scholarly journals Dye-Sensitized Solar Cells with Optimal Gel Electrolyte Using the Taguchi Design Method

2013 ◽  
Vol 2013 ◽  
pp. 1-5 ◽  
Author(s):  
Jenn-Kai Tsai ◽  
Wen Dung Hsu ◽  
Tian-Chiuan Wu ◽  
Jia-Song Zhou ◽  
Ji-Lin Li ◽  
...  

The Taguchi method was adopted to determine the optimal gel electrolyte used in dye-sensitized solar cells (DSSCs). Since electrolyte is a very important factor in fabrication of high performance and long-term stability DSSCs, to find the optimal composition of gel electrolyte is desired. In this paper, the common ingredients used in the liquid electrolyte were chosen. The ingredients then mixed with cheap ionic liquids and poly(vinylidenefluoride-co-hexafluoropropylene) (PVDF-HFP) were added to form colloidal electrolyte (gel). The optimal composition of each materials in the gel electrolyte determined by Taguchi method consists of 0.03 M I2, 0.15 M KI, 0.6 M LiI, 0.5 M 4-tertbutylpyridine (TBP), and 10% PVDF-HFP dissolved in the acetonitrile and 3-methoxypropionitrile (MPN) solution with volume ratio of 2 : 1. The short circuit current density of 14.11 mA/cm2, the conversion efficiency (η) of 5.52%, and the lifetime of over 110 days were observed for the dye-sensitized solar cell assembled with optimal gel electrolyte. The lifetime increases 10 times when compared with the conventional dye-sensitized solar cell assembled with liquid electrolyte.

2018 ◽  
Vol 6 (42) ◽  
pp. 11444-11456 ◽  
Author(s):  
Jonnadula Venkata Suman Krishna ◽  
Narra Vamsi Krishna ◽  
Towhid H. Chowdhury ◽  
Suryaprakash Singh ◽  
Idriss Bedja ◽  
...  

We have designed and synthesised four novel porphyrin sensitizers for dye-sensitized solar cell applications and shown power conversion efficiency of 10.5%.


2016 ◽  
Vol 13 (1) ◽  
pp. 14
Author(s):  
Lia Muliani ◽  
Natalia M. Nursam ◽  
Jojo Hidayat

Electrolyte is one of the crucial elements in dye sensitized solar cells (DSC) due to the reduction-oxidation reactions take place in this area and it has the function as the charge transfer medium. An electrolyte solution contains redox couple such as I-/I3 is filled up into a space between the photo-anodes and the counter electrode. Usually, the DSC employs a liquid electrolyte which using organic solution because easy preparation. But it has disadvantage, solvent evaporation occurs and this can decrease the cell performance. One of way to solve this problem is change liquid electrolyte to gel electrolyte. This paper describes fabrication of DSC based on gel electrolyte. Performance of the DSC is compared to the cell which using a liquid electrolyte. The result shows that the energy conversion efficiency of the solar cells based on gel electrolyte was lower than liquid electrolyte solar cell that is 1.51% and 2.23% respectively. Based on life time investigation obtained the performance of gel electrolyte solar cell is much stable than liquid electrolyte solar cell.


2020 ◽  
Vol 8 (38) ◽  
pp. 19991-19999
Author(s):  
Ellie Tanaka ◽  
Neil Robertson

Solid-state dye-sensitized solar cells were obtained by drying a standard I−/I3− liquid-electrolyte cell in ambient conditions.


2018 ◽  
Vol 47 (34) ◽  
pp. 11942-11952 ◽  
Author(s):  
Kitty Y. Chen ◽  
Phil A. Schauer ◽  
Brian O. Patrick ◽  
Curtis P. Berlinguette

Two sets of structurally analogous Co(iii/ii)-based redox mediators were incorporated in the dye-sensitized solar cells and a linear correlation was demonstrated between redox potential and photovoltage.


2015 ◽  
Vol 3 (12) ◽  
pp. 6383-6391 ◽  
Author(s):  
Jia-De Peng ◽  
Chuan-Pei Lee ◽  
D. Velayutham ◽  
V. Suryanarayanan ◽  
Kuo-Chuan Ho

A quasi-solid state dye-sensitized solar cell with the photoanode film of mesoporous TiO2spheres exhibited an efficiency of 6.18% and unfailing stability for 1200 h at 50 °C.


Open Physics ◽  
2017 ◽  
Vol 15 (1) ◽  
pp. 1022-1027 ◽  
Author(s):  
Magdalena M. Szindler ◽  
Marek Szindler ◽  
Leszek A. Dobrzański

AbstractThis article presents the results of a research on the effects and properties of the potassium iodide additive onto the structure of the MEH-PPV polymer material, in its aspect of application in the dye-sensitized solar cell. Changes in MEH-PPV surface morphology were researched through increasing of the potassium iodide content measured by scanning electron microscope. The increased content of potassium iodide also led to increased electrical conductivity measured by the Keithley meter. The electrical properties of the dye-sensitized solar cell were also studied, in which the liquid electrolyte was replaced with a thin layer of polyelectrolyte, based on MEH-PPV and potassium iodide.


2017 ◽  
Vol 41 (13) ◽  
pp. 5605-5612 ◽  
Author(s):  
Radhakrishnan Sivakumar ◽  
Rodrigo Recabarren ◽  
Sekar Ramkumar ◽  
Arumugam Manivel ◽  
Jans Alzate-Morales ◽  
...  

A new type of ruthenium sensitizers, S3 and S4, consisting of carbazole–diazafluorene based bipolar ancillary ligands have been synthesized and characterized for dye sensitized solar cells.


2017 ◽  
Vol 1 (6) ◽  
pp. 1059-1072 ◽  
Author(s):  
N. Prachumrak ◽  
T. Sudyoadsuk ◽  
A. Thangthong ◽  
P. Nalaoh ◽  
S. Jungsuttiwong ◽  
...  

Three new D–π–A dyes containing different numbers of triphenylamine donor substitutions on a π-linker were synthesized for dye-sensitized solar cells.


2015 ◽  
Vol 44 (33) ◽  
pp. 14697-14706 ◽  
Author(s):  
Tejaswi Jella ◽  
Malladi Srikanth ◽  
Rambabu Bolligarla ◽  
Yarasi Soujanya ◽  
Surya Prakash Singh ◽  
...  

Three new heteroleptic Ru(ii) polypyridyl complexes have been designed with a pyridine-benzimidazole functionalized ligand for dye-sensitized solar cells.


RSC Advances ◽  
2015 ◽  
Vol 5 (40) ◽  
pp. 31404-31409 ◽  
Author(s):  
S. Veerapandian ◽  
S. Amudha ◽  
S. Austin Suthanthiraraj ◽  
M. Abdul Rahman ◽  
A. Sultan Nasar

The photovoltaic parameters of dye sensitized solar cells (DSSCs) fabricated with and without fourth generation polyurethane dendrimers have been discussed.


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