scholarly journals Solid-State Synthesis, Characterization, and Biological Activity of the Bioinorganic Complex of Aspartic Acid and Arsenic Triiodide

2013 ◽  
Vol 2013 ◽  
pp. 1-5 ◽  
Author(s):  
Guo-Qing Zhong ◽  
Wen-Wei Zhong ◽  
Rong-Rong Jia ◽  
Yu-Qing Jia
Keyword(s):  
Crystal Structure ◽  
Biological Activity ◽  
Solid State ◽  
Complex Formation ◽  
Aspartic Acid ◽  
Infrared Spectra ◽  
Room Temperature ◽  
Biological Test ◽  
Bridge Structure ◽  
Monoclinic System

The bioinorganic complex of aspartic acid and arsenic triiodide was synthesized by a solid-state reaction at room temperature. The formula of the complex is AsI3[HOOCCH2CH(NH2)COOH]2.5. The crystal structure of the complex belongs to monoclinic system with lattice parameters:a=1.0019 nm,b=1.5118 nm,c=2.1971 nm, andβ=100.28°. The infrared spectra can demonstrate the complex formation between the arsenic ion and aspartic acid, and the complex may be a dimer with bridge structure. The result of primary biological test indicates that the complex possesses better biological activity for the HL-60 cells of the leukemia than arsenic triiodide.

Darstellung, Reaktionen und spektroskopische Charakterisierung von [Os2X8]2-, X = Cl, Br, I, und Kristallstruktur von (PPN)2[Os2I8] · 2 CH2Cl2 / Preparation, Reactions and Spectroscopic Characterization of [Os2X8]2-, X = Cl, Br, I, and Crystal Structure of (PPN)2[Os2I8] · 2 CH2Cl2

1990 ◽  
Vol 45 (10) ◽  
pp. 1416-1424 ◽  
Author(s):  
W. Preetz ◽  
P. Hollmann ◽  
G. Thiele ◽  
H. Hillebrecht
Keyword(s):  
Crystal Structure ◽  
Structure Determination ◽  
Triple Bond ◽  
Room Temperature ◽  
Spectroscopic Characterization ◽  
Spectroscopic Constants ◽  
Monoclinic System ◽  
X Ray ◽  
Fine Structures

The triply bonded octahalogenodiosmate(III) anions [Os2X8]2-, previously known with X = Cl, Br, have now been extended to include the iodide with two staggered OsI4 units. This compound was prepared by treating [Os2Cl8]2- with Nal at room temperature in acetone solution. The structure determination by X-ray diffractometry on single crystals of (PPN)2[Os2I8] · 2 CH2Cl2, reveals crystallization in the monoclinic system, space group P21/c with Z = 4. The Os-Os triple bond is with 2.212(1) Å the longest within the three octahalogenodiosmates(III). The Raman spectra show ν(OsOs) at 285, [Os2Cl8]2-; at 287, [Os2Br8]2- and for the iodo compound at 270.1 cm-1 with up to three overtones. The spectroscopic constants are calculated to be ω1 = 270.9 cm-1; X11 = -0.50 cm-1. The 10 Κ UV-VIS spectra of solid [(n-C4H9)4N]2[Os2X8] exhibit δ-π* transitions with maxima at 723, 690 and 643 nm, superimposed by vibrational fine structures with long progressions of 195, 211 and 183 cm-1 for X = Cl, Br, I, respectively. Oxidation of [Os2X8]2-, X = Cl, Br with the corresponding halogen leads to the cleavage of the Os-Os bond, and the dekahalogenodiosmates(IV), [Os2X10]2-, are formed

Solid-Liquid Reaction Synthesis and Characterization of Bioinorganic Complexes of Nicotinic Acid with Antimony(III) and Bismuth(III) Ion

2011 ◽  
Vol 282-283 ◽  
pp. 267-270 ◽  
Author(s):  
Guo Qing Zhong ◽  
Mei Gu ◽  
Yan Zhang
Keyword(s):  
Crystal Structure ◽  
Nicotinic Acid ◽  
Room Temperature ◽  
Synthesis And Characterization ◽  
Reaction Synthesis ◽  
Monoclinic System ◽  
Triclinic System ◽  
Liquid Reaction ◽  
Solid Liquid

Bioinorganic complexes of nicotinic acid with trivalent antimony and bismuth are synthesized by solid-liquid reaction at room temperature. The formula of the complexes is Sb(C5H4NCOOH)2Cl3•H2O and Bi(C5H4NCOOH)2Cl3•H2O respectively. The crystal structure of the complex of nicotinic acid and Sb(III) belongs to triclinic system and that of nicotinic acid and Bi(III) belongs to monoclinic system. Thermal analysis can indicate the complex formation between antimony or bismuth ion and nicotinic acid.

scholarly journals Metallation of Isatin (2,3-Indolinedione). X-Ray Structure and Solution Behavior of Bis(Isatinato)Mercury(II)

1995 ◽  
Vol 2 (2) ◽  
pp. 81-90 ◽  
Author(s):  
Angel Garcia-Raso ◽  
Juan J. Fiol ◽  
Elies Molins ◽  
Antonia M. Calafat ◽  
Patricia A. Marzilli ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Solid State ◽  
Metal Complex ◽  
Bond Length ◽  
Spectral Data ◽  
Structure Determination ◽  
Monoclinic System ◽  
Heterocyclic Nitrogen ◽  
X Ray

The first X-ray structure of an isatin (2,3-indolinedione, isaH) metal complex, bis(isatinato)memury(II) (C16H8N2O4Hg) (1), was determined. (1) was obtained from the reaction of isaH with mercury(II) acetate in methanol. Analogously, treatment of sodium saccharinate and mercury(II) acetate in methanol yielded Hg(saccharinato)2•0.5CH3OH (3). (1) crystallizes in the monoclinic system, space group P21/a with a = 7.299(1) Å, b = 8.192(1) Å, c = 11.601(1) Å , β = 105.82(1)°, V = 667.4 Å3, Z = 2, Dcalc = 2.452 g cm−3, MoKα radiation(λ = 0.71073 Å), μ = 115.5 cm-1, F(000) = 460, 21(1) °C. The structure was refined on the basis of 2023 observed reflections to R= 0.044. The two deprotonated, non coplanar isa ligands are trans to each other in a head to tail orientation and bound to the Hg through the nitrogen in a linear N-Hg-N arrangement. The Hg atom is at the center of symmetry of the complex and displaced by 0.62 Å from the two planes of the isa ligands (τ Hg-N1-C2-O2= -16°). The Hg-N bond length is 2.015 Å. Noπ-aryl-memury(ll)-π-aryl stacking interaction was observed either in the solid state or in the solution state. The IR, electronic, and H1 and C13NMR spectral data of (1) and (3) suggest binding of the memury to the heterocyclic nitrogen, in agreement with the crystal structure determination of (1).

scholarly journals Synthesis and structure study of new manganese and indium based phosphate: (Ca,Ba)1.222Mn0.923In1.570(PO4)3

2018 ◽  
Vol 149 ◽  
pp. 01085
Author(s):  
Elhassan Benhsina ◽  
Abderrazzak Assani ◽  
Mohamed Saadi ◽  
Lahcen El Ammari
Keyword(s):  
Crystal Structure ◽  
Solid State ◽  
Three Dimensional ◽  
Structural Diversity ◽  
Structure Study ◽  
Important Class ◽  
Common Edge ◽  
Monoclinic System ◽  
Metal Phosphates ◽  
Cell Parameters

Phosphates are an important class of materials which are well-known due to their structural diversity and their important potential application in many fields of sciences. A member of this family, represented by transition metal phosphates, is in the forefront of important researchers. A new manganese and indium based phosphate is successfully isolated by means of solid state reaction. Its corresponding crystal structure is isotypic to the alluaudite and crystallizes in the monoclinic system with the space group C2/c and cell parameters a=12.4697(5)Å ; b=12.9365(5)Å ; c=6.5625(3)Å and β=115.603(1)°. The framework of this phosphate is built up on the basis of MnO6, InO6 and PO4 polyhedra. The InO6 octahedra are linked together via common edge, leading to the formation of In2O10 dimers. The In2O10 dimers share edge with MnO6 octahedra, generating chains along the [101] direction. The PO4 tetrahedra connect two chains giving arise to a three-dimensional framework with hexagonal tunnels where the barium and calcium are located.

Infrared Spectra of the Alkali Metal Cyanides in the Solid State

1973 ◽  
Vol 27 (2) ◽  
pp. 93-94 ◽  
Author(s):  
Zakya K. Ismail ◽  
Robert H. Hauge ◽  
John L. Margrave
Keyword(s):  
Solid State ◽  
Alkali Metal ◽  
Liquid Nitrogen ◽  
Infrared Spectra ◽  
Room Temperature ◽  
Solid Phase ◽  
Liquid Nitrogen Temperature ◽  
Metal Cyanides ◽  
Sodium And Potassium

The infrared spectra of lithium isocyanide and of sodium and potassium cyanides in the solid phase were examined over the range 4000 to 140 cm−1 at room temperature. A study of the effect of cooling the solids to liquid nitrogen temperature has been carried out.

Preparation and crystal structure of SbV1.50InIII0.50(PO4)3 and (SbV0.50InIII0.50)P2O7

2008 ◽  
Vol 23 (3) ◽  
pp. 232-240
Author(s):  
Abderrahim Aatiq ◽  
Rachid Bakri ◽  
Aaron Richard Sakulich
Keyword(s):  
Crystal Structure ◽  
Solid State ◽  
Room Temperature ◽  
Rietveld Method ◽  
Monoclinic Space Group ◽  
Unit Cell Parameters ◽  
Orthorhombic System ◽  
Space Group ◽  
X Ray ◽  
Cell Parameters

Synthesis and structure of two phosphates belonging to the ternary Sb2O5–In2O3–P2O5 system are realized. Structures of SbV1.50InIII0.50(PO4)3 and (SbV0.50InIII0.50)P2O7 phases, obtained by solid state reaction in air at 950 °C, were determined at room temperature from X-ray powder diffraction using the Rietveld method. SbV1.50InIII0.50(PO4)3 have a monoclinic (space group P21/n) distortion of the Sc2(W O4)3-type framework. Its structure is constituted by corner-shared SbO6 or InO6 octahedra and PO4 tetrahedra. Monoclinic unit cell parameters are a=11.801(2) Å, b=8.623(1) Å, c=8.372(1) Å, and β=90.93(1)°. (Sb0.50In0.50)P2O7 is isotypic with (Sb0.50Fe0.50)P2O7 and crystallizes in orthorhombic system (space group Pna21) with a=7.9389(1) Å, b=16.0664(2) Å, and c=7.9777(1) Å. Its structure is built up from corner-shared SbO6 or InO6 octahedra and P2O7 groups (two group-types). Each P2O7 group shares its six vertices with three SbO6 and three InO6 octahedra, and each octahedron is connected to six P2O7 groups.

scholarly journals Room-Temperature Mg-Ion Conduction Through Molecular Crystal Mg{N(SO2CF3)2}2(CH3OC5H9)2

2021 ◽  
Vol 9 ◽  
Author(s):  
Takaaki Ota ◽  
Shota Uchiyama ◽  
Keiichi Tsukada ◽  
Makoto Moriya
Keyword(s):  
Crystal Structure ◽  
Solid State ◽  
Ionic Conductivity ◽  
Molecular Crystal ◽  
Solid Electrolytes ◽  
Room Temperature ◽  
Molecular Crystals ◽  
Transference Number ◽  
Ion Conducting ◽  
State Ionic

Molecular crystals have attracted increasing attention as a candidate for innovative solid electrolytes with solid-state Mg-ion conductivity. In this work, we synthesized a novel Mg-ion-conducting molecular crystal, Mg{N(SO2CF3)2}2(CH3OC5H9)2 (Mg(TFSA)2(CPME)2), composed of Mg bis(trifluoromethanesulfonyl)amide (Mg(TFSA)2) and cyclopentyl methyl ether (CPME) and elucidated its crystal structure. We found that the obtained Mg(TFSA)2(CPME)2 exhibits solid-state ionic conductivity at room temperature and a high Mg-ion transference number of 0.74. Contrastingly, most Mg-conductive inorganic solid electrolytes require heating above 150–300°C to exhibit ionic conductivity. These results further prove the suitability of molecular crystals as candidates for Mg-ion-conducting solid electrolytes.

scholarly journals A new zinc(II) supramolecular square: Synthesis, crystal structure, thermal behavior and luminescence

2015 ◽  
Vol 80 (10) ◽  
pp. 1289-1295
Author(s):  
Xiu-Yan Wang ◽  
Zhong-Yu Zhao ◽  
Qian Han ◽  
Miao Yu ◽  
De-Yu Kong
Keyword(s):  
Crystal Structure ◽  
Solid State ◽  
Thermal Behavior ◽  
Luminescence Property ◽  
Room Temperature ◽  
Hydrothermal Condition ◽  
Stacking Interactions ◽  
Triclinic Space Group ◽  
Four Corners ◽  
State Luminescence

A new square-shaped Zn(II) complex, namely, [Zn4(L)4(phen)4]?6H2O (1) (L = 2-hydroxynicotinate and phen = 1,10- phenanthroline), has been synthesized under hydrothermal condition. The crystal of 1 belongs to triclinic, space group P -1 with a = 10.773(2) ?, b = 12.641(3) ?, c = 13.573(3) ?, ? = 107.44(3)?, ? = 102.66(3)?, ? = 93.89(3)?, C72H56N12O18Zn4, Mr = 1638.77, V = 1702.8(6) ?3 , Z = 1, Dc = 1.598 g/cm3 , S = 1.045, ?(MoK?) = 1.475 mm-1 , F(000) = 836, R = 0.0472 and wR = 0.0919. In 1, four L ligands bridge four Zn(II) atoms to form a square-shaped structure, where four phen ligands are respectively located on four corners of the square. The ?-? stacking interactions extend the adjacent squares into a 1D supramolecular chain. The thermal behavior of 1 has been characterized. Moreover, its solid state luminescence property has been studied at room temperature.

scholarly journals Synthesis and crystal structure of two new phosphates with Alluaudite type structure: (M, Mn)3Fe(PO4)3 (M= Ca, Cd)

2018 ◽  
Vol 149 ◽  
pp. 01084 ◽  
Author(s):  
Ghaleb Alhakmi ◽  
Abderrazzak Assani ◽  
Mohamed Saadi ◽  
Lahcen El Ammari
Keyword(s):  
Crystal Structure ◽  
Solid State ◽  
Type Structure ◽  
X Ray Diffraction ◽  
Monoclinic System ◽  
Synthesis And Crystal Structure ◽  
X Ray ◽  
Open Framework ◽  
Bivalent Cations ◽  
The Common

Two new phosphates with alluaudite type structure (M, Mn)3Fe(PO4)3 (M= Ca, Cd), namely Ca1.54Mn1.46Fe(PO4)3 and Cd0.66Mn2.34Fe(PO4)3, has been synthesized by a solid state reaction and characterized by single-crystal X-ray diffraction. The two compounds crystallize in the monoclinic system with C2/c space group. Their open framework results from (Fe1/Mn1)2O10 units of edge-sharing (Fe/Mn)O6 octahedra, which alternate with M(1)O6 octahedra (M(1)=Ca1/Mn2 or Cd1/Mn2) that form infinite chains running along [10-1] direction. These chains are linked together through the common corners of PO4 tetrahedra giving rise to two types of tunnels occupied by bivalent cations Ca2+ or Cd2+ and Mn2+.

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