scholarly journals Up- and Downconversion Luminescence Properties of Nd3+Ions Doped in Bi2O3–BaO–B2O3Glass System

2014 ◽  
Vol 2014 ◽  
pp. 1-5 ◽  
Author(s):  
R. Ruamnikhom ◽  
P. Limsuwan ◽  
M. Horprathum ◽  
N. Chanthima ◽  
H. J. Kim ◽  
...  
Keyword(s):  
Radiative Decay ◽  
Excited State Absorption ◽  
Upconversion Emission ◽  
Luminescence Properties ◽  
Barium Borate ◽  
Melt Quenching ◽  
Strong Fluorescence ◽  
Nir Emission ◽  
Quenching Method ◽  
Barium Borate Glass

Physical, optical, and luminescence properties of Nd3+ions in bismuth barium borate glass system were studied. The glasses prepared by a melt quenching method were doped at various Nd2O3concentrations in compositions (40-x)B2O3 : 40Bi2O3 : 20BaO : xNd2O3(wherex= 0.00, 0.50, 1.00, 1.50, 2.00, and 2.50 in mol%). Luminescence properties of the glasses were studied under two excitations of 585 and 750 nm for downconversion. From both excitations, the results show emission bands in NIR region corresponding to the transitions between4F3/2 → 4I9/2(900 nm),4F3/2 → 4I11/2(1,060 nm), and4F3/2 → 4I13/2(1,345 nm). The luminescence intensity obtained with 585 nm excitation was stronger than 750 nm, with the strongest NIR emission at 1,060 nm. The upconversion emission spectrum exhibits strong fluorescence bands in the UV region at 394 nm (λex=591 nm). The processes are associated with excited state absorption (ESA) from4F3/2level to4D3/2level and it is the radiative decay from the4D3/2to ground levels (4D3/2 → 4I13/2) which are responsible for the emission at 394 nm.

Physical and Structural Properties of Dysprosium Doped Barium Borate Glass

2019 ◽  
Vol 290 ◽  
pp. 46-52 ◽  
Author(s):  
Norihan Yahya ◽  
Mardhiah Abdullah ◽  
Mohamed Najmi Naquib Mohamed Zainal Abidin ◽  
Azman Kasim ◽  
Azhan Hashim
Keyword(s):  
Molar Volume ◽  
Structural Properties ◽  
Borate Glass ◽  
Glass Network ◽  
Barium Borate ◽  
X Ray Diffraction ◽  
Melt Quenching ◽  
X Ray ◽  
Amorphous Nature ◽  
Barium Borate Glass

Five distinguish glass samples were prepared by melt quenching technique of the composition (81-x)H3BO3-19BaCO3-xDy2O3 with x = 0, 0.2, 0.4, 0.6 and 0.8 mol%. The effect of Dy3+ to the barium borate glass can be investigated in terms of their physical properties such as density, molar volume and oxygen packing density. The structural properties were analyzed by X-Ray Diffraction (XRD) technique and Fourier Transform Infrared Spectroscopy (FTIR). The result revealed that the increment of mol% of Dy3+ in the compound generally will increases the density and molar volume of the glass samples. The amorphous nature of the glass system was verified from the XRD spectra pattern. Meanwhile, the FTIR spectra shown the presence of Ba2+, BO3, BO4, B-O-B linkage, H-O-H and isolated borate in the glass network.

Luminescence Properties of Magnesium Phosphate Glass Doped Samarium

2012 ◽  
Vol 501 ◽  
pp. 111-115 ◽  
Author(s):  
M.R. Sahar ◽  
Nurulhuda Mohammad Yusoff ◽  
S.K. Ghosal ◽  
M. Supar Rohani ◽  
Khaidzir Hamzah ◽  
...  
Keyword(s):  
Emission Spectrum ◽  
Phosphate Glass ◽  
Room Temperature ◽  
Emission Spectra ◽  
Magnesium Phosphate ◽  
Luminescence Properties ◽  
Melt Quenching ◽  
Quenching Method

Samarium doped magnesium phosphate glass having a composition of [P2O5]50-x-[MgO]50-[Sm2O3]x, with 0≤x≤4 mol% were prepared by melt-quenching method. The emission spectra were recorded using the photoluminescence spectrometer in the range of 540-730 nm at room temperature after being excited at 403 nm. It was found that the emission spectrum of Sm3+consisted of four emission bands at ~559.76 nm, ~597.32 nm, ~641.55 nm and ~705.57 nm which were assign as a transition of 4G5/2→6H5/2, 4G5/2 →6H7/2, 4G5/2→6H9/2 and 4G5/2→6H11/2 respectively. The transition of 4G5/2→6H7/2 is detected as the strongest orange (597.32 nm) luminescence peaks thus dominates the transition.

scholarly journals Morphology and Magnetic Properties of Ferriferous Two-Phase Sodium Borosilicate Glasses

2014 ◽  
Vol 2014 ◽  
pp. 1-7 ◽  
Author(s):  
Alexander Naberezhnov ◽  
Nadezda Porechnaya ◽  
Viktor Nizhankovskii ◽  
Alexey Filimonov ◽  
Bernard Nacke
Keyword(s):  
Magnetic Properties ◽  
Iron Oxides ◽  
Channel Structure ◽  
Borosilicate Glasses ◽  
Melt Quenching ◽  
Two Phase ◽  
Furnace Charge ◽  
Self Assembling ◽  
Quenching Method ◽  
Drop Structure

This contribution is devoted to the study of morphology and magnetic properties of sodium borosilicate glasses with different concentrations (15, 20, and 25 wt.%) ofα-Fe2O3in an initial furnace charge. These glasses were prepared by a melt-quenching method. For all glasses a coexistence of drop-like and two-phase interpenetrative structures is observed. The most part of a drop structure is formed by self-assembling iron oxides particles. All types of glasses demonstrate the magnetic properties and can be used for preparation of porous magnetic matrices with nanometer through dendrite channel structure.

Energy transfer from UO++2 → Nd3+ in barium borate glass

1978 ◽  
Vol 16 (4) ◽  
pp. 435-440 ◽  
Author(s):  
J.C. Joshi ◽  
N.C. Pandey ◽  
B.C. Joshi ◽  
Janardan Joshi
Keyword(s):  
Energy Transfer ◽  
Borate Glass ◽  
Barium Borate ◽  
Barium Borate Glass

Structural Studies of Lead Sodium Borate Glasses

2010 ◽  
Vol 93-94 ◽  
pp. 439-442
Author(s):  
Pruittipol Limkitjaroenporn ◽  
Jakrapong Kaewkhao ◽  
Suparat Tuscharoen ◽  
Pichet Limsuwan ◽  
Weerapong Chewpraditkul
Keyword(s):  
Molar Volume ◽  
Glass Network ◽  
Sodium Borate ◽  
Borate Glasses ◽  
Structural Studies ◽  
Melt Quenching ◽  
Network Modifier ◽  
Ir Analysis ◽  
Quenching Method ◽  
Glass Compositions

Glass compositions xPbO : 20Na2O : (80-x)B2O3 (x = 5,10,15,20,25,30,35,40,45,50 and 55 %mol) have been prepared using melt-quenching method. The density and molar volume of these glass samples have been found to be compositional dependent. The results indicate that PbO acts on the glass structures were different between the range 0≤ x ≤ 20 %mol and beyond x = 20 %mol (with inflection at x = 20 %mol). These due to the PbO can enter the glass network both as a network modifier and also as a network former. This role depends on the type of bond between lead and oxide. These results are interpreted in term of IR analysis.

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