scholarly journals Mechanistic Study of Adsorption of Acid Orange-7 over Aluminum Oxide Nanoparticles

2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
Ekta Khosla ◽  
Satindar Kaur ◽  
Pragnesh N. Dave
Keyword(s):  
Aluminum Oxide ◽  
Surface Area ◽  
Nano Particles ◽  
Effluent Treatment ◽  
Area Measurement ◽  
Oxide Nanoparticles ◽  
Order Kinetic ◽  
Acid Orange 7 ◽  
Aluminum Oxide Nanoparticles ◽  
Acid Orange

The adsorption behavior of acid orange-7 (AO-7) on aluminum oxide nanoparticles (ANP) generated by sol-gel method has been investigated to understand the physicochemical process involved and to explore the potential use of nano particles in textile effluent treatment and management. The results revealed that ANP can remove AO-7 dye up to 97.6 mg/g at 303 K. The adsorption process is found to be pH dependent and the optimum pH obtained is 2.0. The equilibrium was established in 1 h. Langmuir, Freundlich, and Temkin Isotherm models were applied on the system. Scanning electron microscopic analysis reveals eye-catching nanoporous morphology of the material. The results of FTIR spectroscopy reveal that the process is electrostatic complexation mechanism driven. XRD studies revealed nanocrystalline structure of ANP. BET surface area measurement suggests high pore volume and surface area of adsorbent. The kinetic measurements suggest pseudo-second-order kinetic processes. The thermodynamic measurements suggest that all processes are endothermic accompanied with negative ΔG° and positive ΔS°, ΔH°.

Preparation of cationic waste paper and its application in poisonous dye removal

2013 ◽  
Vol 67 (11) ◽  
pp. 2560-2567 ◽  
Author(s):  
Fan Yang ◽  
Xiaojie Song ◽  
Lifeng Yan
Keyword(s):  
Low Cost ◽  
Aqueous Suspension ◽  
Order Kinetic ◽  
Acid Orange 7 ◽  
Anionic Dyes ◽  
Experimental Conditions ◽  
Adsorption Models ◽  
Acid Orange ◽  
Initial Ph ◽  
Pseudo Second Order

Cationic paper was prepared by reaction of paper with 2,3-epoxypropyltrimethylammonium chloride in aqueous suspension, and tested as low-cost adsorbent for wastewater treatment. The experimental results revealed that anionic dyes (Acid Orange 7, Acid Red 18, and Acid Blue 92) were adsorbed on the cationic paper nicely. The maximum amount of dye Acid Orange 7 adsorbed on cationic paper was 337.2 mg/g in experimental conditions. The effects of initial dye concentration, temperature, and initial pH of dye solution on adsorption capacity of cationic paper were studied. The pseudo-first-order and pseudo-second-order kinetic models were applied to describe the kinetic data. The Freundlich and Langmuir adsorption models were used to describe adsorption equilibrium. The thermodynamic data indicated that the adsorption process of dye on cationic paper occurred spontaneously.

Slip velocity and temperature jump of a non-Newtonian nanofluid, aqueous solution of carboxy-methyl cellulose/aluminum oxide nanoparticles, through a microtube

2019 ◽  
Vol 29 (5) ◽  
pp. 1606-1628 ◽  
Author(s):  
Marjan Goodarzi ◽  
Saeed Javid ◽  
Ali Sajadifar ◽  
Mehdi Nojoomizadeh ◽  
Seyed Hossein Motaharipour ◽  
...  
Keyword(s):  
Heat Transfer ◽  
Aqueous Solution ◽  
Aluminum Oxide ◽  
Temperature Jump ◽  
Methyl Cellulose ◽  
Oxide Nanoparticles ◽  
Carboxy Methyl Cellulose ◽  
Aluminum Oxide Nanoparticles ◽  
Content Type ◽  
Carboxy Methyl

Purpose With respect to two new subjects, i.e. nanofluids and microchannels, in heat transfer systems and modern techniques used for building them, this paper aims to study on effect of using aluminum oxide nanoparticles in non-Newtonian fluid of aqueous solution of carboxy-methyl cellulose in microtube and through application of different slip coefficients to achieve various qualities on surface of microtube. Design/methodology/approach Simultaneously, the effect of presence of nanoparticles and phenomenon of slip and temperature jump has been explored in non-Newtonian nanofluid in this essay. The assumption of homogeneity of nanofluid and fixed temperature of wall in microtube has been used in modeling processes. Findings The results have been presented as diagrams of velocity, temperature and Nusselt Number and the investigations have indicated that addition of nanoparticles to the base fluid and increase in microtube slip coefficient might improve rate of heat transfer in microtube. Originality/value The flow of non-Newtonian nanofluid of aqueous solution of carboxy methyl cellulose-aluminum oxide has been determined in a microtube for the first time.

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