scholarly journals Modeling and Optimization for Production of Rice Husk Activated Carbon and Adsorption of Phenol

2014 ◽  
Vol 2014 ◽  
pp. 1-10 ◽  
Author(s):  
Y. S. Mohammad ◽  
E. M. Shaibu-Imodagbe ◽  
S. B. Igboro ◽  
A. Giwa ◽  
C. A. Okuofu
Keyword(s):  
Activated Carbon ◽  
Adsorption Capacity ◽  
Removal Efficiency ◽  
Rice Husk ◽  
Adsorption Process ◽  
Operating Conditions ◽  
Optimum Operating ◽  
Process Variables ◽  
Adsorbent Dosage ◽  
Pretreatment Temperature

Modeling of adsorption process establishes mathematical relationship between the interacting process variables and process optimization is important in determining the values of factors for which the response is at maximum. In this paper, response surface methodology was employed for the modeling and optimization of adsorption of phenol onto rice husk activated carbon. Among the action variables considered are activated carbon pretreatment temperature, adsorbent dosage, and initial concentration of phenol, while the response variables are removal efficiency and adsorption capacity. Regression analysis was used to analyze the models developed. The outcome of this research showed that 99.79% and 99.81% of the variations in removal efficiency and adsorption capacity, respectively, are attributed to the three process variables considered, that is, pretreatment temperature, adsorbent dosage, and initial phenol concentration. Therefore, the models can be used to predict the interaction of the process variables. Optimization tests showed that the optimum operating conditions for the adsorption process occurred at initial solute concentration of 40.61 mg/L, pretreatment temperature of 441.46°C, adsorbent dosage 4 g, adsorption capacity of 0.9595 mg/g, and removal efficiency of 97.16%. These optimum operating conditions were experimentally validated.

scholarly journals Removal of aniline from aqueous solutions by activated carbon coated by chitosan

2015 ◽  
Vol 5 (4) ◽  
pp. 610-618 ◽  
Author(s):  
Qian Liu ◽  
Lujie Zhang ◽  
Pan Hu ◽  
Ruihua Huang
Keyword(s):  
Activated Carbon ◽  
Aqueous Solutions ◽  
Ph Value ◽  
Operating Conditions ◽  
Optimum Operating ◽  
Order Kinetic ◽  
Factors Affecting ◽  
Adsorbent Dosage ◽  
Wide Range ◽  
Carbon Coated

In this work, activated carbon (AC) coated by chitosan was synthesized and characterized by Fourier transform infrared spectrophotometer and scanning electron microscope (SEM) techniques. The removal of aniline from aqueous solutions by AC coated by chitosan was investigated. The factors affecting the adsorption of aniline onto AC coated by chitosan, including the ratio of AC to chitosan, adsorbent dosage, pH value of solution, initial aniline concentration, and contact time were evaluated. These results showed that the optimum operating conditions were: the ratio of AC to chitosan = 0.5, adsorbent dosage = 0.2 g, and the adsorption of aniline from aqueous solutions had better removal in the concentration range of 20–50 mg/L. This adsorbent allowed high removal toward aniline in a wide range of pH. The equilibrium time was 100 minutes. The Freundlich model exhibited better correlation of the equilibrium adsorption data. The pseudo-second-order kinetic equation could better describe the kinetic behavior of aniline adsorption.

Improving Porosity of Activated Carbon Nanotubes via Alkali Agents for the Enhancement of Adsorptive Desulfurization Process

2020 ◽  
Vol 1002 ◽  
pp. 423-434 ◽  
Author(s):  
Muayad A. Shihab ◽  
Amer Talal Nawaf ◽  
Shaho A. Mohamedali ◽  
Mazin N. Alsalmaney
Keyword(s):  
Carbon Nanotubes ◽  
Activated Carbon ◽  
Removal Efficiency ◽  
Contact Time ◽  
Sulfur Removal ◽  
Agitation Speed ◽  
Sulfur Compounds ◽  
Operating Conditions ◽  
Organosulfur Compounds ◽  
Adsorbent Dosage

This work was focused on the removal of sulfur compounds via adsorption process from heavy naphtha using alkali agents-activated carbon nanotubes (ACNTs). Commercial CNTs were activated using three alkali agents (KOH, NaOH, and CaCl2) to amend their surfaces for application in the petroleum industry. The characterization of the physicochemical properties of as-received CNTs and CNTs/alkali agents was performed using a scanning electron microscope (SEM), N2 adsorption/desorption isotherm, and Fourier transform infrared spectroscopy (FTIR). The effects of three operating conditions including adsorbent dosage (1-3 g), agitation speed (330-1500 rpm), and contact time (30-70 min) on the removal efficiency of sulfur compounds at constant pressure and temperature were investigated. Studying of the removal efficiency at different operating conditions was adopted to effectively evaluate the surface modifications of adsorbents on the present process. The specific surface areas of the CNTs were found to be increased upon treatment with alkali agents especially KOH and NaOH. SEM images demonstrated the formation of many defects on the CNTs surface due to the strong etching effect of both alkali agents KOH and NaOH. FTIR spectra showed different relative intensities around band 3440 cm-1 for CNTs/KOH and CNTs/NaOH which was potentially attributed to the presence of hydroxyl functional groups. The sulfur removal experiments from heavy naphtha (initially had a sulfur concentration of 350 ppm) showed that the largest sulfur removal efficiency and adsorption capacity were 69.6% and 6.6 mg/g adsorbent respectively and obtained with CNTs/KOH which presented a superior adsorption efficiency over others. The highest sulfur removal efficiency was gained at adsorbent dosage=3 g, agitation speed=1500 rpm, and contact time=70 min. The study of adsorption kinetics demonstrated that the adsorption of organosulfur compounds from heavy naphtha obeyed the pseudo-second order kinetics

scholarly journals Optimasi Adsorpsi Ion Mg2+ pada Fixed Bed Column dengan Menggunakan Response Surface Methodology

REAKTOR ◽  
2017 ◽  
Vol 17 (3) ◽  
pp. 126
Author(s):  
Novi Sylvia ◽  
Meriatna Meriatna ◽  
Fikri Hasfita ◽  
Lukman Hakim
Keyword(s):  
Response Surface Methodology ◽  
Response Surface ◽  
Flow Rate ◽  
Adsorption Process ◽  
Fixed Bed ◽  
Operating Conditions ◽  
Optimum Operating ◽  
Process Variables ◽  
Fixed Bed Column ◽  
Box Behnken Design

Abstract OPTIMIZATION ADSORPTION OF Mg2+ ION ON FIXED BED COLUMN USING RESPONSE SURFACE METHODOLOGY. Modeling of the adsorption process is used to establish the mathematical relationship between the interacting process variables and process optimization. This is important to determine the factor values that produce a maximum response. Adsorption of Mg from groundwater was optimized using response surface methodology based on Box-Behnken design was used to analyze adsorption data. The process was investigated by continuous experiments. Variables included in the process were: bed depths (7.5, 10, and 12.5 cm), time (20, 40, and 60 min), and flow rate (6, 10, and 14 L/min). Regression analysis was used to analyze the developed models. The outcome of this research showed that 72.784% of the variability in removal efficiency is attributed to the three process variables considered, that is, bed depths, time, and flow rate. Optimization tests showed that the optimum operating conditions for the adsorption process occurred at a bed depth of 11.37 cm, time of 55.53 min and flow rate of 6 L/min. Keywords: adsorption; Box-Behnken design; magnesium (Mg2+); optimization  AbstrakPemodelan dari proses adsorpsi digunakan untuk menentukan hubungan matematis antara variabel proses interaksi dan proses optimasi. Hal ini penting untuk menentukan nilai faktor yang menghasilkan respon maksimum. Adsorpsi magnesium (Mg2+) dari air tanah dioptimalkan menggunakan metodologi respon permukaan model Desain Box-Behnken yang digunakan untuk menganalisis data adsorpsi. Percobaan dilakukan secara kontinyu. Variabel yang termasuk dalam proses tersebut adalah: tinggi unggun (7,5, 10 dan 12,5 cm), waktu kontak (20, 40, dan 60 menit), dan laju alir (6, 10, dan 14 L/menit). Analisis regresi digunakan untuk menganalisis model yang dikembangkan. Hasil penelitian menunjukkan bahwa 72,784% efisiensi penyisihan Mg2+ ditentukan oleh tiga variabel proses, yaitu tinggi unggun, waktu kontak, dan laju alir. Hasil optimasi menunjukkan bahwa kondisi operasi optimum untuk proses adsorpsi terjadi pada tinggi unggun 11,37 cm, waktu kontak 55,53 menit dan laju alir 6 L/menit. Kata kunci: adsorpsi; Box-Behnken desain; magnesium (Mg2+); optimasi

scholarly journals STUDI ADSORPSI ZAT WARNA NAPHTHOL YELLOW S PADA LIMBAH CAIR MENGGUNAKAN KARBON AKTIF DARI AMPAS TEBU

Jurnal Kimia ◽  
2019 ◽  
Vol 13 (1) ◽  
pp. 104
Author(s):  
W. P. Utoo1 ◽  
E. Santoso ◽  
G. Yuhaneka ◽  
A. I. Triantini ◽  
M. R. Fatqi ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Adsorption Capacity ◽  
Surface Area ◽  
Contact Time ◽  
Adsorption Process ◽  
Activation Process ◽  
Adsorption Model ◽  
High Adsorption ◽  
Prolonged Contact ◽  
Test Result

The aim of this research is to get activated carbon from sugarcane bagasse with high adsorption capacity to Naphthol Yellow S and to know factors influencing the adsorption capacity. Activated carbon is prepared by incomplete combustion of sugracane bagasse. The resulting carbon is activated with H2SO4 with concentration variation of 0.5; 1.0; 1.5 and 2.0 M and is continued by calcination at 400 °C. The measurement of the surface area of ??activated carbon by the methylene blue method indicates that the activation process successfully extends the surface area of carbon from 31.87 m2/g before activation to 66-72 m2/g after activation. Activated carbon with concentration of 2.0 M H2SO4 showed the highest surface area of ??71.85 m2/g, however, the best adsorption was shown by activated carbon with a concentration of 0.5 M H2SO4 with the adsorption capacity of 83.93%. The adsorption test showed that the best amount of adsorbent was 0.2 g with contact time for 30 minutes. Prolonged contact time can decrease the amount of Naphthol Yellow S adsorbed. The best adsorption test result was shown by sample with activator concentration of 0,5 M, mass of 0,2 g and contact time of 30 min with adsorption capacity 95,81% or amount of dye adsorbed equal to 143,72 mg/g. The adsorption study also showed that the entire Naphthol Yellow S adsorption process followed the Langmuir isothemal adsorption model. Qualitative testing of real batik waste indicates that activated carbon can reduce the dyes waste containing Naphthol Yellow Sexhibited by the color of batik waste which is more faded.  

Characterization of Adsorbents Derived from Palm Fiber Waste and its Potential on Methylene Blue Adsorption

2020 ◽  
Vol 841 ◽  
pp. 273-277
Author(s):  
Ariany Zulkania ◽  
Muhammad Iqbal ◽  
Syamsumarlin
Keyword(s):  
Methylene Blue ◽  
Activated Carbon ◽  
Phosphoric Acid ◽  
Adsorption Capacity ◽  
Adsorption Process ◽  
Methylene Blue Adsorption ◽  
Palm Fiber ◽  
Methylene Blue Removal ◽  
Phosphoric Acid Concentration

In this study, two types of adsorbent including activated carbon and bio-sorbent were produced from Palm fiber wastes (PFW), which were activated by phosphoric acid. The influence of adsorbent type and phosphoric acid concentration on methylene blue adsorption was investigated. The most optimum adsorbent was determined based on adsorption capacity and removal percentage of each adsorbent. The result shows that 9.984 mg/g of adsorption capacity and 99.84% of removal percentage were achieved in 90 minutes’ adsorption, which demonstrates the huge potential of bio-sorbent and was chosen to be the most optimum adsorbent based on methylene blue removal. The characterization of bio-sorbent was then investigated using FTIR and SEM. FTIR result shows that bio-sorbent contains cellulose which affected the adsorption process while SEM result shows the cleaner pores and surface compared to bio-sorbent before activation.

Coupling ultrafiltration and adsorption onto activated carbon cloth: application to the treatment of highly coloured wastewaters

2000 ◽  
Vol 42 (5-6) ◽  
pp. 355-362 ◽  
Author(s):  
H. Pignon ◽  
C. Brasquet ◽  
P. Le Cloirec
Keyword(s):  
Molecular Weight ◽  
Activated Carbon ◽  
Adsorption Capacity ◽  
Membrane Filtration ◽  
Flow Reactor ◽  
Great Influence ◽  
Dye Adsorption ◽  
Operating Conditions ◽  
Carbon Cloth ◽  
Kinetics And Isotherms

The aim of this work is to evaluate the efficiency of Activated Carbon Cloths (ACCs) as a refining treatment of membrane filtration in the case of effluent streams containing both dyes and suspended solids (SS) or colloids responsible for turbidity. It is divided into two parts. First, dye adsorption experiments are carried out. Kinetics and isotherms enable us to show the feasibility of the adsorption and to study the influence of different operating conditions. The results demonstrate that adsorption is enhanced under acidic conditions, the adsorption capacity being increased by 40% in some cases. Moreover, microscopic characteristics of ACCs have a great influence on the adsorption process: there is a relationship between the adsorbent porosity and the adsorbate molecular weight, the mesoporous adsorbent being more efficious to remove the larger molecular weight dyes. In the case of low molecular weight compounds, the adsorbent with the higher specific surface area provides the greater adsorption capacity. Molecular connectivity indexes were used to confirm the correlation of the molecular structure of the adsorbates with their adsorbability. The second part consists of an estimation of the efficiency of the coupling of ultrafiltration and adsorption onto ACC. Tests performed on a laboratory-scale coupling show that a molecular weight cut-off of 3,000 D gives rise to a 98% removal of turbidity whereas dyes are not much retained. Furthermore, ultrafiltration is useful in improving the adsorption capacities of ACC in a continuous flow reactor (up to 50%).

Adsorption performance of powdered activated carbon-ultrafiltration systems

2001 ◽  
Vol 1 (5-6) ◽  
pp. 13-19 ◽  
Author(s):  
C. Campos ◽  
I. Baudin ◽  
J.M. Lainé
Keyword(s):  
Activated Carbon ◽  
Adsorption Process ◽  
Carbon Particle ◽  
Drinking Water Treatment ◽  
Powdered Activated Carbon ◽  
Operating Conditions ◽  
Adsorption Model ◽  
Filtration Time ◽  
Adsorption Removal ◽  
Carbon Performance

The use of powdered activated carbon in combination with ultrafiltration membranes is attracting increasing interest for the removal of organic compounds in drinking water treatment. The overall adsorption efficiency of this hybrid membrane process strongly depends on the reactor configuration and its operating conditions. Identification of the operating conditions yielding optimum carbon performance can be facilitated by the use of mathematical models describing the adsorption process. In this study, the effect of various designs and operating parameters on the efficiency of the adsorption process is discussed using an adsorption model previously developed and verified by the authors. This discussion includes the effect of filtration time, membrane reactor volume, carbon dosing procedure, carbon dose and carbon particle size on the adsorption removal of two selected micropollutants and dissolved organic matter.

scholarly journals Various Impregnation Methods Used for the Surface Modification of the Adsorbent: A Review

2018 ◽  
Vol 7 (4.7) ◽  
pp. 330 ◽  
Author(s):  
C. R. Girish ◽  
. .
Keyword(s):  
Surface Modification ◽  
Activated Carbon ◽  
Adsorption Capacity ◽  
Surface Properties ◽  
Chemical Treatment ◽  
Water Contamination ◽  
Recent Time ◽  
Operating Conditions ◽  
Physical Chemical

The water contamination is an important crisis which is to be addressed in the recent time. The pollutants present in wastewater are treated by adsorption using activated carbon, which is considered as one of the effective method. The adsorbent has to be modified to improve the adsorption capacity and the surface properties. Various methods such as physical, chemical treatment, impregnation and functionalization techniques are available. Impregnation is one of the effective method carried out for surface modification and to increase the adsorption capacity. Therefore, current study investigates the different impregnation methods used for the surface modification of the adsorbent. It also reviews the various precursors used for adsorbent preparation, the impregnating agent, the operating conditions and the adsorption capacity of the adsorbent.  

scholarly journals Phenol removal from aqueous solution using silica and activated carbon derived from rice husk

2019 ◽  
Vol 14 (4) ◽  
pp. 897-907 ◽  
Author(s):  
Hosseinali Asgharnia ◽  
Hamidreza Nasehinia ◽  
Roohollah Rostami ◽  
Marziah Rahmani ◽  
Seyed Mahmoud Mehdinia
Keyword(s):  
Aqueous Solution ◽  
Activated Carbon ◽  
Water Treatment ◽  
Organic Pollutants ◽  
Rice Husk ◽  
Contact Time ◽  
Adsorption Process ◽  
Phenol Removal ◽  
Initial Concentration ◽  
Maximum Removal

Abstract Phenol and its derivatives are organic pollutants with dangerous effects, such as poisoning, carcinogenicity, mutagenicity, and teratogenicity in humans and other organisms. In this study, the removal of phenol from aqueous solution by adsorption on silica and activated carbon of rice husk was investigated. In this regard, the effects of initial concentration of phenol, pH, dosage of the adsorbents, and contact time on the adsorption of phenol were investigated. The results showed that the maximum removal of phenol by rice husk silica (RHS) and rice husk activated carbon (RHAC) in the initial concentration of 1 mgL−1 phenol, 2 gL−1 adsorbent mass, 120 min contact time, and pH 5 (RHS) or pH 6 (RHAC) were obtained up to 91% and 97.88%, respectively. A significant correlation was also detected between increasing contact times and phenol removal for both adsorbents (p < 0.01). The adsorption process for both of the adsorbents was also more compatible with the Langmuir isotherm. The results of this study showed that RHS and RHAC can be considered as natural and inexpensive adsorbents for water treatment.

scholarly journals Biogas Production from Rice Husk Waste by using Solid State Anaerobic Digestion (SSAD) Method

2018 ◽  
Vol 31 ◽  
pp. 02007 ◽  
Author(s):  
Hashfi Hawali Abdul Matin ◽  
Hadiyanto
Keyword(s):  
Anaerobic Digestion ◽  
Solid State ◽  
Rice Husk ◽  
Alternative Energy ◽  
Biogas Production ◽  
Lignin Content ◽  
Operating Conditions ◽  
Optimum Operating ◽  
Future Research ◽  
Continuous Systems

An effort to obtain alternative energy is still interesting subject to be studied, especially production of biogas from agriculture waste. This paper was an overview of the latest development of biogas researches from rice husk waste by Solid State Anaerobic Digestion (SSAD). The main obstacle of biogas production from rice husk waste was the lignin content which is very difficult degraded by microbes. Various pretreatments have been conducted, either physically, chemically as well as biologically. The SSAD method was an attractive option because of the low water content of rice husk waste. The biogas yield by SSAD method gave more attractive result compared to Liquid Anaerobic Digestion (LAD) method. Various studies were still conducted in batch mode laboratory scale and also has not found optimum operating conditions. Research on a larger scale such as bench and pilot scale with continuous systems will be an increase trend in the future research.

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