scholarly journals Enhancement of Oxygen Mass Transfer and Gas Holdup Using Palm Oil in Stirred Tank Bioreactors with Xanthan Solutions as Simulated Viscous Fermentation Broths

2013 ◽  
Vol 2013 ◽  
pp. 1-9 ◽  
Author(s):  
Suhaila Mohd Sauid ◽  
Jagannathan Krishnan ◽  
Tan Huey Ling ◽  
Murthy V. P. S. Veluri

Volumetric mass transfer coefficient (kLa) is an important parameter in bioreactors handling viscous fermentations such as xanthan gum production, as it affects the reactor performance and productivity. Published literatures showed that adding an organic phase such as hydrocarbons or vegetable oil could increase thekLa. The present study opted for palm oil as the organic phase as it is plentiful in Malaysia. Experiments were carried out to study the effect of viscosity, gas holdup, andkLaon the xanthan solution with different palm oil fractions by varying the agitation rate and aeration rate in a 5 L bench-top bioreactor fitted with twin Rushton turbines. Results showed that 10% (v/v) of palm oil raised thekLaof xanthan solution by 1.5 to 3 folds with the highestkLavalue of 84.44 h−1. It was also found that palm oil increased the gas holdup and viscosity of the xanthan solution. ThekLavalues obtained as a function of power input, superficial gas velocity, and palm oil fraction were validated by two different empirical equations. Similarly, the gas holdup obtained as a function of power input and superficial gas velocity was validated by another empirical equation. All correlations were found to fit well with higher determination coefficients.

Energies ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 4329
Author(s):  
Radek Šulc ◽  
Jan Dymák

The gas–liquid hydrodynamics and mass transfer were studied in a concentric tube internal jet-loop airlift reactor with a conical bottom. Comparing with a standard design, the gas separator was equipped with an adjustable deflector placed above the riser. The effect of riser superficial gas velocity uSGR on the total gas holdup εGT, homogenization time tH, and overall volumetric liquid-phase mass transfer coefficient kLa was investigated in a laboratory bioreactor, of 300 mm in inner diameter, in a two-phase air–water system and three-phase air–water–PVC–particle system with the volumetric solid fraction of 1% for various deflector clearances. The airlift was operated in the range of riser superficial gas velocity from 0.011 to 0.045 m/s. For the gas–liquid system, when reducing the deflector clearance, the total gas holdup decreased, the homogenization time increased twice compared to the highest deflector clearance tested, and the overall volumetric mass transfer coefficient slightly increased by 10–17%. The presence of a solid phase shortened the homogenization time, especially for lower uSGR and deflector clearance, and reduced the mass transfer coefficient by 15–35%. Compared to the gas–liquid system, the noticeable effect of deflector clearance was found for the kLa coefficient, which was found approx. 20–29% higher for the lowest tested deflector clearance.


2013 ◽  
Vol 11 (1) ◽  
pp. 47-56 ◽  
Author(s):  
Laleh Hadavand ◽  
Ali Fadavi

Abstract Bubble size has a key role in gas holdup and mass transfer in bubble column reactors. In order to have small and uniform bubbles, a new structure was designed; the reactor operates in two modes, with vibrating sparger and conventional bubble column in which sparger is fixed. In vibrating mode, the sparger vibrates gently during gas entering. The vibrating sparger performs like a paddle, resulting in a forced recirculation of gas–liquid inside the reactor; moreover, the bubble detachment is accelerated. The superficial gas velocity was between 0.003 and 0.013 ms− 1, and the vibration frequency was changed between 0 and 10.3 Hz. The bubble size was measured at three various positions of the reactor height by photographic method and using MATLAB 7.0.1 software. The mass transfer coefficient was determined by means of the dynamic gassing-out method. The results show that the bubbles were bigger in vibrating mode than those working without vibration. The bubble size decreases with increase in height from sparger. Gas holdup increased with increase in superficial gas velocity and vibration frequency. The effect of vibration increased the gas holdup with an average of 70% for all superficial gas velocities. Volumetric mass transfer coefficient was almost stable as vibration frequency increased.


2008 ◽  
Vol 2 (1) ◽  
pp. 7
Author(s):  
Taslim Taslim ◽  
Mohd Sobri Takriff

Gas holdup and gas-liquid mass transfer were investigated in a vertical baffled column. Pure carbon dioxide (C02) was used as the dispersed phase and tap water was used as the continuous phase. Gas holdup and mass transfer rate of C02 were measured under semi-batch condition, while the liquid phase was measured in batch mode. Gas holdup was estimated as the volume fraction of the gas in the two-phase mixture in the column. Mass transfer was expressed in terms of the liquid-side volumetric mass transfer coefficient (kLa). The effects of oscillation frequency, oscillation amplitude and gas flow rate on gas holdup andmass transfer were also determined. The results showed that a significant increase in gas holdup and mass transfer could be achieved in an oscillatory baffled column compared to a bubble column. Gas holdup and mass transfer were correlated as a function of power density and superficial gas velocity. Keywords: gas holdup, mass transfer coefficient, power density, superficial gas velocity


2017 ◽  
Vol 2017 ◽  
pp. 1-7 ◽  
Author(s):  
Shaobai Li ◽  
Siyuan Huang ◽  
Jungeng Fan

In this study, the gas holdup of bubble swarms in shear-thinning fluids was experimentally studied at superficial gas velocities ranging from 0.001 to 0.02 m·s−1. Carboxylmethyl cellulose (CMC) solutions of 0.2 wt%, 0.6 wt%, and 1.0 wt% with sodium dodecyl sulfate (SDS) as the surfactant were used as the power-law (liquid phase), and nitrogen was used as the gas phase. Effects of SDS concentration, rheological behavior, and physical properties of the liquid phase and superficial gas velocity on gas holdup were investigated. Results indicated that gas holdup increases with increasing superficial gas velocity and decreasing CMC concentration. Moreover, the addition of SDS in CMC solutions increased gas holdup, and the degree increased with the surfactant concentration. An empirical correlation was proposed for evaluating gas holdup as a function of liquid surface tension, density, effective viscosity, rheological property, superficial gas velocity, and geometric characteristics of bubble columns using the experimental data obtained for the different superficial gas velocities and CMC solution concentrations with different surfactant solutions. These proposed correlations reasonably fitted the experimental data obtained for gas holdup in this system.


2005 ◽  
Vol 70 (12) ◽  
pp. 1533-1544 ◽  
Author(s):  
Ivica Stamenkovic ◽  
Olivera Stamenkovic ◽  
Ivana Bankovic-Ilic ◽  
Miodrag Lazic ◽  
Vlada Veljkovic ◽  
...  

Gas holdup was investigated in a gas-liquid and gas-liquid-solid reciprocating plate column (RPC) under various operation conditions. Aqueous carboxymethyl cellulose (sodium salt, CMC) solutions were used as the liquid phase, the solid phase was spheres placed into interplate spaces, and the gas phase was air. The gas holdup in the RPC was influenced by: the vibration intensity, i.e., the power consumption, the superficial gas velocity, the solids content and the rheological properties of the liquid phase. The gas holdup increased with increasing vibration intensity and superficial gas velocity in both the two- and three-phase system. With increasing concentration of the CMC PP 50 solution (Newtonian fluid), the gas holdup decreased, because the coalescence of the bubbles was favored by the higher liquid viscosity. In the case of the CMC PP 200 solutions (non-Newtonian liquids), the gas holdup depends on the combined influence of the rheological properties of the liquid phase, the vibration intensity and the superficial gas velocity. The gas holdup in the three-phase systems was greater than that in the two-phase ones under the same operating conditions. Increasing the solids content has little influence on the gas holdup. The gas holdup was correlated with the power consumption (either the time-averaged or total power consumption) and the superficial gas velocity.


Author(s):  
S. Dhanasekaran ◽  
T. Karunanithi

This investigation reports the experimental and theoretical results carried out to evaluate the volumetric mass transfer coefficient (kLa) in a novel hybrid rotating and reciprocating perforated plate bubble column. Countercurrent condition is performed. kLa is studied by the absorption of oxygen from air into deoxygenated water at room temperature (27 ± 1°C). Effects of agitation level, superficial gas velocity, superficial liquid velocity and plate spacing on kLa were analyzed and found to be significant. With an increase in agitation level at a constant superficial gas and liquid velocities, the breakage process of gas bubbles starts to be more pronounced and intensive oxygen mass transfer occurs. Hence, kLa increases sharply. kLa increases with an increase in superficial gas velocity, due to higher gas holdup and the enhanced breakup of bubbles. Similarly, kLa increases with an increase in superficial liquid velocity and the effect is found to be significant. When plate spacing is decreased (by increasing the number of plates), it is observed that the kLa increases at higher superficial gas velocity and agitation level. Correlation is developed for the determination of kLa and found to concur with experimental results. This correlation can be used for the determination of kLa for this hybrid column with 95% accuracy within the range of variables investigated in this present study.


Author(s):  
Chunxi Lu ◽  
Nana Qi ◽  
Kai Zhang ◽  
Jiaqi Jin ◽  
Hu Zhang

An external liquid circulation is introduced into a traditional internal loop reactor in order to improve liquid circulation and increase the interface between gas and liquid phases. The effects of superficial gas velocity and external liquid circulation velocity on local and overall gas holdups are explored experimentally and numerically in the loop section of a combined gas-liquid contactor, which consists of a liquid spray, sieve plates and an internal loop with external liquid circulation. Local gas holdup is measured experimentally by a double-sensor conductivity probe. Numerical simulations are conducted in the platform of a commercial software package, ANSYS CFX 10.0. Gas holdup and other information are obtained by solving the governing equations of mass and momentum balances for gas and liquid phases in a hybrid mesh system. Both measured and simulated results indicate that local, section-averaged, and overall gas holdups increase with an increase of the superficial gas velocity. The downcomer tube for circulating external liquid has a significant influence in the gas-distributor and the downcomer-tube action regions rather than in the upper draft-tube and the gas-liquid separation regions. Good agreement between measured and predicted data suggests that CFD simulation together with experimental investigation can be employed to develop novel gas-liquid contactors with a complex geometrical configuration.


Author(s):  
Xi Zhang ◽  
Ping Zhu ◽  
Shuaichao Li ◽  
Wenyuan Fan ◽  
Jingyan Lian

Abstract A numerical simulation was performed to study the hydrodynamics of micro-bubble swarm in bubble column with polyacrylamide (PAM) aqueous solution by using computational fluid dynamics coupled with population balance models (CFD-PBM). By considering rheological characteristics of fluid, this approach was able to accurately predict the features of bubble swarm, and validated by comparing with the experimental results. The gas holdup, turbulent kinetic energy and liquid velocity of bubble column have been elucidated by considering the influences of superficial gas velocity and gas distributor size respectively. The results show that with the rise of the superficial gas velocity, the gas holdup and its peak width increase significantly. Especially, the curve peak corresponding to high gas velocity tends to drift obviously toward the right side. Except for the occurrence of a smooth holdup peak at the column center under the condition of the moderate distributor size, the gas holdups for the small and large distributor sizes become flat in the radial direction respectively. The distribution of turbulent kinetic energy presents an increasingly asymmetrical feature in the radial direction and also its variation amplitude enhances obviously with the rise of gas velocity. The increase in gas distributor size can enhance markedly turbulent kinetic energy as well as its overall influenced width. At the low and moderate superficial gas velocity, the curves of the liquid velocity in radial direction present the Gaussian distributions, whereas the perfect distribution always is broken in the symmetry for high gas velocity. Both liquid velocities around the bubble column center and the ones near both column walls go up consistently with the gas distributor size, especially near the walls at the large distributor size condition.


Author(s):  
Shivanand M. Teli ◽  
Viraj S. Pawar ◽  
Channamallikarjun Mathpati

AbstractStirred tanks are commonly used in chemical and allied industries for reaction and separation. In order to improve the mixing performance, large scale reactors are often equipped with multiple impellers. In the case of gas-liquid systems, the gas hold-up, mass transfer coefficient, and interfacial area strongly depend on the size and type of impellers, clearance between impellers and superficial gas velocity. In the present work, the effect of the impeller speed, superficial gas velocity, and top impeller position has been investigated on gas hold-up, interfacial area, and mass transfer coefficient. Computational fluid dynamics have been carried out for the multiphase multi-impeller system and the model predictions have been compared with the experimental data.


2016 ◽  
Vol 14 (5) ◽  
pp. 975-990
Author(s):  
Hiba A. Abdulkareem ◽  
Saba A. Gheni ◽  
Rafi’ J. Yacoup

Abstract Bubble columns are widely used for contacting gas–liquid and gas–liquid–solid mass transfer/chemical reactions. Gas distributor is the most important accessory because it decides the bubble size/rise velocity and gas distribution. In this study, the effect of distributor design on hydrodynamics and mass transfer coefficient are studied at different operating conditions of height to diameter ratio, solid loading, and superficial gas velocity The overall gas holdup, is studied experimentally using a rectangular slurry bubble column operating at ambient temperature and pressure, using liquid paraffin (C9–C11), three heights to diameter ratios (6, 7.5 and 10) and silica as a solid phase (0 %, 9 % and 25 %) with oxygen as gas phase. Two types of distributor were used, perforated plate and ring type. The results showed that the overall gas holdup increased by increasing gas velocity and decreased by increasing height to diameter ratio and solid loading. Also, it is found that the perforated plate distributor gave a higher gas hold up than ring distributor at gas velocity higher than 0.03 m/sec. The following correlations are obtained: Plate distributor at presence of silica particles: $$\eqalign{{{\rm{\varepsilon}}_{\rm{g}}} =& {\left({1.343{\rm{U}}_{\rm{g}}^{0.0612} - 0.00891{\rm{\varepsilon}}_{\rm{s}}^{- 0.374} - 0.702{{\left({{{\rm{L}} \over {\rm{D}}}} \right)}^{0.041}}} \right)^{4.904}}\cr& - 0.0251}$$ Ring distributor at presence and absence of silica particles: $$\eqalign{{{\rm{\varepsilon}}_{\rm{g}}} = &{\left({0.216{\rm{U}}_{\rm{g}}^{0.297} - 0.354{\rm{\varepsilon}}_{\rm{s}}^{1.4671} - 0.127{{\left({{{\rm{L}} \over {\rm{D}}}} \right)}^{0.147}}} \right)^{1.1206}} \cr&+ 0.058}$$ There is a good agreement between experimental and predicted values with a percent of error less than 2 %. It has been found that the mass transfer coefficient is higher for ring distributor than the perforated plate and growing higher for heterogeneous flow regime and higher solid loading.


Sign in / Sign up

Export Citation Format

Share Document