scholarly journals N-Formylation of Anilines with Silica Sulfuric Acid under Solvent-Free Conditions

2013 ◽  
Vol 2013 ◽  
pp. 1-6 ◽  
Author(s):  
Davood Habibi ◽  
Payam Rahmani ◽  
Ziba Akbaripanah
Keyword(s):  
Sulfuric Acid ◽  
Formic Acid ◽  
Reaction Times ◽  
Solvent Free ◽  
Secondary Amines ◽  
Silica Sulfuric Acid ◽  
Excellent Yield ◽  
Solvent Free Conditions ◽  
Primary And Secondary Amines

N-formylation of primary and secondary amines was carried out with formic acid in the presence of silica sulfuric acid under solvent-free conditions to give the corresponding formamides in excellent yield and short reaction times.

scholarly journals A Green Solventless Protocol for the Synthesis ofβ-Enaminones andβ-Enamino Esters Using Silica Sulfuric Acid as a Highly Efficient, Heterogeneous and Reusable Catalyst

2010 ◽  
Vol 7 (4) ◽  
pp. 1546-1554 ◽  
Author(s):  
Alireza Hasaninejad ◽  
Abdolkarim Zare ◽  
Mohammad Rez Mohammadizadeh ◽  
Mohsen Shekouhy ◽  
Ahmad Reza Moosavi-Zare
Keyword(s):  
Sulfuric Acid ◽  
Reaction Times ◽  
Recyclable Catalyst ◽  
Solvent Free ◽  
Reusable Catalyst ◽  
Silica Sulfuric Acid ◽  
Dicarbonyl Compounds ◽  
Highly Efficient ◽  
Solvent Free Conditions

Silica sulfuric acid is utilized as a green, highly efficient, heterogeneous and recyclable catalyst for the preparation ofβ-enaminones andβ-enamino esters from amines andβ-dicarbonyl compounds under solvent-free conditions at 80 °C. Using this method, the title compounds are produced in high to excellent yields and in short reaction times.

ChemInform Abstract: Silica Sulfuric Acid Mediated Acylation of Amines with 1,3-Diketones via C-C Bond Cleavage under Solvent-Free Conditions.

ChemInform ◽  
2016 ◽  
Vol 47 (8) ◽  
pp. no-no
Author(s):  
Ruiqiang Guo ◽  
Chuanlei Zhu ◽  
Zhe Sheng ◽  
Yanzhe Li ◽  
Wei Yin ◽  
...  
Keyword(s):  
Sulfuric Acid ◽  
Bond Cleavage ◽  
Solvent Free ◽  
Silica Sulfuric Acid ◽  
Solvent Free Conditions

scholarly journals Silica sulfuric acid: a reusable solid catalyst for one pot synthesis of densely substituted pyrrole-fused isocoumarins under solvent-free conditions

2013 ◽  
Vol 9 ◽  
pp. 2344-2353 ◽  
Author(s):  
Sudipta Pathak ◽  
Kamalesh Debnath ◽  
Animesh Pramanik
Keyword(s):  
Sulfuric Acid ◽  
Low Cost ◽  
Solvent Free ◽  
Primary Amines ◽  
Solid Catalyst ◽  
Silica Sulfuric Acid ◽  
Reaction Conditions ◽  
One Pot ◽  
Solvent Free Conditions ◽  
Solvent Free Reaction

A convenient and efficient methodology for the synthesis of densely substituted pyrrole-fused isocoumarins, which employs solid-supported silica sulfuric acid (SSA) as catalyst, has been developed. When the mixture of ninhydrin adducts of acetylacetone/ethyl acetoacetate and primary amines was heated on the solid surface of SSA under solvent-free conditions, the pyrrole-fused isocoumarins were formed in good yields. This synthetic method has several advantages such as the employment of solvent-free reaction conditions without the use of any toxic reagents and metal catalysts, the ease of product isolation, the use of a recyclable catalyst, the low cost, the easy availability of the starting materials, and the excellent yields of products.

Mixed er-NHC/phosphine Pd(ii) complexes and their catalytic activity in the Buchwald–Hartwig reaction under solvent-free conditions

2019 ◽  
Vol 48 (10) ◽  
pp. 3447-3452 ◽  
Author(s):  
Alexandra A. Ageshina ◽  
Grigorii K. Sterligov ◽  
Sergey A. Rzhevskiy ◽  
Maxim A. Topchiy ◽  
Gleb A. Chesnokov ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Solvent Free ◽  
Secondary Amines ◽  
Solvent Free Conditions ◽  
Primary And Secondary Amines

A single catalyst for solvent-free Buchwald–Hartwig amination with both primary and secondary amines.

Silica sulfuric acid as an efficient and recyclable catalyst for the methoxymethylation of alcohols under solvent-free conditions

2006 ◽  
Vol 7 (7) ◽  
pp. 494-498 ◽  
Author(s):  
Khodabakhsh Niknam ◽  
Mohammad Ali Zolfigol ◽  
Ahmad Khorramabadi-Zad ◽  
Reza Zare ◽  
Mohsen Shayegh
Keyword(s):  
Sulfuric Acid ◽  
Recyclable Catalyst ◽  
Solvent Free ◽  
Silica Sulfuric Acid ◽  
Solvent Free Conditions

Rapid and efficient diazotization and diazo coupling reactions on silica sulfuric acid under solvent-free conditions

2009 ◽  
Vol 81 (3) ◽  
pp. 240-244 ◽  
Author(s):  
A ZAREI ◽  
A HAJIPOUR ◽  
L KHAZDOOZ ◽  
B MIRJALILI ◽  
A NAJAFICHERMAHINI
Keyword(s):  
Sulfuric Acid ◽  
Solvent Free ◽  
Coupling Reactions ◽  
Silica Sulfuric Acid ◽  
Solvent Free Conditions ◽  
Diazo Coupling
Sign in / Sign up

Export Citation Format

Share Document