scholarly journals Study of Natural and Accelerated Weathering on Mechanical Properties of Antioxidants Modified Low Density Polyethylene Films for Greenhouse

2014 ◽  
Vol 2014 ◽  
pp. 1-5 ◽  
Author(s):  
Othman Al Othman ◽  
Shan Faiz ◽  
Muhammad Abduh Tuasikal
Keyword(s):  
Tensile Strength ◽  
Low Density Polyethylene ◽  
Commercial Application ◽  
Accelerated Weathering ◽  
Low Density ◽  
Life Effectiveness ◽  
Elongation At Break ◽  
Polyethylene Films ◽  
Twin Screw ◽  
Outdoor Weathering

Natural and accelerated weatherings were studied to inspect the effect of antioxidants to protect low-density polyethylene (LDPE) films for commercial application as greenhouse covering materials in Saudi Arabia. In this investigation, six different formulations of LDPE film with incorporation of antioxidants were prepared and compared with neat LDPE. The samples were extruded and blown into a film using twin-screw extruder and film blowing machine. The LDPE films were exposed for outdoor weathering in Riyadh during the period of 90 days (mid of June to mid of September) while the accelerated tests were performed by Weather-Ometer. The film having 0.2 wt% Alkanox-240 (AN-0.2) stabilizers showed the highest tensile strength among all samples during natural and 100-hour accelerated weathering (10.9 MPa and 21.8 MPa, resp.). The best elongation at break was witnessed in 0.2% Good-rite antioxidants which were 64% in natural weathering; however, 0.5% Good-rite antioxidants showed 232% in accelerated weathering. The film having 0.5 wt% Good-rite 3114 (GR-0.5) antioxidant could withstand 70 days during natural exposure before the tensile strength values were reduced to 2/3rd of the initial. The present study suggested that the addition of antioxidants Good-rite, Anox, and Alkanox can improve the mechanical strength, film’s life, effectiveness, and stability and they are suitable to be incorporated in LDPE for commercial greenhouse films.

Study on Anti-Fog Films of Polyethylene Modified with Inorganic Micrometer Diatomite

2012 ◽  
Vol 200 ◽  
pp. 347-350
Author(s):  
Wei He ◽  
Qing Hong Fang ◽  
Wei Lin ◽  
A.S. Luyt ◽  
Tie Jun Ge
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Fourier Transform ◽  
Surface Treatment ◽  
Fourier Transform Infrared ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Elongation At Break ◽  
Treatment Agent ◽  
Infrared Spectrometer

Anti-fog films of low density polyethylene (LDPE) modified with micrometer diatomite were prepared by a process of blow molding. Through examination of antifogging property of the film added the anti-fog agents, the modification effectiveness of inorganic micrometer diatomite and the influence of different treating agents were studied with Fourier transform infrared spectrometer (FTIR), mechanical properties, and antifogging performances. The results indicate that the anti-fog property of the film can be improved by premixing inorganic micrometer diatomite with the anti-fog agents; the film modified by inorganic micrometer diatomite added surface treatment agent has obviously effectiveness anti-fog properties than that the films modified only by the anti-fog agents. Addition of polyacrylamide can make the anti-fog durability of the films modified by inorganic micrometer diatomite be further prolonged. It was observed that the tensile strength does not show any decrease, however, elongation at break show a massive decreased.

scholarly journals Development of technology for producing biodegradable hybrid composites based on polyethylene, starch, and monoglycerides

2021 ◽  
Vol 15 (6) ◽  
pp. 44-55
Author(s):  
I. Yu. Vasilyev ◽  
V. V. Ananyev ◽  
V. V. Kolpakova ◽  
A. S. Sardzhveladze
Keyword(s):  
Tensile Strength ◽  
Mechanical Performance ◽  
Hybrid Composites ◽  
Composite Films ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Elongation At Break ◽  
Biodegradable Composite ◽  
Develop Technology ◽  
Distilled Monoglycerides

Objectives. This work aimed to develop technology to produce biodegradable hybrid composite (BHC) films based on low-density polyethylene (LDPE) 115030-070 and thermoplastic starches (TPS) of various origins (corn, pea, and rice), with distilled monoglycerides as the plasticizer. The properties of the produced BHC films were studied and the optimal native starch : glycerol : monoglycerides ratio is proposed.Methods. TPS and BHC films based on this material were produced from different types of native starches in laboratory extruders (Brabender and MashPlast, Russia), and the extruded melts were subjected to ultrasonic vibrations. The structure and appearance of the BHC films were studied using scanning electron microscopy and rheology. Their biodegradability was assessed by immersing them in biocompost for three months. To evaluate the mechanical performance of the BHC films produced with and without ultrasound, the changes in tensile stress and elongation at break were determined during the biodegradation process.Results. The BHC films had a homogeneous structure, except small agglomerates (non-melted starch grains), which did not reduce their quality. The films with monoglycerides had high tensile strength, which was comparable with low-density polyethylene. After removing samples of the BHC films from the biocompost, their tensile strength decreased by 20%, which shows their biodegradability.Conclusions. The produced biodegradable composite films and the technology used to produce them will be applicable for the packaging industry to reduce environmental impact.

Tensile Properties LLDPE/Soya Spent Powder Blends: Oven Aging

2013 ◽  
Vol 795 ◽  
pp. 429-432
Author(s):  
S.T. Sam ◽  
N.Z. Noriman ◽  
S. Ragunathan ◽  
H. Ismail
Keyword(s):  
Tensile Strength ◽  
Tensile Properties ◽  
Aging Time ◽  
Thermal Aging ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Linear Low Density Polyethylene ◽  
Elongation At Break ◽  
Powder Blends ◽  
Internal Mixer

Linear low-density polyethylene (LLDPE)/soya spent powder blends with different blends ratio were prepared by using internal mixer. Soya spent powder was varied from 5 to 40 wt. The thermal degradability was assessed by subjecting the dumbbell sample to oven aging. Thermal aging was carried out for 5 weeks. The degradability was measured by the periodic change in tensile properties of the blend samples. The tensile strength and elongation at break of the blends reduced as increasing the aging time. The effect of degradation was obvious in higher soya spent powder blends.

Tensile and Morphological Properties of Spear Grass (Imperata cylindrica) Filled Low Density Polyethylene/ Thermoplastic Soya Spent Powder Blends

2014 ◽  
Vol 679 ◽  
pp. 149-153 ◽  
Author(s):  
M.A. Nuradibah ◽  
S.T. Sam ◽  
N.Z. Noimam ◽  
Hanafi Ismail
Keyword(s):  
Tensile Strength ◽  
Morphological Properties ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Elongation At Break ◽  
Degradable Polymer ◽  
Powder Blends ◽  
Sem Micrograph

This study investigate about the tensile and morphological properties of degradable polymer produce from low density polyethylene/ thermoplastic soya spent powder filled spear grass loading varied from 0-3 wt %. Meanwhile, ratio of LDPE/ TSSP which is 95:5 was used as matrix in this composite. The tensile strength increased up to addition of 1.5 wt% spear grass and decreased when 3 wt% spear grass was added. SEM micrograph showed fibrils formation for sample with 1.5 wt% spear grass as it has the highest elongation at break compared to 1 wt% and 3 wt % spear grass.

Characterization of Linear Low Density Polyethylene/Rambutan Peels Flour Blends: Effect of Loading Content

2016 ◽  
Vol 673 ◽  
pp. 171-179 ◽  
Author(s):  
A. Ainatun Nadhirah ◽  
S.T. Sam ◽  
N.Z. Noriman ◽  
Mohd Mustafa Al Bakri Abdullah ◽  
Mohd Firdaus Omar ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Tensile Properties ◽  
Testing Machine ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Linear Low Density Polyethylene ◽  
Screw Extruder ◽  
Twin Screw ◽  
Flour Blends

The effect of rambutan peels flour (RPF) content on the tensile properties of linear low density polyethylene filled with rambutan peel flour was studied. RPF was melt blended with linear low–density polyethylene (LLDPE). LLDPE/RPF blends were prepared by using twin screw extruder at 150°C with the flour content ranged from 0 to 25 wt%. The tensile properties were tested by using a universal testing machine (UTM) according to ASTM D638. The highest tensile strength was pure LLDPE meanwhile the tensile strength LLDPE/RPF decreased gradually with the addition of rambutan peels flour. Young’s modulus of rambutan peels flour filled LLDPE increased with increasing fiber loading. The crystallinity of the blends was significantly reduced with increasing RPF content. Instead, the water absorption increased with the addition of RPF content.

Effect of Poly(Methyl Methacrylate) (PMMA) on Tensile Properties and Spectroscopy Infrared (FTIR) Characteristics of LDPE/WHF Composites

2015 ◽  
Vol 815 ◽  
pp. 101-105
Author(s):  
Soo Jin Tan ◽  
A.G. Supri ◽  
K.L. Foo ◽  
A.M.M. Al Bakri ◽  
Y.M. Liew ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Methyl Methacrylate ◽  
Tensile Properties ◽  
Water Hyacinth ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Rotor Speed ◽  
Elongation At Break ◽  
Fiber Loading ◽  
Blade Mixer

In this work, the effect of PMMA in low density polyethylene/water hyacinth fibers composites were prepared and characterized in terms of tensile properties and FTIR characteristics. Water hyacinth fibers (WHF) were incorporated into the LDPE matrix with different fiber loading. LDPE/WHF and LDPE/WHFPMMAcomposites were prepared with Z-blade mixer at 180 °C with rotor speed of 50 rpm. The PMMA modified WHF increased the tensile strength and Young’s modulus while reduced the elongation at break of LDPE/WHFPMMAcomposites in comparison with LDPE/WHF composites. The absorption peak at 1736.28 cm-1indicated the presence of ester carbonyl group (C=O) in LDPE/WHFPMMAcomposites.

Properties of kapok husk-filled linear low-density polyethylene ecocomposites

2016 ◽  
Vol 29 (12) ◽  
pp. 1641-1655 ◽  
Author(s):  
Koay Seong Chun ◽  
Salmah Husseinsyah ◽  
Nurul Fatin Syazwani
Keyword(s):  
Tensile Strength ◽  
Water Absorption ◽  
Coupling Agent ◽  
Tensile Modulus ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Linear Low Density Polyethylene ◽  
Elongation At Break ◽  
Ester Linkage ◽  
Natural Filler

This research focuses on utilization of kapok husk (KH) as a natural filler in linear low-density polyethylene (LLDPE) ecocomposites. The effect of KH content and coupling agent on tensile properties, thermal properties, water absorption behavior, and morphology of ecocomposites were studied. The addition of KH had increased tensile modulus and water absorption of ecocomposites, whereas tensile strength and elongation at break decreased. However, the polyethylene-grafted acrylic acid (PEAA) was used as a polymeric-coupling agent to enhance the properties of LLDPE/KH ecocomposites. The incorporation of PEAA improved the tensile strength, tensile modulus, crystallinity, and thermal stability as well as reduced the water absorption of LLDPE/KH ecocomposites. The improvement of those properties was caused by the enhanced interfacial bonding, which was evidenced by scanning electron microscopy. The Fourier transmission infrared spectra also confirmed the presence of ester linkage between PEAA and KH.

Electron-beam irradiation of low density polyethylene/ethylene vinyl acetate blends

2013 ◽  
Vol 33 (2) ◽  
pp. 149-161 ◽  
Author(s):  
Maziyar Sabet ◽  
Azman Hassan ◽  
Chantara Thevy Ratnam
Keyword(s):  
Tensile Strength ◽  
Electron Beam ◽  
Vinyl Acetate ◽  
Electron Beam Irradiation ◽  
Ethylene Vinyl Acetate ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Beam Irradiation ◽  
Elongation At Break ◽  
Gel Content

Abstract In this work, the properties of electron-beam irradiated low density polyethylene (LDPE), ethylene vinyl acetate (EVA) and blends were investigated. EVA addition had an enhancement effect on crosslinking of irradiated LDPE/EVA blends. The measured gel content increase of the blends and the improvement of thermal elongation, tensile strength, elongation at break, thermal aging and heat deformation, have confirmed the positive effects of electron-beam irradiation on the blend properties. The crystallinity of the blends decreased with irradiation. The gel content and hot set tests showed that the degree of crosslinking in the amorphous regions was dependent on the dose and blend composition. Increasing the EVA content resulted in tighter network structures. A significant improvement in the tensile strength of the neat EVA samples was obtained upon electron-beam irradiation up to 210 kGy. The irradiated LDPE/EVA blends showed improved tensile strength and elongation at break, when compared to LDPE. The enhanced irradiation crosslinking of the LDPE/EVA blends was proportional to the good compatibility and the increasing degree of the amorphous region’s content of the LDPE/EVA blends. The possible degradation mechanism of LDPE/EVA blends was discussed quantitatively with a novel method step analysis process of irradiated LDPE/EVA blends in the thermal gravimetric analysis (TGA) technique. It was found, with measuring thermal conductivity (k) and specific heat capacity (Cp) of the blends, that the k values of the LDPE samples at a prescribed temperature range decreased with increasing irradiation. An increase in the crystallinity led to an increase in the k values and a decrease in the Cp values of the LDPE samples. Irradiation below 150 kGy decreased the Cp (at 40°C) and k in average values, whereas increasing the EVA made enhanced the Cp and k values of LDPE/EVA blends at each irradiation. The surface resistance and volume resistivity (VR) of the blends reached a maximum at a 170 kGy irradiation and 30 wt% of EVA. Increasing the amount of EVA contents resulted in enhancement of the dielectric loss factor for the irradiated blends.

scholarly journals EFFECTS OF NaOH MODIFICATION ON THE MECHANICAL PROPERTIES OF BAOBAB POD FIBER REINFORCED LDPE COMPOSITES

2016 ◽  
Vol 36 (1) ◽  
pp. 87-95
Author(s):  
U Shehu ◽  
MT Isa ◽  
BO Aderemi ◽  
TK Bello
Keyword(s):  
Tensile Strength ◽  
Water Absorption ◽  
Natural Fiber ◽  
Fiber Composite ◽  
Natural Fibers ◽  
Hydraulic Press ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Fiber Reinforced ◽  
Elongation At Break

In order to improve properties of natural fibers as reinforcement, different treatment methods have being adopted by researchers. However, the use of sodium hydroxide (NaOH) for the treatment of baobab pod fiber as reinforcement in low density polyethylene is sparsely reported. Therefore, this study, investigated the effect of 2 wt%, 4 wt% 6 wt%, 8 wt% and 10 wt%  concentration of NaOH on baobab pod fibers as reinforcement for low density polyethylene (LDPE). Two roll mill machine and hydraulic press at a pressure of 10 kN and temperature of 120oC aided the production of the composite. FT-IR was used to analyze the functional groups of the treated and un-treated fibers. The result showed the disappearance of the peak 1550 cm-1 corresponding to lignin after modification. Further, the composites were characterized for the following tensile strength (TS), modulus of elasticity (MOE), elongation at break, impact strength and water absorption. Preliminary studies on the effect of loading of the unmodified baobab fiber in the LDPE matrix showed desirable properties at 10 wt%, where fiber content was in the range of 5 wt% to 30 wt% at interval of 5 wt%. The composite produced from the 8 wt% NaOH modified fiber had the highest tensile strength, MOE, elongation at break. At this modification level, the tensile strength, MOE and elongation at break were about 75.48%, 92.18% and 28% respectively higher than the composite produced from unmodified fiber. Composite produced with 10 wt% NaOH modified fiber exhibited least water absorption of 1.80%, which was 50% lower than unmodified. These showed that the modification of the fiber improved the composite properties. These properties compared favorably with some reported properties for natural fiber reinforced polymer composites. http://dx.doi.org/10.4314/njt.v36i1.12

Tensile Properties of Linear Low Density Polyethylene (LLDPE)/ Recycled Acrylonitrile Butadiene Rubber (NBRr)/ Rice Husk Powder (RHP) Composites

2015 ◽  
Vol 754-755 ◽  
pp. 210-214 ◽  
Author(s):  
Ragunathan Santiagoo ◽  
Sam Sung Ting ◽  
Hanafi Ismail ◽  
Mastura Jaafar
Keyword(s):  
Tensile Strength ◽  
Tensile Properties ◽  
Rice Husk ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Butadiene Rubber ◽  
Linear Low Density Polyethylene ◽  
Melt Mixing ◽  
Elongation At Break ◽  
Acrylonitrile Butadiene Rubber

The compatibilizer effect of ENR-50 on the tensile properties and morphology of linear low density polyethylene (LLDPE)/ recycled acrylonitrile butadiene rubber (NBRr)/ rice husk powder (RHP) composites has been studied. The RHP size utilize in this work is 150 – 300 μm. LLDPE/NBRr/RHP composites were prepared by melt mixing technique at 180 °C for 9 minutes at 50 rpm rotor speed using heated two roll mill. The series of composites investigated were 100/0/5, 80/20/5, 70/30/5, 60/40/5, 50/50/5, and 40/60/5. The composites were analysed by using tensile test and morphology examination. The result showed that the tensile strength of composite was decreased with the increasing of recycled acrylonitrile butadiene rubber (NBRr) content while elongation at break (Eb) were increased. However, the tensile strength and elongation at break result for composites with ENR-50 as compatibilizer showed higher values. The morphological finding supports the tensile properties which indicate better interaction between the RHP filler and LLDPE/NBRr matrix in the presence of ENR-50 compatibilizer.

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