scholarly journals Effect of Sugar, Urea, and Molasses and the Influence of Radiation on the Plasticization of Acacia catechu Extract Incorporated Starch/Poly-(Vinyl Alcohol) Based Film

2013 ◽  
Vol 2013 ◽  
pp. 1-10
Author(s):  
Marufa Naznin ◽  
Md. Zainul Abedin

Acacia catechu extract was incorporated in the starch/PVA (60% : 40%) based films (0% to 15%) to the total weight of starch/PVA based film. The tensile strength (TS) of the starch/PVA blend film was 24 MPa whereas the acacia incorporated film shows the highest tensile strength (TS) of 33.8 MPa at 0.5%. Again, 0.5% acacia based film was treated with 10% urea, sugar, and molasses separately both at nonirradiated and irradiated conditions. At the nonirradiated condition molasses incorporated film gives the best results (TS 16 MPa, EB 59%), while sugar incorporated film shows a value of 10 MPa TS and EB of 123% at 200 krad. The films were investigated by FTIR. Thermal studies were carried out by TG/DTA. Water absorption experiment showed a different uptake of water by the different films. Soil degradation test revealed that after 70 days molasses incorporated film (both irradiated and nonirradiated) degrades to 100% into the soil.

2018 ◽  
Vol 21 (2) ◽  
pp. 80-84 ◽  
Author(s):  
Retno Ariadi Lusiana ◽  
Vivi Dia Ahmad Sangkota ◽  
Sri Juari Santosa

Evaluation character of chitosan membrane-succinate / poly vinyl alcohol-poly ethylene glycol (PVA-PEG) were prepared in acetic acid solvent through a phase inversion method has been performed. The study began with the preparation of crosslinked chitosan compounds with succinic acid, followed by preparation into membrane by combining PVA-PEG. Character analysis of the resulting material using FTIR, EDX, TGA, water absorption test, tensile strength, membrane hydrophilicity. The ability of membrane permeation was tested against creatinine. The results showed that the succinate had reacted with chitosan. Chitosan modification through cross link and polymer alloys increases tensile strength and membrane strain of 1.7-2.5 x of pure chitosan membrane. In addition, the modified membrane also has higher water absorption and hydrophilicity values than the unmodified membrane, and this implies the ability of membrane-induced creatinine permeation. Permeable permeation values were 13.8% in chitosan, 24.84% on chitosan-succinate and 25% in chitosan-succinate / PVA-PEG. Chitosan-succinate membranes have the ability to use more than 4x repeated use.


2021 ◽  
Author(s):  
Yanhong Jin ◽  
Yuanyuan Jing ◽  
Wenxin Hu ◽  
Jiaxian Lin ◽  
Yu Cheng ◽  
...  

Abstract Lignin has been used as a sustainable and eco-friendly filler in composite fibers. However, lignin aggregation occurred at high lignin content, which significantly hindered the further enhancement of fiber performance. The incorporation of graphene oxide (GO) enhanced the mechanical properties of the lignin/poly(vinyl alcohol) (PVA) fibers and affected their structure. With the GO content increasing from 0 to 0.2%, the tensile strength of 5% lignin/PVA fibers increased from 491 MPa to 631 MPa, and Young's modulus increased from 5.91 GPa to 6.61 GPa. GO reinforced 30% lignin/PVA fibers also showed the same trend. The tensile strength increased from 455 MPa to 553 MPa, and Young's modulus increased from 5.39 GPa to 7 GPa. The best mechanical performance was observed in PVA fibers containing 5% lignin and 0.2% GO, which had an average tensile strength of 631 MPa and a Young’s modulus of 6.61 GPa. The toughness values of these fibers are between 9.9-15.6 J/g, and the fibrillar and ductile fracture microstructure were observed. Structure analysis of fibers showed that GO reinforced 5% lignin/PVA fibers had higher crystallinity, and evidence of hydrogen bonding among GO, lignin, and PVA in the gel fibers was revealed. Further, water resistance and swelling behavior of composite PVA fibers were studied to further evidence the structure change of composite fibers.


2021 ◽  
pp. 002199832110417
Author(s):  
Wei Chen ◽  
Yifan Wang ◽  
Kun Zhang ◽  
Fujun Xu

Carbon nanotube (CNT) fiber/yarn reinforced composites are considered as a new generation of advanced materials for applications in aerospace and space industry. In this study, two types of CNT composite yarns were produced by twisting CNT films and infiltrating with thermoset epoxy (EP) and thermoplastic poly vinyl alcohol (PVA) resins. The tensile strength of CNT/PVA and CNT/EP composite yarn was 409.91 MPa and 206.87 MPa, much higher than that of pure CNT yarn (129.94 MPa). After mono-cryogenic condition, the mechanical and electrical properties of CNT/EP and CNT/PVA composite yarns were both enhanced due to the structure reorder of the CNT bundles and improvement of interfacial bonding. However, after 60 times cyclic-cryogenic conditions, CNT/EP composite yarn showed a ∼10% degradation of tensile strength; while CNT/PVA composite yarn exhibited 6% increment. This study provides fundamental data of the CNT reinforced thermoset and thermoplastic composite yarns for their practical applications in cryogenic environment.


2014 ◽  
Vol 968 ◽  
pp. 80-83
Author(s):  
Chuan Bao Wu ◽  
Bo Qiao

A novel kind of environmentally friendly composite materials containing upper part of rice straw segments (URSS), poly (vinyl alcohol) (PVA) and waste paper (WP) were prepared by hot-pressing at 140°C for 10 min. The tensile strength, tensile elongation and hardness of composites were measured. Results showed that the tensile strength and the strength at tensile break of the composites first increased and then decreased with increasing PVA content. Tensile strength was higher than the strength at tensile break at different PVA contents, indicating that URSS/PVA/WP composite materials had certain toughness. Otherwise, URSS/PVA/WP composite materials had higher tensile strength than URSS/PVA composites. The tensile strengths of them were respectively 9.25 MPa and 3.9 MPa when prepared at PVA content of 40%. The hardness of composites lay between 90 and 96. Negligible difference exists in every composite.


2014 ◽  
Vol 881-883 ◽  
pp. 1171-1174
Author(s):  
Chuan Bao Wu

The effect of season factor on the performances of poly (vinyl alcohol)/rice straw (PVA/RS) composites prepared by hot-pressing was studied. Two forms of RS, including shortcut RS and RS wires, were used to prepare composite. For PVA/ shortcut RS composites, samples of winter showed higher tensile strength and strength at tensile fracture at different PVA contents than that of summer. When PVA content is 50%, tensile strength of winter sample is 136% higher than that of summer sample and strength at tensile fracture of winter sample is 320% higher than that of summer sample. In addition, samples of winter showed lower tensile stretch and higher hardness at different PVA contents than that of summer. For PVA/RS wire composites, the comparison results are similar. These indicated that season is an important factor for preparing plant based composite with PVA as adhesive.


2011 ◽  
Vol 45 (11) ◽  
pp. 1201-1207 ◽  
Author(s):  
Toh Wen Yee ◽  
Lai Jau Choy ◽  
Wan Aizan Wan Abdul Rahman

A series of blends of sago pith waste (SPW) and poly(vinyl alcohol) (PVA) were prepared. Mechanical and water absorption properties of the composites have been investigated. In this study, variable amounts of plasticized SPW (pSPW) and PVA (pPVA) were processed in the presence of glycerol as plasticizers. Composites were compression molded and evaluated. The addition of pSPW reduced the tensile properties of the composites, lowering the elongation and increasing Young’s modulus. The reduction in mechanical strength with the addition of pSPW was a general phenomenon due to the poor interfacial adhesion between the pPVA and Pspw, which can be proved by the scanning electron microscope observations. The percentage of water absorbed of the pPVA/pSPW biocomposites was higher than either the pPVA or pSPW alone while pSPW showed better water resistance compared to pPVA because of the restricted mobility exerted by the cellulose fibers. The incorporation of SPW into PVA decreased both the mechanical and water absorption properties.


2014 ◽  
Vol 525 ◽  
pp. 166-169 ◽  
Author(s):  
Chuan Bao Wu ◽  
Yang Bo

A series of such composites of poly (vinyl alcohol) and short-cut rice straw were prepared by hot-pressing method at different water medium amounts. And the effects of medium amount on the strength, elongation and hardness of composites were studied. Results indicate tensile strength of composite prepared with 5 mL medium is 119% higher than that with 10 mL medium at formula of 18 g rice straw and 12 g poly (vinyl alcohol). And this kind of strength difference is 98% higher at formula of 15 g rice straw and 15 g poly (vinyl alcohol). Elongation at break is 17.85% when 5 mL medium, 12 g poly (vinyl alcohol) and 18 g short-cut rice straw were used. However, it reaches 21.46% when 10 mL medium was used. The hardness fluctuation range shows no difference when preparation conditions were changed. But samples prepared with 5 mL medium roughly show higher hardness than that prepared with 10 mL medium.


2011 ◽  
Vol 287-290 ◽  
pp. 302-305
Author(s):  
Xi Ping Gao ◽  
Ke Yong Tang ◽  
Yu Qing Zhang

The mechanical properties, swelling, solubility, and optical properties of composite films with poly(vinyl alcohol) (PVA) and gelatin were studied. With increasing the PVA content in the composite films, the tensile strength (TS) and elongation at break (EB) of the films increase. The swelling and solubility are different with different gelatin/PVA ratios, with the lowest at 1:5.


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