scholarly journals Tunable Band Gap Energy of Mn-Doped ZnO Nanoparticles Using the Coprecipitation Technique

2014 ◽  
Vol 2014 ◽  
pp. 1-6 ◽  
Author(s):  
Tong Ling Tan ◽  
Chin Wei Lai ◽  
Sharifah Bee Abd Hamid

A simple coprecipitation technique was introduced to form manganese (Mn) doped on zinc oxide (ZnO) nanoparticles effectively. Based on our morphological studies, it was revealed that mean particle size was increased while bigger agglomeration of nanoparticles could be observed as the amount of concentration of Mn was increased. Interestingly, it was found that the position of the absorption spectra was shifted towards the lower wavelength (UV region) as correlated with the increasing of Mn dopants concentration into ZnO nanoparticles. This result inferred that optimum content of Mn doped into the ZnO nanoparticles was crucial in controlling the visible/UV-responsive of samples. In the present study, 3 mol% of Mn dopants into the ZnO nanoparticles exhibited the better UV as well as visible light-responsive as compared to the other samples. The main reason might be attributed to the modification of electronic structure of ZnO nanoparticles via lattice doping of Mn ions into the lattice, whereas excessive Mn dopants doped on ZnO nanoparticles caused the strong UV-responsive due to the more 3d orbitals in the valence band.

Coatings ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 882
Author(s):  
Yuechan Li ◽  
Yongli Li ◽  
An Xie

Doping impurity into ZnO is an effective and powerful technique to tailor structures and enhance its optical properties. In this work, Zn1−xMgxO and Zn1−x−yMgxByO nanoparticles (x = 0, 0.1, 0.2, 0.3, 0.4; y = 0, 0.02, 0.04) were synthesized via one-pot method. It shows that the Mg and B dopants has great influence on crystallinity and surface morphology of ZnO nanoparticles, without changing the wurtzite structure of ZnO. The band structure study indicates that the competition of Conductive Band (CB) shift, Burstein–Moss (B-M) shift and Shrinkage effect will cause the band gap energy change in ZnO.


2014 ◽  
Vol 12 (0) ◽  
pp. 283-288 ◽  
Author(s):  
Murugesan Silambarasan ◽  
Shanmugam Saravanan ◽  
Tetsuo Soga

2006 ◽  
Vol 17 (5) ◽  
pp. 1278-1285 ◽  
Author(s):  
O D Jayakumar ◽  
H G Salunke ◽  
R M Kadam ◽  
Manoj Mohapatra ◽  
G Yaswant ◽  
...  

2017 ◽  
Vol 9 (6) ◽  
pp. 483-488 ◽  
Author(s):  
V. Sumithra ◽  
A. Manikandan ◽  
M. Durka ◽  
Saravana Kumar Jaganathan ◽  
A. Dinesh ◽  
...  

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