scholarly journals Multivariate Analysis, Mass Balance Techniques, and Statistical Tests as Tools in Igneous Petrology: Application to the Sierra de las Cruces Volcanic Range (Mexican Volcanic Belt)

2014 ◽  
Vol 2014 ◽  
pp. 1-32 ◽  
Author(s):  
Fernando Velasco-Tapia

Magmatic processes have usually been identified and evaluated using qualitative or semiquantitative geochemical or isotopic tools based on a restricted number of variables. However, a more complete and quantitative view could be reached applying multivariate analysis, mass balance techniques, and statistical tests. As an example, in this work a statistical and quantitative scheme is applied to analyze the geochemical features for the Sierra de las Cruces (SC) volcanic range (Mexican Volcanic Belt). In this locality, the volcanic activity (3.7 to 0.5 Ma) was dominantly dacitic, but the presence of spheroidal andesitic enclaves and/or diverse disequilibrium features in majority of lavas confirms the operation of magma mixing/mingling. New discriminant-function-based multidimensional diagrams were used to discriminate tectonic setting. Statistical tests of discordancy and significance were applied to evaluate the influence of the subducting Cocos plate, which seems to be rather negligible for the SC magmas in relation to several major and trace elements. A cluster analysis following Ward’s linkage rule was carried out to classify the SC volcanic rocks geochemical groups. Finally, two mass-balance schemes were applied for the quantitative evaluation of the proportion of the end-member components (dacitic and andesitic magmas) in the comingled lavas (binary mixtures).

Author(s):  
Dennis Sánchez-Mora ◽  
Christopher R.M. McFarlane ◽  
James A Walker ◽  
David R. Lentz

Gold mineralization at Williams Brook in northern New Brunswick is hosted within the Siluro-Devonian, bimodal, volcano-sedimentary rocks of the Tobique-Chaleur Zone (Wapske Formation). Gold mineralization occurs in two styles: 1) as disseminations (refractory gold) in rhyolite, and 2) in cross-cutting quartz veins (free gold). Dating of the felsic volcanic host rocks by in situ LA-ICP-MS zircon U-Pb geochronology returned ages of 422 ± 3, 409 ± 2, 408 ± 3, 405 ± 2, 401 ± 9 Ma. Zr/Y of subvolcanic felsic intrusion (<8 for syn-mineralization and >8 for post-mineralization) suggests evolution from transitional to more alkalic affinities. Two mineralizing events are recognized; the first is a disseminated mineralization style formed at ~422–416 Ma and the second consists of quartz vein-hosted gold emplaced at 410–408 Ma. Felsic rocks from Williams Brook and elsewhere in the Tobique Group (i.e. Wapske, Costigan Mountain, and Benjamin formations), and the Coastal Volcanic Belt have similar Th/Nb ratios of ~0.1 to 1, reflecting similar levels of crustal contamination, and similar Nb and Y content, suggesting A-type affinities. These data indicate a similar environment of formation. Regionally, mafic rocks show similar within-plate continental signatures and an E-MORB mantle source that formed from partial melts of 10–30%. Mafic volcanic rocks from Williams Brook have a more alkaline affinity (based on Ti/V), and derivation from lower percentage partial melting (~5%). The chemical and temporal variations in the Williams Brook rocks suggest that they were erupted in an evolving transpressional tectonic setting during the oblique convergence of Gondwana and Laurentia.


Geosphere ◽  
2021 ◽  
Author(s):  
Juliana Mesa ◽  
Rebecca A. Lange

A detailed petrological study is presented to constrain the origin of a suite of alkali olivine basalt and hawaiite (&gt;5 wt% MgO) lavas that were erupted in a rift zone within the western Mexican arc (Trans-Mexican Volcanic Belt), adjacent to the Sangangüey andesitic stratovolcano, together with more evolved lavas (mugearites and benmoreites; &lt;5 wt% MgO). As previously documented in the literature, the Sangangüey mafic lavas are devoid of any arc geochemical signature, despite their location within an arc. In this study, a new olivine-melt thermometer/hygrometer, based on the partition­ing behavior of Ni2+ and Mg2+, was applied to the Sangangüey basalts (SB). The results show that the high-MgO (&gt;9 wt%) SB crystallized at higher temperatures and lower melt-water contents (0–1.3 wt%) compared to high-MgO arc basalts (≤5.7 wt% H2O) erupted in the west-central Mexican arc. The Sangangüey lavas with 5–8 wt% MgO display evidence of mixing between high-MgO alkali olivine basalts and low-MgO mugearites. It is proposed that the unique composition of the mugearites (i.e., low SiO2 contents and elevated FeO and TiO2 contents) is the result of partial melting of mafic lower crust driven by the influx of high-MgO intraplate basalts under relatively hot, dry, and reduced conditions. On the basis of crystal textures and compositional zoning patterns, it is shown that both phenocryst growth and magma mixing occurred rapidly, most likely during ascent along fractures, and not slowly during prolonged storage in a crustal magma chamber.


Nova Scientia ◽  
2014 ◽  
Vol 6 (11) ◽  
pp. 158 ◽  
Author(s):  
Lorena Díaz-González ◽  
René Cruz-Huicochea

Our aim is to show a statistical procedure along with two new computer programs (DODESSYS and UDASYS). For this task we compiled a database of 249 samples of dacite coming from four closely located Mexican Volcanic Belt (MVB) areas: monogenetic volcanoes from the Sierra de Chichinautzin and Valle de México, the Nevado de Toluca stratovolcano, the Iztaccíhuatl stratovolcano and the Popocatépetl stratovolcano. The discordancy and significance (ANOVA –ANalysis Of Variance–, Fishers´ F and Student´s t) statistical tests were applied at 99% confidence level. The final statistical was calculated for 98 geochemical parameters, these include major oxides, rare earth elements, trace elements and additional parameters, as well as log-ratio parameters used in new tectonic discrimination diagrams. These geochemical parameters were treated as univariate statistical samples and were classified according with the four MVB regions. Discordancy statistical tests detected discordant outliers in 124 (amount to about 35%) statistical samples. ANOVA tests showed significant differences among all groups in 32 parameters. The similarities and differences between the log-ratios parameters elements may eventually be useful in future to propose tectonic discrimination diagrams from a representative database.


2002 ◽  
Vol 39 (5) ◽  
pp. 687-710 ◽  
Author(s):  
D T James ◽  
S Kamo ◽  
T Krogh

A new model for evolution of the Archean Hopedale Block, based on mapping and supporting U–Pb geochronological and geochemical studies, is highlighted by (i) ca. 3.25 Ga emplacement of igneous precursors of Maggo Gneiss; (ii) &gt3.1 Ga, high-grade Hopedalian metamorphism and attendant deformation; (iii) emplacement of the Hopedale mafic dykes; (iv) 3.1 Ga deposition of Hunt River volcanic rocks; (v) ca. 3.0 Ga deposition of Florence Lake volcanic rocks; (vi) 2.88–2.96 Ga, greenschist- to amphibolite-facies Fiordian metamorphism and formation of penetrative, northeast-striking Fiordian structures; and (vii) emplacement of a suite of 2.89–2.83 Ga tonalite to granite intrusions, which partially overlap and locally postdate Fiordian metamorphism and deformation. The Hunt River and Florence Lake volcanic sequences are different in age but similar in most other respects. The former consists mainly of amphibolite-facies mafic metavolcanic rocks and lesser amounts of komatiite flows and metasedimentary and 3105 ± 3 Ma felsic volcanic rocks. The Florence Lake volcanic belt consists mainly of greenschist- to amphibolite-facies mafic metavolcanic rocks, lesser amounts of felsic metavolcanic rocks, dated at 2979 ± 1 and 2990 ± 2 Ma, komatiite flows, and rare metasedimentary rocks. The similarity of rock types, field relationships between different rock types, such as the common association of ultramafic and felsic metavolcanic rocks, and the chemistry of volcanic rocks in both belts suggest a common tectonic setting for each belt. A model involving episodic volcanism, separated by 100 Ma, in ensialic basins is consistent with the dominance of tholeiitic basalt and an abundance of pre-volcanic basement.


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