scholarly journals Different Surfactants-Assisted Hydrothermal Fabrication and Photocatalytic Properties of Bi2MoO6for Methylene Blue Degradation under Simulated Sunlight Irradiation

2014 ◽  
Vol 2014 ◽  
pp. 1-5 ◽  
Author(s):  
Wenfeng Guo ◽  
Heping Li ◽  
Haisheng Ma ◽  
Weixiu Teng

Bi2MoO6single-crystallites were synthesized by a simple hydrothermal method in the presence of surfactant sodium dodecyl sulfate (SDS), polyvinyl pyrrolidone (PVP), or cetyl trimethyl ammonium bromide (CTAB). The samples were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), and ultraviolet-visible diffuse reflectance spectra (UV-vis DRS) techniques. The photocatalytic activities of the as-fabricated Bi2MoO6samples were measured for the degradation of methylene blue (MB) under the Xe light illumination. It is shown that the introduction of surfactant have a crucial influence on the size and morphology of the Bi2MoO6product. Among the as-fabricated Bi2MoO6samples, the ones derived hydrothermally with CTAB showed outstanding photocatalytic activities for the addressed reaction under simulated sunlight irradiation, attributed to the ultrafine nanocrystals and the higher surface areas.

2011 ◽  
Vol 71-78 ◽  
pp. 122-125 ◽  
Author(s):  
Ling Li Song ◽  
Ren Yuan Zhang ◽  
Ling Bo Mao ◽  
Wen Jie Zhu ◽  
Miao Yan Zheng

The influences of dispersant type, supersonic time and concentration on the dispersion property of the nano-aluminium powders in glycol water were systematically studied by using Sodium dodecyl sulfate (SDS),cetyl trimethyl ammonium bromide (CTAB) and sodium hexa metah posphate(SHMP)as dispersants. During the first stage of the experiments, influences of dispersant type and ultrasonic time with these dispersants were evaluated. The next stage of the study was focused on SHMP concentration. The influence of SHMP concentration was assessed. The results show that with the increasing of ultrasonic time, the dispersion property of nano-aluminum powders first increases and then decreases, and SHMP is the best one. The excellent dispersing condition on the dispersion property of nano-aluminium is: 5g/L SHMP and 50 min ultrasonic vibration.


2016 ◽  
Vol 40 (12) ◽  
pp. 10219-10226 ◽  
Author(s):  
Sheng-Ping Guo ◽  
Yang Chi ◽  
Jian-Ping Zou ◽  
Huai-Guo Xue

Novel crystalline α-EuZrS3 shows Eu2+ photoluminescence and is photocatalytically active towards the decomposition of methylene blue under visible light or simulated sunlight irradiation.


2009 ◽  
Vol 5 ◽  
pp. 135-142
Author(s):  
Jorge A. García-Macedo ◽  
A. Franco ◽  
Guadalupe Valverde-Aguilar ◽  
M.A. Ríos-Enríquez

The kinetics of the orientation of Disperse Red 1 (DR1) molecules embedded in nanostructured Polymethylmetacrylate (PMMA) films was studied under the effect of an intense constant electric poling field. The changes in the orientation distribution of the DR1 molecules were followed by Second Harmonic Generation (SHG) measurements. The SHG signal was recorded as function of time at three different temperatures. We focused on both, the signal increases under the presence of the poling field and the signal decays without the poling field. The studied PMMA films were nanostructured by the incorporation of ionic surfactants as the Sodium Dodecyl Sulfate (SDS) and the Cetyl Trimethyl Ammonium Bromide (CTAB) during their preparation. The kinds of nanostructures obtained in the films were determined by means of X-ray diffraction (XRD) measurements. Substantial differences in signal intensity and in growth and decay rates between amorphous and nanostructured films were found.


2011 ◽  
Vol 361-363 ◽  
pp. 1946-1949
Author(s):  
Yi Fei Li ◽  
Tian Wei Qian ◽  
Li Juan Huo

In this paper,the effect of surfactant to the infiltration and the change of saturated hydraulic conductivity was studied by GUELPH PERMEAMETER. We investigated effects on soil infiltration by three representative surfactants.The results show that the existing of sodium dodecyl benzene sulfonate (SDBS), cetyl trimethyl ammonium bromide bromide (CTAB) and polyxyethylene fatty alcohol (AEO9) would decrease soil saturated hydraulic conductivity.


2008 ◽  
Vol 273-276 ◽  
pp. 22-27 ◽  
Author(s):  
Ali Shokuhfar ◽  
S. Alibeigi ◽  
Mohammad Reza Vaezi ◽  
Sayed Khatiboleslam Sadrnezhaad

Magnetite (Fe3O4) nanoparticles were prepared simply by the reverse co-precipitation method from the solution of ferrous/ferric mixed salt in the presence of cationic surfactant (cetyl trimethyl ammonium bromide, CTAB) and nonionic surfactant (Polyethylene glycol, PEG) in two concentrations. Meanwhile, Fe3O4 nanoparticles without surfactant are also synthesized under the same condition for comparison. In addition via the reverse co-precipitation method, the pH which is an important factor in synthesis of magnetite was controlled at high values easily. The experimental results reveal that addition of surfactants affected on the size and morphology of the nanoparticles based on the X-ray diffraction (XRD) and scanning electron microscope (SEM) characterizations.


2013 ◽  
Vol 2013 ◽  
pp. 1-5 ◽  
Author(s):  
J. F. Dai ◽  
T. Xian ◽  
L. J. Di ◽  
H. Yang

BiFeO3nanoparticles were prepared via a polyacrylamide gel route. BiFeO3-graphene nanocomposites were fabricated by mixing BiFeO3nanoparticles and graphene into absolute ethanol solution followed by thermal drying. The TEM observation demonstrates that the BiFeO3nanoparticles are well anchored onto graphene sheets. The photocatalytic activities of the as-prepared samples were evaluated by the degradation of methyl orange (MO) under simulated sunlight irradiation. Compared to bare BiFeO3nanoparticles, BiFeO3-graphene nanocomposites exhibit enhanced photocatalytic activity. The outstanding photocatalytic performance is mainly ascribed to the efficient transfer of photogenerated electrons from BiFeO3to graphene, thus leading to an increased availability of h+for the photocatalytic reaction. In addition, hydroxyl (·OH) radicals were detected by the photoluminescence technique using terephthalic acid as a probe molecule and are found to be produced on the irradiated BiFeO3and BiFeO3-graphene nanocomposites; in particular, an enhanced yield is observed for the latter.


2018 ◽  
Vol 936 ◽  
pp. 47-52 ◽  
Author(s):  
Chaval Sriwong ◽  
Kittisak Choojun ◽  
Worapol Tejangkura ◽  
Warot Prasanseang

This research aims to investigate photocatalytic activities of titanium dioxide (TiO2) incorporated with reduced graphene oxide (rGO) nanocomposite catalysts. These TiO2-rGO photocatalysts were easily prepared through a direct-mixing of TiO2powder suspended in acidic solution under the different amounts of rGO loading (0.25, 0.50, 0.75 and 1.00 wt%). Then, the obtained TiO2-rGO samples were characterized by a several techniques. The results demonstrated that the crystalline phases of all samples are corresponding to pristine TiO2, whereas the characteristic peaks of rGO in the TiO2-rGO nanocomposites could be observed and also well-confirmed by Raman spectroscopy. TEM results showed that the TiO2nanoparticles were well-combined with rGO nanosheets. Moreover, the photocatalytic activities of all TiO2-rGO photocatalyst samples were evaluated by photodegrading of methylene blue (MB) dye solution under natural sunlight irradiation. The results revealed that all TiO2-rGO nanocatalysts exhibited much higher activity than those of the bare TiO2. The improved photocatalytic activity can be attributed to the presence of rGO nanosheets, leading to the decrease of electron (e-) - hole (h+) recombination of TiO2catalyst, increasing charge transfer rate of electrons and surface-adsorbed amount of MB molecules which enhances the photocatalytic activity.


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