scholarly journals Small Angle X-Ray Scattering Technique for the Particle Size Distribution of Nonporous Nanoparticles

2013 ◽  
Vol 2013 ◽  
pp. 1-11 ◽  
Author(s):  
A. Agbabiaka ◽  
M. Wiltfong ◽  
C. Park

Nanoparticles are small particles whose sizes are less than 100 nm. They have many industrial applications due to their unique properties. Their properties are often size-dependent; thus the accurate determination of nanoparticle sizes is important for quality assurance of nanoparticle production processes. A small angle X-ray scattering technique is a promising method used for characterizing nanoparticle sizes. It has distinctive advantages over other techniques such as electron microscope techniques. In this paper, we review the state-of-the-art methods for determining the sizes of nanoparticles with small angle X-ray experiments and discuss the advantages and limitations of the state-of-the-art methods.

2018 ◽  
Author(s):  
Jorick Maes ◽  
Nicolo Castro ◽  
Kim De Nolf ◽  
Willem Walravens ◽  
Benjamin Abécassis ◽  
...  

<div> <div> <div> <p>The accurate determination of the dimensions of a nano-object is paramount to the de- velopment of nanoscience and technology. Here, we provide procedures for sizing quasi- spherical colloidal nanocrystals (NCs) by means of small-angle x-ray scattering (SAXS). Using PbS NCs as a model system, the protocols outline the extraction of the net NC SAXS pattern by background correction and address the calibration of scattered x-ray intensity to an absolute scale. Different data analysis methods are compared, and we show that they yield nearly identical estimates of the NC diameter in the case of a NC ensemble with a monodisperse and monomodal size distribution. Extending the analysis to PbSe, CdSe </p> </div> </div> <div> <div> <p>and CdS NCs, we provide SAXS calibrated sizing curves, which relate the NC diameter and the NC band-gap energy as determined using absorbance spectroscopy. In compari- son with sizing curves calibrated by means of transmission electron microscopy (TEM), we systematically find that SAXS calibration assigns a larger diameter than TEM calibration to NCs with a given band gap. We attribute this difference to the difficulty of accurately sizing small objects in TEM images. To close, we demonstrate that NC concentrations can be directly extracted from SAXS patterns normalized to an absolute scale, and we show that SAXS-based concentrations agree with concentration estimates based on absorption spectroscopy.</p></div></div></div>


1997 ◽  
Vol 29 (12) ◽  
pp. 1007-1011 ◽  
Author(s):  
T Misra ◽  
J Shukla ◽  
Md N Khan ◽  
D K Bisoyi ◽  
T Patel

2010 ◽  
Vol 28 (2) ◽  
pp. 165-170 ◽  
Author(s):  
Yu-jing Tang ◽  
Zhi-yong Jiang ◽  
Hans-Friedrich Enderle ◽  
Dieter Lilge ◽  
Stephan V. Roth ◽  
...  

2015 ◽  
Vol 49 (8) ◽  
pp. 1052-1056
Author(s):  
M. D. Sharkov ◽  
M. E. Boiko ◽  
A. M. Boiko ◽  
A. V. Bobyl ◽  
S. G. Konnikov

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