scholarly journals Study of Magnetic Property of Sn Doped Ni-Zn-Fe Nanoparticles

2014 ◽  
Vol 2014 ◽  
pp. 1-4 ◽  
Author(s):  
B. S. Tewari ◽  
Archana Dhyani ◽  
S. K. Joshi ◽  
Santosh Dubey ◽  
Kailash Pandey

The Ni0.6+xZn0.4SnxFe2-2xO4 (x=0.00 to 0.04) samples were prepared by solution route technique. These samples were characterized by XRD and EPR spectra at X-band frequency (~9.2 GHz). The XRD spectra of these ferrites confirm the formation of spinel structure. The average particle size calculated by using Scherrer’s formula was found to be of the order of 24.7 nm. The EPR spectra of these ferrites are mainly due to Fe3+ ions. Fe2+ ions have very short spin-lattice relaxation time and therefore EPR spectra of Fe2+ could be observed only at very low temperature. This fact is also supported by the isomer shift values of these ferrites obtained from Mössbauer spectroscopy. The variation of geff and ΔHPP with Sn4+ concentration is attributed to the variation of superexchange interaction. Moreover in this system the dominant process of relaxation is the spin lattice relaxation rather than the spin-spin interaction.

1963 ◽  
Vol 41 (1) ◽  
pp. 33-45 ◽  
Author(s):  
K. E. Rieckhoff ◽  
D. J. Griffiths

The magneto-optical Faraday effect was used to measure the saturation of the spin levels in concentrated neodymium ethylsulphate in both steady-state and pulsed microwave resonance experiments at liquid helium temperatures. The steady-state experiments yielded the paramagnetic resonance spectrum consisting of a main triplet and an extensive hyperfine structure. The line positions are explained in terms of the known spin Hamiltonian of the diluted salt and spin–spin interaction between nearest neighbors. An asymmetry of the line shape was observed for sufficiently low temperatures in qualitative agreement with existing theories. Measurements of saturation s versus microwave power P at constant field and temperature were made and yielded the relationship [Formula: see text] for s > 10%. The steady-state experiments also revealed the existence of a spatial gradient in the saturation across the sample.The pulsed experiments gave the spin–lattice relaxation time τ as a function of magnetic field H at various temperatures. At 4.2 °K, τ was found to be independent of H and of the order of 11 msec for fields from 800 to [Formula: see text], while at temperatures below 2 °K, τ was found to be strongly field-dependent, indicating the importance of cross-relaxation effects at temperatures [Formula: see text].


1978 ◽  
Vol 39 (C6) ◽  
pp. C6-1215-C6-1216
Author(s):  
H. Ahola ◽  
G.J. Ehnholm ◽  
S.T. Islander ◽  
B. Rantala

1988 ◽  
Vol 11 (2) ◽  
pp. 97-102 ◽  
Author(s):  
Kiichiro Matsumura ◽  
Imaharu Nakano ◽  
Nobuo Fukuda ◽  
Hiroo Ikehira ◽  
Yukio Tateno ◽  
...  

2020 ◽  
Vol 44 (44) ◽  
pp. 19393-19403
Author(s):  
Krishna Kishor Dey ◽  
Manasi Ghosh

The correlation between the structure and dynamics of omeprazole is portrayed by extracting CSA parameters through the 13C 2DPASS CP-MAS SSNMR experiment, site specific spin–lattice relaxation time by Torchia CP experiment, and calculation of the molecular correlation time.


1985 ◽  
Vol 40 (11) ◽  
pp. 1075-1084
Author(s):  
W. T. Sobol ◽  
K.R. Sridharan ◽  
I. G. Cameron ◽  
M. M. Pintar

The frequency dependence of the spin-lattice relaxation time T1 was measured at three temperatures near one of the Zeeman-tunneling level matching resonances for pentamethylbenzene. These measurements are correlated with 71 temperature dependence data from the literature. It is shown that the frequency dependence of the Zeeman-torsion coupling time cannot be explained in terms of the semiclassical perturbation theory using time correlation functions. A three bath polarization transfer model is also employed and the applicability of both models discussed. Zeeman-torsion coupling is further investigated using a saturation sequence and the results are compared with the predictions of the three bath polarization transfer model.


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