scholarly journals Tunable Nanodielectric Composites

2014 ◽  
Vol 2014 ◽  
pp. 1-6 ◽  
Author(s):  
Daniel Qi Tan ◽  
Yang Cao ◽  
Xiaomei Fang ◽  
Patricia C. Irwin

This paper presents a progress update with the development of nanodielectric composites with electric field tunability for various high energy, high power electrical applications. It is demonstrated that nonlinear electrical/dielectric properties can be achieved via the nanostructure and interface engineering. A high level summary was given on the progress achieved as well as challenges remaining in nanodielectric engineering towards high energy density capacitors for energy storage and conversion, nonlinear dielectrics for tunable device, and high voltage varistor for surge suppression.

2020 ◽  
Vol 8 (35) ◽  
pp. 12314-12322
Author(s):  
Bingchao Yang ◽  
Xiangjun Li ◽  
Yong Cheng ◽  
Shuai Duan ◽  
Bo Zhao ◽  
...  

Two-dimensional (2D) layered bismuth (Bi) with a thickness-dependent direct bandgap (0–0.55 eV) has attracted ever-increasing research interest in electronics, energy storage and conversion devices.


Author(s):  
Haixiong Tang ◽  
Yirong Lin ◽  
Clark Andrews ◽  
Henry A. Sodano

0–3 Piezoceramic polymer composites have attracted immense attention due to the flexibility afforded by the polymer matrix and the strong electromechanical coupling and high dielectric properties of the piezoceramic filler. The majority of research on these materials has focused on the effective piezoelectric properties of the piezoceramic polymer composites. However, the high dielectric strength of the polymer combined with the high permittivity of the ceramic filler make them well suited for use as high energy density capacitors and various pulsed power applications. Current work in this area has focused on the enhancement of the dielectric properties through a variation of nanoparticle composition or surface modifications to the fillers to enhance the energy density of composites. Recently, research and micromechanics modeling have shown that the filler aspect ratio plays an important role in increasing the effective dielectric properties of the composites. Therefore, unlike prior efforts, this work will focus on the effect of filler aspect ratio on the dielectric properties of the bulk nanocomposite. Nanocomposites were synthesized using lead zirconate titanate (PZT) with two different aspect ratio (nanowires, nanorods) fillers at various volume fractions dispersed in a polyvinylidene fluoride (PVDF) matrix. It was shown that the nanocomposites containing PZT nanowires (NWs) significantly increased the energy density compared to those containing lower aspect ratio PZT nanorods (NRs). The permittivity constants of composites containing PZT NWs were higher than those with PZT NRs at the same inclusion volume fraction. The experimental results also indicated that the high frequency loss tangent of nanocomposites with PZT NWs was smaller than those of PZT NRs, demonstrating the high electrical energy storage efficiency of the PZT NW composite. The PZT NW nanocomposites showed a 77.8% increase in energy density over the PZT NR nanocomposites, under an electric field of 15 kV/mm and 50% volume fraction. Because the energy density exhibits a quadratic relationship with the applied electric field, the performance enhancement through the use of NWs is even greater at higher electric fields. These results indicate that higher aspect ratio PZT nanowires shows promising potential to improve the energy density of nanocomposites, leading the development of advanced capacitors with high energy density.


Author(s):  
Zhiqiang Luo ◽  
Silin Zheng ◽  
Shuo Zhao ◽  
Xin Jiao ◽  
Zongshuai Gong ◽  
...  

Benzoquinone with high theoretical capacity is anchored on N-plasma engraved porous carbon as a desirable cathode for rechargeable aqueous Zn-ion batteries. Such batteries display tremendous potential in large-scale energy storage applications.


RSC Advances ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 5432-5443
Author(s):  
Shyam K. Pahari ◽  
Tugba Ceren Gokoglan ◽  
Benjoe Rey B. Visayas ◽  
Jennifer Woehl ◽  
James A. Golen ◽  
...  

With the cost of renewable energy near parity with fossil fuels, energy storage is paramount. We report a breakthrough on a bioinspired NRFB active-material, with greatly improved solubility, and place it in a predictive theoretical framework.


Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3586
Author(s):  
Qi An ◽  
Xingru Zhao ◽  
Shuangfu Suo ◽  
Yuzhu Bai

Lithium-ion capacitors (LICs) have been widely explored for energy storage. Nevertheless, achieving good energy density, satisfactory power density, and stable cycle life is still challenging. For this study, we fabricated a novel LIC with a NiO-rGO composite as a negative material and commercial activated carbon (AC) as a positive material for energy storage. The NiO-rGO//AC system utilizes NiO nanoparticles uniformly distributed in rGO to achieve a high specific capacity (with a current density of 0.5 A g−1 and a charge capacity of 945.8 mA h g−1) and uses AC to provide a large specific surface area and adjustable pore structure, thereby achieving excellent electrochemical performance. In detail, the NiO-rGO//AC system (with a mass ratio of 1:3) can achieve a high energy density (98.15 W h kg−1), a high power density (10.94 kW kg−1), and a long cycle life (with 72.1% capacity retention after 10,000 cycles). This study outlines a new option for the manufacture of LIC devices that feature both high energy and high power densities.


2019 ◽  
Vol 7 (8) ◽  
pp. 4110-4118 ◽  
Author(s):  
Chunyang Li ◽  
Wenzhuo Wu ◽  
Shuaishuai Zhang ◽  
Liang He ◽  
Yusong Zhu ◽  
...  

A proof-of-concept lithium ion capacitor comprising LiMn2O4 nanorods as the cathode, a nitrogen-rich biomass carbon anode and a stable alkaline–neutral electrolyte was designed and fabricated.


2018 ◽  
Vol 10 (8) ◽  
pp. 2660 ◽  
Author(s):  
Yi Yuan ◽  
Yingjie Li ◽  
Jianli Zhao

The intermittent and inconsistent nature of some renewable energy, such as solar and wind, means the corresponding plants are unable to operate continuously. Thermochemical energy storage (TES) is an essential way to solve this problem. Due to the advantages of cheap price, high energy density, and ease to scaling, CaO-based material is thought as one of the most promising storage mediums for TES. In this paper, TES based on various cycles, such as CaO/CaCO3 cycles, CaO/Ca(OH)2 cycles, and coupling of CaO/Ca(OH)2 and CaO/CaCO3 cycles, were reviewed. The energy storage performances of CaO-based materials, as well as the modification approaches to improve their performance, were critically reviewed. The natural CaO-based materials for CaO/Ca(OH)2 TES experienced the multiple hydration/dehydration cycles tend to suffer from severe sintering which leads to the low activity and structural stability. It is found that higher dehydration temperature, lower initial sample temperature of the hydration reaction, higher vapor pressure in the hydration reactor, and the use of circulating fluidized bed (CFB) reactors all can improve the energy storage performance of CaO-based materials. In addition, the energy storage performance of CaO-based materials for CaO/Ca(OH)2 TES can be effectively improved by the various modification methods. The additions of Al2O3, Na2Si3O7, and nanoparticles of nano-SiO2 can improve the structural stabilities of CaO-based materials, while the addition of LiOH can improve the reactivities of CaO-based materials. This paper is devoted to a critical review on the development on thermochemical energy storage based on CaO-based materials in the recent years.


Sign in / Sign up

Export Citation Format

Share Document