scholarly journals A Ternary Catalytic System for the Room Temperature Suzuki-Miyaura Reaction in Water

2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
Aires da Conceição Silva ◽  
Jaqueline Dias Senra ◽  
Andréa Luzia Ferreira de Souza ◽  
Luiz Fernando Brum Malta

The formation of Pd(0) in the absence of any classical reducing agent in a medium containing Mg2+/Al3+layered double hydroxide (LDH) andN,N-dimethylformamide was evidenced. XRD analysis showed the presence of crystalline phases of palladium in the Pd/LDH composite. Suzuki-Miyaura reactions in aqueous medium were carried out at room temperature, and good yields were obtained with bromoarenes and iodoarenes using the ternary system LDH-Pd-CD (cyclodextrin) as catalyst.

2020 ◽  
Vol 6 ◽  
pp. 248-254
Author(s):  
Seong Hyun Kim ◽  
Yoo Sei Park ◽  
Chiho Kim ◽  
Il Yeong Kwon ◽  
Jooyoung Lee ◽  
...  

2013 ◽  
Vol 2013 ◽  
pp. 1-6 ◽  
Author(s):  
Aires da Conceição Silva ◽  
Andréa Luzia Ferreira de Souza ◽  
Renata Antoun Simão ◽  
Luiz Fernando Brum Malta

The present work introduces a new procedure to obtain gold nanoparticles (AuNPs). AuNPs (77–213 nm) were obtained in the absence of any classical reducing agents in a medium containing Mg2+/Al3+layered double hydroxide (LDH) andN,N-dimethylformamide. XRD analysis showed the presence of crystalline phases of gold in the Au/LDH composite. The 2θvalues of peaks corresponding to the LDH interlayer distance indicated that metallic NPs were deposited on the surface of the material. Furthermore, atomic force microscopy (AFM) analysis showed that AuNPs tend to agglomerate in a nonclassical halter-like shape.


RSC Advances ◽  
2018 ◽  
Vol 8 (34) ◽  
pp. 18814-18827 ◽  
Author(s):  
Jagat Singh Kirar ◽  
Savita Khare

A heterogeneous catalytic system, LDH-[NAPABA–Cu(ii)]/TBHP gave maximum 80.54% conversion and 99.60% selectivity for acetophenone in oxidation of ethylbenzene and catalyst can be reused for seven cycles.


RSC Advances ◽  
2019 ◽  
Vol 9 (16) ◽  
pp. 8768-8777 ◽  
Author(s):  
Xueying Zhang ◽  
Muhammad Ikram ◽  
Zhi Liu ◽  
Lei Teng ◽  
Jialing Xue ◽  
...  

Expanded graphite/NiAl-LDH nanowires for ultra-sensitive, ultra-low detection limits and selective NOx gas detection at room temperature.


RSC Advances ◽  
2016 ◽  
Vol 6 (41) ◽  
pp. 34280-34287 ◽  
Author(s):  
Jiawei Ye ◽  
Bei Cheng ◽  
S. Wageh ◽  
Ahmed A. Al-Ghamdi ◽  
Jiaguo Yu

Flexible and bendable Mg–Al layered double hydroxide supported Pt catalysts fabricated and used in room-temperature catalytic decomposition of formaldehyde.


RSC Advances ◽  
2016 ◽  
Vol 6 (105) ◽  
pp. 103192-103198 ◽  
Author(s):  
Dahai Hong ◽  
Jiawei Zhang ◽  
Afrasiab Ur Rehman ◽  
Lihong Gong ◽  
Jiao Zhou ◽  
...  

Hierarchical flower-like Ni–Al-layered and Ni–Fe–Al-layered double hydroxide intercalation compounds were synthesized and showed good sensing for NOx at room temperature.


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