide ◽  
Greenhouse Study ◽  
Mobility Factor ◽  
Heavy Metal Remediation

Aims: The present study investigated the effect of cow manure amendment on fractionation and availability of some heavy metals (Cd, Cu, Cr, Mn, Pb and Zn) in refuse dump soil. Study Design: A greenhouse study experiment was conducted to determine the uptake of the metals by Ricinus communis in dump soil treated with 0%, 5%, 10% and 20% cow manure. Place and Duration of Study: The study was carried out at the Department of Pure and Industrial Chemistry, Nnamdi Azikiwe University Awka, Anambra State, Nigeria, between May and October 2018. Methodology: Experimental pots were filled with 2.0kg refuse dump soil in a green house and treated with 5%, 10% and 20% of Cow manure in three replicates per treatment. The seeds of Ricinus communis were planted in each pot and analysed after 12 weeks of planting for heavy metals using AAS. Sequential extraction was carried out on the treated soil after the harvest with each extract further analysed for heavy metals using AAS. Results: Application of cow manure significantly (p ˂ 0.05) affected the redistribution and the mobility of the heavy metals in the dump soil; as the concentration of the amendment increased, heavy metals in the mobile fractions reduced. 20% amendment had the best immobilization effect as the mobility factor decreased with increasing manure amendment. The mobility factors at 20% amendment were 18.34%, 15.82%, 5.23%, 15.86%, 25.56% and 12.81% for Cd, Cr, Cu, Mn, Pb and Zn respectively with the general trend of metal forms given as: residual > bound to organic > bound to Fe-Mn oxide > bound to carbonate > exchangeable. Conclusion: Cow manure amendment of the dump soil decreased the availability of heavy metals for plant uptake; and the metal uptake generally decreased as percentage amendment increased. Cow manure is therefore a good immobilizing agent for remediation of Cd, Cr, Cu, Mn, Pb and Zn in polluted soils.

scholarly journals Advances in Heavy Metal Bioremediation: An Overview

2021 ◽  
Vol 2021 ◽  
pp. 1-8
Author(s):  
Ali Sayqal ◽  
Omar B. Ahmed
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Heavy Metal Contamination ◽  
Ex Situ ◽  
Toxic Heavy Metals ◽  
Heavy Metal Remediation ◽  
Land Farming ◽  
Biological Methods ◽  
Metal Bioremediation

The pollution of toxic heavy metals is considered one of the most important environmental issues which has accelerated dramatically due to changing industrial activities. This review focuses on the most common methods, strategies, and biological approaches of heavy metal bioremediation. Also, it provides a general overview of the role of microorganisms in the bioremediation of heavy metals in polluted environments. Advanced methods of heavy metal remediation include physicochemical and biological methods; the latter can be further classified into in situ and ex situ bioremediation. The in situ process includes bioventing, biosparging, biostimulation, bioaugmentation, and phytoremediation. Ex situ bioremediation includes land farming, composting, biopiles, and bioreactors. Bioremediation uses naturally occurring microorganisms such as Pseudomonas, Sphingomonas, Rhodococcus, Alcaligenes, and Mycobacterium. Generally, bioremediation is of very less effort, less labor intensive, cheap, ecofriendly, sustainable, and relatively easy to implement. Most of the disadvantages of bioremediation relate to the slowness and time-consumption; furthermore, the products of biodegradation sometimes become more toxic than the original compound. The performance evaluation of bioremediation might be difficult as it has no acceptable endpoint. There is a need for further studies to develop bioremediation technologies in order to find more biological solutions for bioremediation of heavy metal contamination from different environmental systems.

scholarly journals Removal of mercury (II) from aqueous solutions by multiwalled carbon nanotubes coated with manganese oxide

2019 ◽  
Vol 21 (6) ◽  
pp. 258-264
Author(s):  
Abbas Khodabakhshi ◽  
Hassan Asgarian
Keyword(s):  
Heavy Metals ◽  
Carbon Nanotubes ◽  
Aqueous Solutions ◽  
Contact Time ◽  
Structural Characteristics ◽  
Initial Density ◽  
High Concentration ◽  
Nano Composite ◽  
Mn Oxide ◽  
The Impact

Background and aims: Water pollution by heavy metals is one of the most important environmental problems. Among the heavy metals, mercury (Hg) is a very toxic metal and its high concentration can lead to impaired pulmonary and renal dysfunction. The aim of this study was to determine the amount of Hg removal by carbon nanotubes coated with manganese (Mn) oxide from aqueous solutions. Methods: In this study, multi-walled carbon nanotubes coated with Mn oxide were prepared and used to remove Hg from aqueous environments. In addition, the physical and structural characteristics of the nanotubes were determined by the X-ray diffraction (XRD). The impact of diverse variables was further investigated, including the initial concentration of Hg, the initial pH of the solution, contact time, mixing rate, as well as the amount of nano-composite and the impacts of confounders (nitrate and chloride). Finally, optimum conditions for each of these parameters were obtained by the Taguchi statistical method. Results: The XRD analysis showed that the nanotubes were properly coated with Mn oxide. Furthermore, the results demonstrated that under pH 7, the rate of mixing of 150 rpm, the contact time of 60 minutes, the amount of nano-composite of 60 mg, and the initial density of Hg 80 mg/L can be achieved by removing 95% Hg. Moreover, the confounder factors of nitrate and chloride reduced the amount of Hg removal by 4 and 5%, respectively. Conclusion: Based on the results, the nanotubes coated with Mn oxide can be used as easy and strong absorbents for the rapid absorption of Hg from drinking water and industrial wastewater.

scholarly journals Using a Multimedia Aquivalence Model to Evaluate the Environmental Fate of Fe, Mn and Trace Metals in an Industrial City, China

Water ◽  
2020 ◽  
Vol 12 (6) ◽  
pp. 1580
Author(s):  
Xuan Chang ◽  
Yingxia Li
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Environmental Fate ◽  
Sediment Resuspension ◽  
Road Dust ◽  
Rapid Expansion ◽  
Surface Areas ◽  
Fe And Mn ◽  
The Impact ◽  
Environmental Compartments

The rapid expansion of urban impervious surface areas complicates urban-scale heavy metal circulation among various environmental compartments (air, soil, sediment, water, and road dust). Herein, a level III steady-state aquivalence model evaluated the fate of heavy metals in Nanjing, China. Iron was the most abundant heavy metal in all environmental compartments, while cadmium was the rarest. Most simulated concentrations agreed with measured values within three logarithmic residuals. In the simulated heavy metal cycle, industrial emission contributed almost the entire input, whereas sediment burial was the dominant output pathway. The transfer fluxes between bottom sediment and water were the highest. Thereinto, the contribution of sediment resuspension for Fe and Mn was significantly higher than that to the other metal elements, which could partly explain why Fe and Mn are the major blackening ingredients in malodorous black rivers. Road dust was also an important migration destination for heavy metals, accounting for 3–45%, although soil and sediment were the main repositories of heavy metals in the urban environment. The impact of road dust on surface water should not be neglected, with its contribution reaching 4–31%. The wash-off rate constant W for road dust–water process was proved to be consistent with that for film–water and was independent of the type of heavy metals. Sensitivity analysis highlighted the notable background value effect on Fe and Mn.

scholarly journals Analysis of Treated Wastewater Produced from Al-Lajoun Wastewater Treatment Plant, Jordan

2009 ◽  
Vol 6 (s1) ◽  
pp. S287-S303
Author(s):  
Waleed Manasreh ◽  
Atef S. Alzaydien ◽  
Malahmeh .M
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Wastewater Treatment ◽  
Organic Carbon ◽  
Total Organic Carbon ◽  
Wastewater Treatment Plant ◽  
Treatment Plant ◽  
Oxygen Demand ◽  
Treated Wastewater ◽  
The Impact

Assessment of treated wastewater produced from Al-Lajoun collection tanks of the wastewater treatment plant in Karak province was carried out in term of physical properties, its major ionic composition, heavy metals and general organic content, for both wastewater influent and effluent. Sampling was done in two periods during (2005-2006) summer season and during winter season to detect the impact of climate on treated wastewater quality. Soil samples were collected from Al-Lajoun valley where the treated wastewater drained, to determine the heavy metal and total organic carbon concentrations at same time. The study showed that the treated wastewater was low in its heavy metals contents during both winter and summer seasons, which was attributed to high pH value enhancing their precipitations. Some of the major ions such as Cl-, Na+, HCO33-, Mg2+in addition to biological oxygen demand and chemical oxygen demand were higher than the recommended Jordanian guidelines for drained water in valleys. The treated wastewater contained some organic compounds of toxic type such as polycyclic aromatic hydrocarbons. Results showed that the soil was low in its heavy metal contents and total organic carbon with distance from the discharging pond, which attributed to the adsorption of heavy metals, total organic carbon and sedimentation of suspended particulates. From this study it was concluded that the treated wastewater must be used in situ for production of animal fodder and prohibit its contact with the surface and groundwater resources of the area specially Al-Mujeb dam where it is collected.

scholarly journals Industrialization as a source of heavy metals and antibiotics which can enhance the antibiotic resistance in wastewater, sewage sludge and river water

PLoS ONE ◽  
2021 ◽  
Vol 16 (6) ◽  
pp. e0252691
Author(s):  
Jakub Hubeny ◽  
Monika Harnisz ◽  
Ewa Korzeniewska ◽  
Martyna Buta ◽  
Wiktor Zieliński ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Antibiotic Resistance ◽  
Sewage Sludge ◽  
River Water ◽  
Selective Pressure ◽  
Treatment Plant ◽  
Antibiotic Resistance Genes ◽  
Treated Wastewater ◽  
Gene Copy ◽  
The Impact

The spread of antibiotic resistance is closely related with selective pressure in the environment. Wastewater from industrialized regions is characterized by higher concentrations of these pollutants than sewage from less industrialized areas. The aim of this study was to compare the concentrations of contaminants such as antibiotics and heavy metals (HMs), and to evaluate their impact on the spread of genes encoding resistance to antimicrobial drugs in samples of wastewater, sewage sludge and river water in two regions with different levels of industrialization. The factors exerting selective pressure, which significantly contributed to the occurrence of the examined antibiotic resistance genes (ARGs), were identified. The concentrations of selected gene copy numbers conferring resistance to four groups of antibiotics as well as class 1 and 2 integron-integrase genes were determined in the analyzed samples. The concentrations of six HMs and antibiotics corresponding to genes mediated resistance from 3 classes were determined. Based on network analysis, only some of the analyzed antibiotics correlated with ARGs, while HM levels were correlated with ARG concentrations, which can confirm the important role of HMs in promoting drug resistance. The samples from a wastewater treatment plant (WWTP) located an industrialized region were characterized by higher HM contamination and a higher number of significant correlations between the analyzed variables than the samples collected from a WWTP located in a less industrialized region. These results indicated that treated wastewater released into the natural environment can pose a continuous threat to human health by transferring ARGs, antibiotics and HMs to the environment. These findings shed light on the impact of industrialization on antibiotic resistance dissemination.

scholarly journals Hydrological and Environmental Impact of Wastewater Treatment and Reuse on Zarqa River Basin in Jordan

Environments ◽  
2020 ◽  
Vol 7 (2) ◽  
pp. 14
Author(s):  
Naser Almanaseer ◽  
Muna Hindiyeh ◽  
Raha Al-Assaf
Keyword(s):  
Wastewater Treatment ◽  
Municipal Wastewater ◽  
Wastewater Reuse ◽  
Treatment Plant ◽  
Treated Wastewater ◽  
Jordan Valley ◽  
Treated Wastewater Reuse ◽  
Effective System ◽  
Zarqa River ◽  
The Impact

Treated wastewater is an important component of the water resource in Jordan. As Samra wastewater treatment plant—the largest treatment plant in Jordan—discharges ~110 MCM per year of secondary treated municipal wastewater to Zarqa River, and eventually to Jordan Valley. This research aims at assessing the impact of treated wastewater reuse on the hydrology and environment in the most vulnerable areas within Amman-Zarqa Basin, specifically from As Samra treatment plant to Jerash Bridge. Historical data is collected, field survey is performed, and chemical and biological analyses are performed at eleven selected locations along the study area. Afterwards, all collected data is managed using suitable tools to address the impact. The findings of this research demonstrate high improvement in biological and microbial parameters along the flow path, yet the salinity is increased downstream. It is found that this increase is due to brackish water intrusion, apparently from sandstone aquifer. Analysis of BOD and COD carried out as part of this research showed effective system recovery with COD reduction from 130 mg/L at the effluent to less than 50 mg/l in the downstream. Moreover, microbial activities are reduced, mainly due to self-purification in the river.

scholarly journals Characterization of preferential flow in soils near Zarqa river (Jordan) using in situ tension infiltrometer measurements

PeerJ ◽  
2019 ◽  
Vol 7 ◽  
pp. e8057
Author(s):  
Michel Rahbeh
Keyword(s):  
Soil Texture ◽  
Preferential Flow ◽  
Winter Season ◽  
Clay Content ◽  
Treated Wastewater ◽  
Irrigated Agriculture ◽  
Tension Infiltrometer ◽  
Significant Difference ◽  
Zarqa River

Background The Zarqa River (ZR) is located in the northern part of Jordan and supplies King Talal Dam (KTD). The streamflow that discharges into KTD is composed of treated wastewater from the Khirbat Es-Samra water treatment plant (KTP) and runoff generated during the winter season. Thus, during the summer, the streamflow of the ZR is dominated by effluent from the KTP. Due to the severe scarcity of water in Jordan, a portion of the streamflow is utilized for irrigated agriculture in the ZR valley, located between the KTP and KTD. The groundwater in the vicinity of the ZR is vulnerable to contamination—a risk that may be exacerbated by the potential occurrence of preferential flow (PF). Therefore, the PF in the soils near the ZR should be carefully considered. Methods The macropore flux fraction (Qmacro) and macroscopic capillary length (λc) were determined from in situ measurements using a tension infiltrometer equipped with an infiltration disc with a diameter of 20 cm. The macropore was defined as the pore size that drains at a tension of less than —-3— cm. The λc less than 80 mm was considered to be an indication of PF. The measurements were taken at 69 sites along the ZR between the KTP and KTD. At each measurement site, the soil organic matter content (OM) and soil texture were determined using a composite soil sample obtained by excavating the soil beneath the infiltration disc to a depth of 10 cm. Results The data was split into two groups: the matrix flow group (MF), which includes data associated with λc > 80 mm, and the PF group, which includes data associated with λc < 80 mm. The Qmacro values of 0.67 and 0.57, respectively, for PF and MF were significantly different at p < 0.01 (t-test). The flow rates at h=0 were generally well associated with λc, as attested to by a significant difference between the averages of PF (57.8 mm/hr) and MF (21.0 mm/hr) at p < 0.01 (t-test). The OM was positively associated with PF. This was statistically confirmed by a t-test at p < 0.01. The average sand and clay contents of PF and MF were not statistically different. Analysis of the ratio of Soil Organic Carbon (SOC) to clay showed that the average SOC/clay of the PF (14%) was larger than that of the MF (13.3%). After the exclusion of soils with clay content less than 8%, the differences between the SOC/clay averages of PF (9.8%) and MF (7.5%) were significant at p < 0.05, as shown by a WM-test. Conclusion The OM was positively associated with PF. Soil texture—and clay content in particular—influenced the λcvalues. However, the association of clay content with PF was not statistically significant. Consideration of the SOC/clay ratio showed that the tendency toward PF increases as the complexation of the clay content increases. This was most obvious in soils with a clay content of greater than 8% and SOC/clay of approximately 10%. The OM either influences or is inter-correlated with the processes responsible for the formation of macropores.

Агрономическая эффективность промышленной (голландской) технологии возделывания картофеля

2018 ◽  
Author(s):  
C. Coy ◽  
A.V. Shuravilin ◽  
O.A. Zakharova
Keyword(s):  
Heavy Metals ◽  
Regression Analysis ◽  
Positive Response ◽  
Growth Yield ◽  
Correlation And Regression Analysis ◽  
Yield And Quality ◽  
Quality Of Products ◽  
High Degree ◽  
The Impact

Приведены результаты исследований по изучению влияния промышленной технологии возделывания картофеля на развитие, урожайность и качество продукции. Выявлена положительная реакция растений на подкормку K2SO4 в период посадки. Корреляционно-регрессионный анализ урожайности и качества клубней выявил высокую степень достоверности результатов опыта. Содержание нитратов и тяжелых металлов в клубнях было ниже допустимых величин.The results of studies on the impact of industrial technology of potato cultivation on growth, yield and quality of products. There was a positive response of plants to fertilizer K2SO4 in the period of planting. Correlation and regression analysis of yield and quality of tubers revealed a high degree of reliability of the results of experience. The contents of nitrates and heavy metals in tubers was below the permissible values.

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