scholarly journals Enhanced Optical Properties of Germanate and Tellurite Glasses Containing Metal or Semiconductor Nanoparticles

2013 ◽  
Vol 2013 ◽  
pp. 1-13 ◽  
Author(s):  
Cid Bartolomeu de Araujo ◽  
Diego Silvério da Silva ◽  
Thiago Alexandre Alves de Assumpção ◽  
Luciana Reyes Pires Kassab ◽  
Davinson Mariano da Silva

Germanium- and tellurium-based glasses have been largely studied due to their recognized potential for photonics. In this paper, we review our recent studies that include the investigation of the Stokes and anti-Stokes photoluminescence (PL) in different glass systems containing metallic and semiconductor nanoparticles (NPs). In the case of the samples with metallic NPs, the enhanced PL was attributed to the increased local field on the rare-earth ions located in the proximity of the NPs and/or the energy transfer from the metallic NPs to the rare-earth ions. For the glasses containing silicon NPs, the PL enhancement was mainly due to the energy transfer from the NPs to the Er3+ions. The nonlinear (NL) optical properties of PbO-GeO2films containing gold NPs were also investigated. The experiments in the pico- and subpicosecond regimes revealed enhanced values of the NL refractive indices and large NL absorption coefficients in comparison with the films without gold NPs. The reported experiments demonstrate that germanate and tellurite glasses, having appropriate rare-earth ions doping and NPs concentration, are strong candidates for PL-based devices, all-optical switches, and optical limiting.

2013 ◽  
Vol 588 ◽  
pp. 188-192 ◽  
Author(s):  
M.C. Neto ◽  
G.H. Silva ◽  
A.P. Carmo ◽  
A.S. Pinheiro ◽  
N.O. Dantas ◽  
...  

1984 ◽  
Vol 39 (5) ◽  
pp. 490-494 ◽  
Author(s):  
B. Köngeter ◽  
S. Kemmler-Sack

By activation of the cubic garnet host lattice Gd3Te2Li3O12 with trivalent rare earth ions the most intense visible emission is observed for Ln3+ = Eu, Tb. Energy transfer from Gd3+ to Sm3+, Eu3+ or Dy3+, from Tb3+ to Eu3+ and from Er3+ to Tm3+ has been found to occur. The luminescence properties are strongly influenced by the substitution of Te6+ by W6+ (systems Gd3-xLnxTe2-yWyLi3O12)


2011 ◽  
Vol 60 (7) ◽  
pp. 077802
Author(s):  
Chen Ying ◽  
Chen Xiao-Bo ◽  
Zhang Hui-Min ◽  
Xu Xiao-Ling ◽  
Wang Ce

2009 ◽  
Vol 18 (12) ◽  
pp. 5523-5533 ◽  
Author(s):  
Chen Xiao-Bo ◽  
Wang Ce ◽  
Gregory J Salamo ◽  
Naruhito Sawanobori ◽  
Kang Dong-Guo ◽  
...  

2021 ◽  
Vol 33 (6) ◽  
pp. 48-56
Author(s):  
SUKHDEV BAIRAGI ◽  
◽  
GHIZAL F. ANSAR ◽  

In this work we review the effect of physical and optical properties with different ion zinc contents of tellurite base glass. The physical properties of the glasses were evaluated and the change in density, molar volume and ionic packing density in these glasses indicates the effect of ZnO different content show on the glasses structure. The study of optical properties such as the optical band gap and refractive index of zinc tellurite glass were studied. Zinc Tellurite glasses doped with Er3+ ions were synthesized by varies researcher. The glasses were characterized by X- ray diffraction, optical absorption and photoluminescence spectra. The glassy nature of zinc Tellurite host glass has been confirmed through XRD measurements. The glasses doped or co-doped with rare-earth ions have generated much interest due to the possibility of several promising applications such as optical data storage, visible laser, fibre amplifier, optical communication and sensor devices


Micromachines ◽  
2018 ◽  
Vol 9 (8) ◽  
pp. 380 ◽  
Author(s):  
Francesco Enrichi ◽  
Elti Cattaruzza ◽  
Maurizio Ferrari ◽  
Francesco Gonella ◽  
Riccardo Ottini ◽  
...  

Rare earth doped materials play a very important role in the development of many photonic devices, such as optical amplifiers and lasers, frequency converters, solar concentrators, up to quantum information storage devices. Among the rare earth ions, ytterbium is certainly one of the most frequently investigated and employed. The absorption and emission properties of Yb3+ ions are related to transitions between the two energy levels 2F7/2 (ground state) and 2F5/2 (excited state), involving photon energies around 1.26 eV (980 nm). Therefore, Yb3+ cannot directly absorb UV or visible light, and it is often used in combination with other rare earth ions like Pr3+, Tm3+, and Tb3+, which act as energy transfer centres. Nevertheless, even in those co-doped materials, the absorption bandwidth can be limited, and the cross section is small. In this paper, we report a broadband and efficient energy transfer process between Ag dimers/multimers and Yb3+ ions, which results in a strong PL emission around 980 nm under UV light excitation. Silica-zirconia (70% SiO2-30% ZrO2) glass-ceramic films doped by 4 mol.% Yb3+ ions and an additional 5 mol.% of Na2O were prepared by sol-gel synthesis followed by a thermal annealing at 1000 °C. Ag introduction was then obtained by ion-exchange in a molten salt bath and the samples were subsequently annealed in air at 430 °C to induce the migration and aggregation of the metal. The structural, compositional, and optical properties were investigated, providing evidence for efficient broadband sensitization of the rare earth ions by energy transfer from Ag dimers/multimers, which could have important applications in different fields, such as PV solar cells and light-emitting near-infrared (NIR) devices.


Author(s):  
Ping Wu ◽  
Qianli Ma ◽  
Wensheng Yu ◽  
Jinxian Wang ◽  
Gui-Xia Liu ◽  
...  

Here, we put forward a viewpoint that the energy transfer between different rare earth (RE) ions plays negative effect in RE ions doped white fluorescent materials if the native fluorescence...


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