scholarly journals Integrated Electrokinetics-Adsorption Remediation of Saline-Sodic Soils: Effects of Voltage Gradient and Contaminant Concentration on Soil Electrical Conductivity

2013 ◽  
Vol 2013 ◽  
pp. 1-6 ◽  
Author(s):  
Mohammed Hussain Essa ◽  
Nuhu Dalhat Mu’azu ◽  
Salihu Lukman ◽  
Alaadin Bukhari
Keyword(s):  
Electrical Conductivity ◽  
Contaminated Soils ◽  
Influential Factors ◽  
Polarity Reversal ◽  
Reversal Rate ◽  
Voltage Gradient ◽  
Contaminant Concentration ◽  
Soil Electrical Conductivity ◽  
Sodic Soils

In this study, an integrated in situ remediation technique which couples electrokinetics with adsorption, using locally produced granular activated carbon from date palm pits in the treatment zones that are installed directly to bracket the contaminated soils at bench-scale, is investigated. Natural saline-sodic clay soil, spiked with contaminant mixture (kerosene, phenol, Cr, Cd, Cu, Zn, Pb, and Hg), was used in this study to investigate the effects of voltage gradient, initial contaminant concentration, and polarity reversal rate on the soil electrical conductivity. Box-Behnken Design (BBD) was used for the experimental design and response surface methodology (RSM) was employed to model, optimize, and interpret the results obtained using Design-Expert version 8 platform. The total number of experiments conducted was 15 with voltage gradient, polarity reversal rate, and initial contaminant concentration as variables. The main target response discussed in this paper is the soil electrical conductivity due to its importance in electrokinetic remediation process. Responses obtained were fitted to quadratic models whoseR2ranges from 84.66% to 99.19% with insignificant lack of fit in each case. Among the investigated factors, voltage gradient and initial contaminant concentration were found to be the most significant influential factors.

scholarly journals Low-Input Estimation of Site-Specific Lime Demand Based on Apparent Soil Electrical Conductivity and In Situ Determined Topsoil pH

Sensors ◽  
2019 ◽  
Vol 19 (23) ◽  
pp. 5280
Author(s):  
Moritz von Cossel ◽  
Harm Druecker ◽  
Eberhard Hartung
Keyword(s):  
Electrical Conductivity ◽  
Field Measurements ◽  
Ex Situ ◽  
Soil Electrical Conductivity ◽  
Standard Equipment ◽  
Site Specific ◽  
Input Estimation ◽  
Low Input ◽  
North Germany

Site-specific liming helps increase efficiency in agricultural production. For adequate determination of the lime demand, a combination of apparent soil electrical conductivity (ECa) and topsoil pH can be used. Here, it was hypothesized that this can also be done at low-input level. Field measurements using the EM38 MK I (Geonics, Canada) were conducted on three experimental sites in north Germany in 2011. The topsoil pH was measured based on two approaches: on the field using a handheld pH meter (Spectrum-Technologies Ltd., Bridgend, UK) with a flat electrode (in situ), and in the lab using standard equipment (ex situ). Both soil ECa (0.4–35.9 mS m−1) and pH (5.13–7.41) were heterogeneously distributed across the sites. The same was true of the lime demand (−1.35–4.18 Mg ha−1). There was a significant correlation between in situ and ex situ determined topsoil pH (r = 0.89; p < 0.0001). This correlation was further improved through non-linear regression (r = 0.92; p < 0.0001). Thus, in situ topsoil pH was found suitable for map-overlay with ECa to determine the site-specific lime demand. Consequently, the hypothesis could be confirmed: The combined use of data from EM38 and handheld pH meters is a promising low-input approach that may help implement site-specific liming in developing countries.

scholarly journals Geochemical Modeling of Trivalent Chromium Migration in Saline-Sodic Soil during Lasagna Process: Impact on Soil Physicochemical Properties

2014 ◽  
Vol 2014 ◽  
pp. 1-20 ◽  
Author(s):  
Salihu Lukman ◽  
Alaadin Bukhari ◽  
Muhammad H. Al-Malack ◽  
Nuhu D. Mu’azu ◽  
Mohammed H. Essa
Keyword(s):  
Physicochemical Properties ◽  
Soil Ph ◽  
Geochemical Modeling ◽  
Buffering Capacity ◽  
Polarity Reversal ◽  
Reversal Rate ◽  
Voltage Gradient ◽  
Sodic Soil ◽  
Geochemical Properties ◽  
And Migration

Trivalent Cr is one of the heavy metals that are difficult to be removed from soil using electrokinetic study because of its geochemical properties. High buffering capacity soil is expected to reduce the mobility of the trivalent Cr and subsequently reduce the remedial efficiency thereby complicating the remediation process. In this study, geochemical modeling and migration of trivalent Cr in saline-sodic soil (high buffering capacity and alkaline) during integrated electrokinetics-adsorption remediation, called the Lasagna process, were investigated. The remedial efficiency of trivalent Cr in addition to the impacts of the Lasagna process on the physicochemical properties of the soil was studied. Box-Behnken design was used to study the interaction effects of voltage gradient, initial contaminant concentration, and polarity reversal rate on the soil pH, electroosmotic volume, soil electrical conductivity, current, and remedial efficiency of trivalent Cr in saline-sodic soil that was artificially spiked with Cr, Cu, Cd, Pb, Hg, phenol, and kerosene. Overall desirability of 0.715 was attained at the following optimal conditions: voltage gradient 0.36 V/cm; polarity reversal rate 17.63 hr; soil pH 10.0. Under these conditions, the expected trivalent Cr remedial efficiency is 64.75 %.

scholarly journals Coupled Electrokinetics-Adsorption Technique for Simultaneous Removal of Heavy Metals and Organics from Saline-Sodic Soil

2013 ◽  
Vol 2013 ◽  
pp. 1-9 ◽  
Author(s):  
Salihu Lukman ◽  
Mohammed Hussain Essa ◽  
Nuhu Dalhat Mu'azu ◽  
Alaadin Bukhari
Keyword(s):  
Heavy Metals ◽  
Contaminated Soils ◽  
Contaminant Removal ◽  
In Situ Remediation ◽  
Sodic Soils ◽  
Sodic Soil ◽  
Mixed Contaminants ◽  
Removal Of Heavy Metals ◽  
Promising Solution

In situ remediation technologies for contaminated soils are faced with significant technical challenges when the contaminated soil has low permeability. Popular traditional technologies are rendered ineffective due to the difficulty encountered in accessing the contaminants as well as when employed in settings where the soil contains mixed contaminants such as petroleum hydrocarbons, heavy metals, and polar organics. In this study, an integrated in situ remediation technique that couples electrokinetics with adsorption, using locally produced granular activated carbon from date palm pits in the treatment zones that are installed directly to bracket the contaminated soils at bench-scale, is investigated. Natural saline-sodic soil, spiked with contaminant mixture (kerosene, phenol, Cr, Cd, Cu, Zn, Pb, and Hg), was used in this study to investigate the efficiency of contaminant removal. For the 21-day period of continuous electrokinetics-adsorption experimental run, efficiency for the removal of Zn, Pb, Cu, Cd, Cr, Hg, phenol, and kerosene was found to reach 26.8, 55.8, 41.0, 34.4, 75.9, 92.49, 100.0, and 49.8%, respectively. The results obtained suggest that integrating adsorption into electrokinetic technology is a promising solution for removal of contaminant mixture from saline-sodic soils.

scholarly journals Spatial and Temporal Variability of Soil Salinity in the Yangtze River Estuary Using Electromagnetic Induction

2021 ◽  
Vol 13 (10) ◽  
pp. 1875
Author(s):  
Wenping Xie ◽  
Jingsong Yang ◽  
Rongjiang Yao ◽  
Xiangping Wang
Keyword(s):  
Electrical Conductivity ◽  
Spatial Distribution ◽  
Soil Salinity ◽  
Yangtze River ◽  
Laboratory Data ◽  
River Estuary ◽  
Yangtze River Estuary ◽  
Soil Electrical Conductivity ◽  
The Yangtze River ◽  
The Yangtze River Estuary

Soil salt-water dynamics in the Yangtze River Estuary (YRE) is complex and soil salinity is an obstacle to regional agricultural production and the ecological environment in the YRE. Runoff into the sea is reduced during the impoundment period as the result of the water-storing process of the Three Gorges Reservoir (TGR) in the upper reaches of the Yangtze River, which causes serious seawater intrusion. Soil salinity is a problem due to shallow and saline groundwater under serious seawater intrusion in the YRE. In this research, we focused on the temporal variation and spatial distribution characteristics of soil salinity in the YRE using geostatistics combined with proximally sensed information obtained by an electromagnetic induction (EM) survey method in typical years under the impoundment of the TGR. The EM survey with proximal sensing method was applied to perform soil salinity survey in field in the Yangtze River Estuary, allowing quick determination and quantitative assessment of spatial and temporal variation of soil salinity from 2006 to 2017. We developed regional soil salinity survey and mapping by coupling limited laboratory data with proximal sensed data obtained from EM. We interpreted the soil electrical conductivity by constructing a linear model between the apparent electrical conductivity data measured by an EM 38 device and the soil electrical conductivity (EC) of soil samples measured in laboratory. Then, soil electrical conductivity was converted to soil salt content (soil salinity g kg−1) through established linear regression model based on the laboratory data of soil salinity and soil EC. Semivariograms of regional soil salinity in the survey years were fitted and ordinary kriging interpolation was applied in interpolation and mapping of regional soil salinity. The cross-validation results showed that the prediction results were acceptable. The soil salinity distribution under different survey years was presented and the area of salt affected soil was calculated using geostatistics method. The results of spatial distribution of soil salinity showed that soil salinity near the riverbanks and coastlines was higher than that of inland. The spatial distribution of groundwater depth and salinity revealed that shallow groundwater and high groundwater salinity influenced the spatial distribution characteristics of soil salinity. Under long-term impoundment of the Three Gorges Reservoir, the variation of soil salinity in different hydrological years was analyzed. Results showed that the area affected by soil salinity gradually increased in different hydrological year types under the impoundment of the TGR.

scholarly journals The Relationship between Soil Electrical Parameters and Compaction of Sandy Clay Loam Soil

Agriculture ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 114
Author(s):  
Katarzyna Pentoś ◽  
Krzysztof Pieczarka ◽  
Kamil Serwata
Keyword(s):  
Electrical Conductivity ◽  
Magnetic Susceptibility ◽  
Precision Agriculture ◽  
Soil Compaction ◽  
Soil Layer ◽  
Soil Parameters ◽  
Soil Electrical Conductivity ◽  
Electrical Parameters ◽  
Management Zones ◽  
Additional Information

Soil spatial variability mapping allows the delimitation of the number of soil samples investigated to describe agricultural areas; it is crucial in precision agriculture. Electrical soil parameters are promising factors for the delimitation of management zones. One of the soil parameters that affects yield is soil compaction. The objective of this work was to indicate electrical parameters useful for the delimitation of management zones connected with soil compaction. For this purpose, the measurement of apparent soil electrical conductivity and magnetic susceptibility was conducted at two depths: 0.5 and 1 m. Soil compaction was measured for a soil layer at 0–0.5 m. Relationships between electrical soil parameters and soil compaction were modelled with the use of two types of neural networks—multilayer perceptron (MLP) and radial basis function (RBF). Better prediction quality was observed for RBF models. It can be stated that in the mathematical model, the apparent soil electrical conductivity affects soil compaction significantly more than magnetic susceptibility. However, magnetic susceptibility gives additional information about soil properties, and therefore, both electrical parameters should be used simultaneously for the delimitation of management zones.

Chemically reduced graphene oxide-coated knitted fabric imparted conductivity and outstanding hydrophobicity

2021 ◽  
pp. 004051752199547
Author(s):  
Min Hou ◽  
Xinghua Hong ◽  
Yanjun Tang ◽  
Zimin Jin ◽  
Chengyan Zhu ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Chemical Reduction ◽  
Knitted Fabric ◽  
Mesh Structure ◽  
Reduced Graphene ◽  
Chemically Reduced Graphene Oxide ◽  
Modified Hummers Method

Functionalized knitted fabric, as a kind of flexible, wearable, and waterproof material capable of conductivity, sensitivity and outstanding hydrophobicity, is valuable for multi-field applications. Herein, the reduced graphene oxide (RGO)-coated knitted fabric (polyester/spandex blended) is prepared, which involves the use of graphite oxide (GO) by modified Hummers method and in-situ chemical reduction with hydrazine hydrate. The treated fabric exhibits a high electrical conductivity (202.09 S/cm) and an outstanding hydrophobicity (140°). The outstanding hydrophobicity is associated with the morphology of the fabric and fiber with reference to pseudo-infiltration. These properties can withstand repeated bending and washing without serious deterioration, maintaining good electrical conductivity (35.70 S/cm) and contact angle (119.39°) after eight standard washing cycles. The material, which has RGO architecture and continuous loop mesh structure, can find wide use in smart garment applications.

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