scholarly journals Characterization of the Organic Thin Film Solar Cells with Active Layers of PTB7/PC71BM Prepared by Using Solvent Mixtures with Different Additives

2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
Masakazu Ito ◽  
Kumar Palanisamy ◽  
Abhirami Kumar ◽  
Vijay Srinivasan Murugesan ◽  
Paik-Kyun Shin ◽  
...  
Keyword(s):  
Thin Film ◽  
Solar Cells ◽  
Current Density ◽  
Spin Coating ◽  
Morphological Changes ◽  
Short Circuit ◽  
Thin Film Solar Cells ◽  
Solvent Mixtures ◽  
Organic Thin Film ◽  
Active Layers

Organic thin film solar cells (OTFSCs) were fabricated with blended active layers of poly[[4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl][3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophenediyl]] (PTB7)/[6,6]-phenyl-C71-butyric (PC71BM). The performances of active layers are prepared in chlorobenzene (CB) with different additives of 1-chloronaphthalene (CN) and 1,8-Diiodooctane (DIO) by a wet process with spin coating technique. The effects of different solvent additives on photovoltaic parameters such as fill factor, short circuit current density, and power conversion efficiency of active layers are reported. The absorption and surface morphology of the active layers are investigated using UV-visible spectroscopy and atomic force microscopy, respectively. The results indicate that structural and morphological changes were induced by the additives with solvent. The current density-voltage (J-V) characteristics of photovoltaic cells were measured under the illumination of simulated solar light with 100 mW/cm2(AM 1.5 G) by an Oriel 1000 W solar simulator. The OTFSCs of PTB7/PC71BM prepared with organic solvent additives of DIO+CN show more improved PCE of 4.96% by spin coating method.

scholarly journals Characterization of Organic Thin Film Solar Cells of PCDTBT : PC71BM Prepared by Different Mixing Ratio and Effect of Hole Transport Layer

2015 ◽  
Vol 2015 ◽  
pp. 1-8 ◽  
Author(s):  
Vijay Srinivasan Murugesan ◽  
Shusuke Ono ◽  
Norio Tsuda ◽  
Jun Yamada ◽  
Paik-Kyun Shin ◽  
...  
Keyword(s):  
Thin Film ◽  
Solar Cells ◽  
Short Circuit ◽  
Hole Transport ◽  
Transport Layer ◽  
Thin Film Solar Cells ◽  
Hole Transport Layer ◽  
Organic Thin Film ◽  
Mixing Ratios ◽  
Active Layers

The organic thin film solar cells (OTFSCs) have been successfully fabricated using PCDTBT : PC71BM with different mixing ratios (1 : 1 to 1 : 8) and the influence of hole transport layer thickness (PEDOT : PSS). The active layers with different mixing ratios of PCDTBT : PC71BM have been fabricated using o-dichlorobenzene (o-DCB). The surface morphology of the active layers and PEDOT : PSS layer with different thicknesses were characterized by AFM analysis. Here, we report that the OTFSCs with high performance have been optimized with 1 : 4 ratios of PCDTBT : PC71BM. The power conversion efficiency (PCE = 5.17%) of the solar cells was significantly improved by changing thickness of PEDOT : PSS layer. The thickness of the PEDOT : PSS layer was found to be of significant importance; the thickness of the PEDOT : PSS layer at 45 nm (higher spin speed 5000 rpm) shows higher short circuit current density (Jsc) and lower series resistance (Rs) and higher PCE.

Nanoimprint Photonic Crystal Film Enhanced Light-Trapping in a-Si Thin Film Solar Cells

2011 ◽  
Vol 110-116 ◽  
pp. 497-502
Author(s):  
Wei Ping Chu ◽  
Fuh Shyang Juang ◽  
Jian Shian Lin ◽  
Tien Chai Lin ◽  
Chen Wei Kuo
Keyword(s):  
Thin Film ◽  
Solar Cells ◽  
Photonic Crystals ◽  
Current Density ◽  
Light Trapping ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Short Circuit Current Density ◽  
Thin Film Solar Cells ◽  
Uv Lamp

We utilize photonic crystals to enhanced lighttrapping in a-Si:H thin film solar cells. The photonic crystals effectively increase Haze ratio of glass and decrease reflectance of a-Si:H solar cells. Therefore, increase the photon path length to obtain maximum absorption of the absorber layer. The photonic crystals can effective in harvesting weakly absorbing photons with energies just above the band edge. We were spin coated UV glue on the glass, and then nanoimprint of photonic crystals pattern. Finally, used UV lamp was curing of UV glue on the glass. When the 45∘composite photonic crystals structures, the haze was increase to 87.9 %, resulting the short circuit current density and efficiency increasing to 13.96 mA/cm2 and 7.39 %, respectively. Because 45∘composite photonic crystals easy to focus on the point of light lead to the effect of scattering can’t achieve. So, we designs 90∘V-shaped photonic crystals structures to increase scattering. When the 90∘V-shaped photonic crystals structures, the Haze was increase to 93.9 %. Therefore, the short circuit current density and Efficiency increasing to 15.62 mA/cm2 and 8.09 %, respectively. We observed ~35 % enhancement of the short-circuit current density and ~31 % enhancement of the conversion efficiency.

DEPENDENCE OF DEVICE CHARACTERISTICS OF BULK-HETEROJUNCTION ORGANIC THIN-FILM SOLAR CELLS ON CONCENTRATION OF GLYCEROL AND SORBITOL ADDITION IN PEDOT: PSS SOLUTIONS FOR FABRICATING BUFFER LAYERS

2010 ◽  
Vol 19 (04) ◽  
pp. 653-662 ◽  
Author(s):  
YUSUKE YAMAKI ◽  
KAZUHIRO MARUMOTO ◽  
TAKUYA FUJIMORI ◽  
TATSUO MORI
Keyword(s):  
Thin Film ◽  
Solar Cells ◽  
Bulk Heterojunction ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Open Circuit ◽  
Buffer Layers ◽  
Thin Film Solar Cells ◽  
Organic Thin Film ◽  
Device Structure

We have investigated the dependence of device characteristics of bulk-heterojunction organic thin-film solar cells on the concentration of glycerol and sorbitol addition in poly(3,4-ethylenedioxy thiophene):poly(4-styrene sulfonate) (PEDOT:PSS) solutions for fabricating buffer layers. The device structure is ITO/buffer/regioregular poly(3-hexylthiophene) (P3HT):[6,6]-phenyl C 61-butyric acid methylester (PCBM)/ Al . Glycerol addition is effective for increasing power conversion efficiency (PCE) from 1.25 to 1.41% because of the increase in short-circuit current density (J sc ) without decreasing open-circuit voltage (V oc ). On the other hand, sorbitol addition decreases PCE from 1.25 to 1.04%, owing to the decrease in V oc . This difference in V oc behavior is ascribed to different work function of PEDOT:PSS with glycerol and sorbitol treatment.

scholarly journals Improved Metal Oxide Electrode for CIGS Solar Cells: The Application of an AgOX Wetting Layer

2021 ◽  
Vol 16 (1) ◽  
Author(s):  
Nils Neugebohrn ◽  
Norbert Osterthun ◽  
Maximilian Götz-Köhler ◽  
Kai Gehrke ◽  
Carsten Agert
Keyword(s):  
Thin Film ◽  
Solar Cells ◽  
Metal Oxide ◽  
Metal Layer ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Thin Film Solar Cells ◽  
Wetting Layer ◽  
Transparent Conductive Oxides ◽  
Effective Measure

AbstractOxide/metal/oxide (OMO) layer stacks are used to replace transparent conductive oxides as front contact of thin-film solar cells. These multilayer structures not only reduce the overall thickness of the contact, but can be used for colouring of the cells utilizing interference effects. However, sheet resistance and parasitic absorption, both of which depend heavily on the metal layer, should be further reduced to reach higher efficiencies in the solar cells. In this publication, AgOX wetting layers were applied to OMO electrodes to improve the performance of Cu(In,Ga)Se2 (CIGS) thin-film solar cells. We show that an AgOX wetting layer is an effective measure to increase transmission and conductivity of the multilayer electrode. With the presented approach, we were able to improve the short-circuit current density by 18% from 28.8 to 33.9 mA/cm2 with a metal (Ag) film thickness as low as 6 nm. Our results highlight that OMO electrodes can be an effective replacement for conventional transparent conductive oxides like aluminium-doped zinc oxide on thin-film solar cells.

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