scholarly journals Indium Phosphide-Based Semiconductor Nanocrystals and Their Applications

2012 ◽  
Vol 2012 ◽  
pp. 1-11 ◽  
Author(s):  
Paul Mushonga ◽  
Martin O. Onani ◽  
Abram M. Madiehe ◽  
Mervin Meyer
Keyword(s):  
Indium Phosphide ◽  
Surface Passivation ◽  
Semiconductor Nanocrystals ◽  
Core Size ◽  
The Core ◽  
Colloidal Semiconductor Nanocrystals ◽  
Biological Studies ◽  
Fluorescent Materials ◽  
Different Types ◽  
Heating Up

Semiconductor nanocrystals or quantum dots (QDs) are nanometer-sized fluorescent materials with optical properties that can be fine-tuned by varying the core size or growing a shell around the core. They have recently found wide use in the biological field which has further enhanced their importance. This review focuses on the synthesis of indium phosphide (InP) colloidal semiconductor nanocrystals. The two synthetic techniques, namely, the hot-injection and heating-up methods are discussed. Different types of the InP-based QDs involving their use as core, core/shell, alloyed, and doped systems are reviewed. The use of inorganic shells for surface passivation is also highlighted. The paper is concluded by some highlights of the applications of these systems in biological studies.

scholarly journals Highly Efficient Mesoporous Core-Shell Structured Ag@SiO2 Nanosphere as an Environmentally Friendly Catalyst for Hydrogenation of Nitrobenzene

Nanomaterials ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 883
Author(s):  
Bonan Zhao ◽  
Zhipeng Dong ◽  
Qiyan Wang ◽  
Yisong Xu ◽  
Nanxia Zhang ◽  
...  
Keyword(s):  
Environmentally Friendly ◽  
Mesoporous Structure ◽  
Core Shell ◽  
Core Size ◽  
One Pot ◽  
The Core ◽  
Different Types ◽  
The Stability ◽  
Catalytic Performances ◽  
The Ideal

The size-uniformed mesoporous Ag@SiO2 nanospheres’ catalysts were prepared in one-pot step via reducing AgNO3 by different types of aldehyde, which could control the size of Ag@SiO2 NPs and exhibit excellent catalytic activity for the hydrogenation of nitrobenzene. The results showed that the Ag core size, monitored by different aldehydes with different reducing abilities, together with the ideal monodisperse core-shell mesoporous structure, was quite important to affect its superior catalytic performances. Moreover, the stability of Ag fixed in the core during reaction for 6 h under 2.0 MPa, 140 °C made this type of Ag@SiO2 catalyst separable and environmentally friendly compared with those conventional homogeneous catalysts and metal NPs catalysts. The best catalyst with smaller Ag cores was prepared by strong reducing agents such as CH2O. The conversion of nitrobenzene can reach 99.9%, the selectivity was 100% and the catalyst maintained its activity after several cycles, and thus, it is a useful novel candidate for the production of aniline.

scholarly journals Geometrical Scaling of Antiresonant Hollow-Core Fibers for Mid-Infrared Beam Delivery

Crystals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 420
Author(s):  
Ang Deng ◽  
Wonkeun Chang
Keyword(s):  
Structural Parameters ◽  
Transmission Band ◽  
Confinement Loss ◽  
Hollow Core ◽  
Core Size ◽  
Core Diameter ◽  
Mid Infrared ◽  
The Core ◽  
Tubular Type ◽  
Beam Delivery

We numerically investigate the effect of scaling two key structural parameters in antiresonant hollow-core fibers—dielectric wall thickness of the cladding elements and core size—in view of low-loss mid-infrared beam delivery. We demonstrate that there exists an additional resonance-like loss peak in the long-wavelength limit of the first transmission band in antiresonant hollow-core fibers. We also find that the confinement loss in tubular-type hollow-core fibers depends strongly on the core size, where the degree of the dependence varies with the cladding tube size. The loss scales with the core diameter to the power of approximately −5.4 for commonly used tubular-type hollow-core fiber designs.

scholarly journals Dynamic lattice distortions driven by surface trapping in semiconductor nanocrystals

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Burak Guzelturk ◽  
Benjamin L. Cotts ◽  
Dipti Jasrasaria ◽  
John P. Philbin ◽  
David A. Hanifi ◽  
...  
Keyword(s):  
Photon Energy ◽  
Semiconductor Nanocrystals ◽  
Atomic Scale ◽  
Atomistic Simulations ◽  
Shell System ◽  
Structural Distortions ◽  
Colloidal Semiconductor Nanocrystals ◽  
Femtosecond Electron Diffraction ◽  
Structural Deformations ◽  
Nonradiative Processes

AbstractNonradiative processes limit optoelectronic functionality of nanocrystals and curb their device performance. Nevertheless, the dynamic structural origins of nonradiative relaxations in such materials are not understood. Here, femtosecond electron diffraction measurements corroborated by atomistic simulations uncover transient lattice deformations accompanying radiationless electronic processes in colloidal semiconductor nanocrystals. Investigation of the excitation energy dependence in a core/shell system shows that hot carriers created by a photon energy considerably larger than the bandgap induce structural distortions at nanocrystal surfaces on few picosecond timescales associated with the localization of trapped holes. On the other hand, carriers created by a photon energy close to the bandgap of the core in the same system result in transient lattice heating that occurs on a much longer 200 picosecond timescale, dominated by an Auger heating mechanism. Elucidation of the structural deformations associated with the surface trapping of hot holes provides atomic-scale insights into the mechanisms deteriorating optoelectronic performance and a pathway towards minimizing these losses in nanocrystal devices.

Colloidal semiconductor nanocrystals: synthesis, optical nonlinearity, and related device applications

2021 ◽  
Author(s):  
Min Li ◽  
Cong Wang ◽  
Lude Wang ◽  
Han Zhang
Keyword(s):  
Nonlinear Optical ◽  
Rapid Development ◽  
Semiconductor Nanocrystals ◽  
Optical Nonlinearity ◽  
Photonic Devices ◽  
Nlo Properties ◽  
Novel Materials ◽  
Colloidal Semiconductor Nanocrystals ◽  
Device Applications ◽  
Colloidal Semiconductor

The rapid development of photonic devices requires the exploration of novel materials with superior nonlinear optical (NLO) properties. Colloidal semiconductor nanocrystals (NCs) exhibit size-tunable exciton resonances and excellent NLO properties....

scholarly journals The hourglass effect in hierarchical dependency networks

2017 ◽  
Vol 5 (4) ◽  
pp. 490-528 ◽  
Author(s):  
KAESER M. SABRIN ◽  
CONSTANTINE DOVROLIS
Keyword(s):  
Low Complexity ◽  
Core Size ◽  
Original Network ◽  
Hierarchical Network ◽  
Modular Systems ◽  
The Core ◽  
Dependency Networks ◽  
Dependency Network ◽  
Hierarchical Dependency ◽  
Almost All

AbstractMany hierarchically modular systems are structured in a way that resembles an hourglass. This “hourglass effect” means that the system generates many outputs from many inputs through a relatively small number of intermediate modules that are critical for the operation of the entire system, referred to as the waist of the hourglass. We investigate the hourglass effect in general, not necessarily layered, hierarchical dependency networks. Our analysis focuses on the number of source-to-target dependency paths that traverse each vertex, and it identifies the core of a dependency network as the smallest set of vertices that collectively cover almost all dependency paths. We then examine if a given network exhibits the hourglass property or not, comparing its core size with a “flat” (i.e., non-hierarchical) network that preserves the source dependencies of each target in the original network. As a possible explanation for the hourglass effect, we propose the Reuse Preference model that captures the bias of new modules to reuse intermediate modules of similar complexity instead of connecting directly to sources or low complexity modules. We have applied the proposed framework in a diverse set of dependency networks from technological, natural, and information systems, showing that all these networks exhibit the general hourglass property but to a varying degree and with different waist characteristics.

scholarly journals Some Metal Ions Complexes Derived From Schiff Base Ligand with Anthranillic Acid: Preparation, Spectroscopic and Biological Studies

2020 ◽  
Vol 17 (1) ◽  
pp. 0099
Author(s):  
Lekaa khalid Karem
Keyword(s):  
Schiff Base ◽  
Schiff Base Ligand ◽  
Magnetic Moment ◽  
Primary Amine ◽  
Molar Conductivity ◽  
Spectroscopic Methods ◽  
Geometrical Shape ◽  
Biological Studies ◽  
Different Types ◽  
Uv Visible

This search includes the preparation of Schiff base ligand (SB) from condensation primary amine with vanillin. The new ligand was diagnosed by spectroscopic methods as Mass, NMR, CHN and FTIR. Ligand complexes were mixed from new (SB) and Anthranillic acid (A) with five metal (II) chlorides. The preparation and diagnosis were conducted by FTIR, CHN, UV-visible, molar conductivity, atomic absorption and magnetic moment. The octahedral geometrical shape of the complexes was proposed. The ligands and their new complexes were screened with two different types of bacteria.

scholarly journals All-fiber passively Q-switched ytterbium doped double-clad fiber lasers: experiment And modeling.

2021 ◽  
Author(s):  
Yi Lu
Keyword(s):  
Pulse Energy ◽  
Traveling Wave ◽  
Pulse Width ◽  
Fiber Lasers ◽  
Peak Power ◽  
Wave Model ◽  
Core Size ◽  
The Core ◽  
Q Switching ◽  
Output Characteristics

All-fiber passively Q-switched lasers were demonstrated using ytterbium-doped double cladding fiber (YDF) as an active medium. The laser was pumped by three 25W, 975nm fiber coupled diodes and Q-switching was initiated when the amplified spontaneous emission generated in the core of the gain fiber bleached the saturable absorber (SA). A piece of samarium-doped fiber was used as SA in first configuration and pulses with 68μJ pulse energy and 210ns pulse width were obtained. In second configuration, a piece of ytterbium-doped fiber with much smaller core size was used as SA to produce pulse energy of 86μJ. The last configuration incorporated a 9m-long YDF as gain fiber. The far end from pump was acting as SA in this case and pulses with 82μJ pulse energy and 148ns pulse width were observed. The peak power was estimated at 554W. Traveling wave model was implemented to numerically simulate the output characteristics versus pump power.

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