scholarly journals Grain-Size Control on the Rare Earth Elements Distribution in the Late Diagenesis of Cretaceous Shales from the Southern Apennines (Italy)

2014 ◽  
Vol 2014 ◽  
pp. 1-11 ◽  
Author(s):  
Francesco Cavalcante ◽  
Claudia Belviso ◽  
Giuseppe Piccarreta ◽  
Saverio Fiore

Different grain-size fractions of samples collected from shales were investigated to determine the role of late diagenetic grade and mineralogy on the rare earth elements (REE) distribution. The samples were collected from Upper Cretaceous varicoloured shales of the Sicilide Unit near the Corleto Perticara villages, Southern Apennines (Italy). The mineralogical and chemical composition of the sample’s five fractions (>63, 32–63, 2–32, 0.1–2, and <0.1 µm) was studied. The data indicate that certain accessory minerals are more important than clay minerals in controlling the REE distribution. In particular, zircon controls the distribution of earth elements in the 0.1–2 µm fraction and is an efficient mechanism in determining the concentration and distribution of REEs in the studied shales.

2002 ◽  
Vol 173 (2) ◽  
pp. 147-160 ◽  
Author(s):  
Samuel Deberdt ◽  
Jérôme Viers ◽  
Bernard Dupré

Abstract While the rare earth elements (REE) have largely contributed to the understanding of some internal geological processes, their use as tracers of superficial mechanisms (i.e., weathering and elements transport) remains tricky. This results from the poor knowledge we have of the REE distribution in the different fractions of solutions. Up to recently, the studies carried out on the REE behavior in continental aquatic systems were mainly based on the “paniculate” and “solution” fractions separated by an arbitrary filtration through a 0.20 or 0.45 μm pore size membrane. Some recent work has shown, using ultrafiltration experiments, that REE are mainly contained in the colloidal fraction (i.e., 0.20 μm - 1 nm). However, studies devoted to the control of REE by the colloidal matter, have essentially focused on the organic pool (i.e., humic substances). By contrast, the mineral colloidal pool has received little attention. In order to model these processes, we have developed a combined approach that consider (1) ultrafiltration experiments performed on a series of rivers located in Africa (Cameroon) and south America (Brazil, Venezuela) and (2) speciation calculations. This quantitative approach reveals, for the first time, that more than 60 % of the total REE in the solution of river waters is controlled by the mineral colloidal pool.


2013 ◽  
Vol 03 (03) ◽  
pp. 154-159 ◽  
Author(s):  
A. Nor Antonina ◽  
N. A. M. Shazili ◽  
B. Y. Kamaruzzaman ◽  
M. C. Ong ◽  
Y. Rosnan ◽  
...  

Author(s):  
Ernest L. Hall ◽  
Lee E. Rumaner ◽  
Mark G. Benz

The intermetallic compound Nb3Sn is a type-II superconductor of interest because it has high values of critical current density Jc in high magnetic fields. One method of forming this compound involves diffusion of Sn into Nb foil containing small amounts of Zr and O. In order to maintain high values of Jc, it is important to keep the grain size in the Nb3Sn as small as possible, since the grain boundaries act as flux-pinning sites. It has been known for many years that Zr and O were essential to grain size control in this process. In previous work, we have shown that (a) the Sn is transported to the Nb3Sn/Nb interface by liquid diffusion along grain boundaries; (b) the Zr and O form small ZrO2 particles in the Nb3Sn grains; and (c) many very small Nb3Sn grains nucleate from a single Nb grain at the reaction interface. In this paper we report the results of detailed studies of the Nb3Sn/Nb3Sn, Nb3Sn/Nb, and Nb3Sn/ZrO2 interfaces.


1962 ◽  
Vol 18 (4) ◽  
pp. 1127-1153
Author(s):  
V FASSEL ◽  
R CURRY ◽  
R KNISELEY

2017 ◽  
Vol 8 (1) ◽  
Author(s):  
Takaaki Hatanaka ◽  
Akimasa Matsugami ◽  
Takamasa Nonaka ◽  
Hideki Takagi ◽  
Fumiaki Hayashi ◽  
...  

2021 ◽  
pp. 138770
Author(s):  
Linlin Guan ◽  
Leiming Yu ◽  
Lijuan Wu ◽  
Shuyu Zhang ◽  
Yuting Lin ◽  
...  

1995 ◽  
Vol 102 (12) ◽  
pp. 5082-5087 ◽  
Author(s):  
Thomas Palberg ◽  
Wolfgang Mönch ◽  
Jürgen Schwarz ◽  
Paul Leiderer

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