Two-Pulse Phase Modulation Based Decoupling Schemes for Removing Heteronuclear Spin Interactions in the NMR Spectroscopy of
Isotropic Systems: An Analysis Using Experiments and Numerical Simulations
Keyword(s):
Heteronuclear spin interactions in solids and anisotropic liquids can be removed by phase modulated decoupling sequences with frequency sweep, such as SWf-TPPM and its variants. The performance of these sequences in isotropic spin systems with regard to the experimental parameters, phase angle, and decoupler offset is presented here. A comparison is made with other commonly used heteronuclear decoupling schemes in liquids, namely, WALTZ-16, GARP, and MLEV. Also, the trajectories of nuclear magnetization vector of abundant nuclei in a simple spin system during TPPM and SWf-TPPM decoupling sequences are traced out using computer simulations.
1983 ◽
Vol 78
(9)
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pp. 5293-5310
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1978 ◽
Vol 92
(3-4)
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pp. 446-458
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2002 ◽
Vol 16
(20n22)
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pp. 3369-3372
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1989 ◽
Vol 83
(2)
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pp. 279-298
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2009 ◽
Vol 150
(4)
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pp. 042076
Keyword(s):
Magnetic properties and spin structure on Ising spin system with two-spin and four-spin interactions
2007 ◽
Vol 310
(2)
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pp. e435-e437
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Keyword(s):