scholarly journals Development of a Novel Solid-State Sensor Electrode Based on Titanium Thin Film as an Indicator Electrode in Potentiometric and Conductometric Acid-Base Titration in Aqueous Solution

2012 ◽  
Vol 2012 ◽  
pp. 1-8 ◽  
Author(s):  
Nasser Abu Ghalwa
Keyword(s):  
Aqueous Solution ◽  
Titanium Substrate ◽  
Reference Electrode ◽  
Molar Conductance ◽  
Specific Conductance ◽  
Indicator Electrode ◽  
Acid Base ◽  
Solid State Sensor ◽  
Acid Base Titration ◽  
Ph Curve

A modified Ti/(SnO2+ Sb2O3) electrode was prepared by thermal deposition on titanium substrate and its use as indicator electrode to potentiometric and conductometric acid-base titration in aqueous solution at 298 K was developed. The E-pH curve is linear with slope of 0.0512 V/dec at 298 K. The standard potential of this electrode,E0, was determined with respect to the SCE as reference electrode. The recovery percentages for potentiometric and conductometric acid-base titration for acetic acid against NaOH were calculated. The cell constant, specific conductance, and the molar conductance with dilution for some common electrolytes were measured.

Determination of the acidity constant of isothiocyanic acid in aqueous solution

2000 ◽  
Vol 78 (12) ◽  
pp. 1627-1628 ◽  
Author(s):  
Y Chiang ◽  
A J Kresge
Keyword(s):  
Aqueous Solution ◽  
Acid Solution ◽  
Acidity Constant ◽  
Acidity Function ◽  
Acid Base ◽  
Perchloric Acid Solution ◽  
Thiocyanate Ion ◽  
Acid Base Titration ◽  
Aqueous Perchloric Acid

Changes in absorbance of the thiocyanate ion (SCN–) at λ = 220 nm, measured in concentrated aqueous perchloric acid solution, were analyzed using a titration curve expression containing the Xo excess acidity function; this provided the acidity constant Ka = 19.2 ± 1.1 M, pKa = –1.28 ± 0.03, for isothiocyanic acid (SCNH).Key words: isothiocyanic acid (acidity of), thiocyanate ion (basicity of), acid–base titration in concentrated aqueous acids, Xo excess acidity function, Cox–Yates method.

Henderson Hasselbalch Relationship and Weak Acid Titration

2019 ◽  
Author(s):  
Marc Blétry
Keyword(s):  
Theoretical Framework ◽  
Weak Acid ◽  
Acid Base ◽  
Sensitive Technique ◽  
Chemistry Students ◽  
Advanced Students ◽  
Acid Titration ◽  
Acid Base Titration ◽  
Analytical Expressions

Henderson-Hasselbalch relation is generally the simplified theoretical framework used to introduce students to acid-base titration. However, it is not always valid and its limitations should be made clear to chemistry students. The appropriate parameter to evaluate its validity is K a /C 0 , in connection with Ostwald dilution law. For more advanced students, it is possible to deduce analytical expressions that always fit accurately acid-base titrations and allow an evaluation of Henderson Hasselbalch relation. Gran plot appears as a particularly sensitive technique to the breakdown of Henderson Hasselbalch relation.

Direct Synthesis of 3,5-Dinitropyrazole Catalyzed by Newly Sulfated Nanosolid Superacid TiO2/ SO

2011 ◽  
Vol 391-392 ◽  
pp. 1296-1301
Author(s):  
Li Min Xi ◽  
Xin Xin Zhang
Keyword(s):  
Direct Synthesis ◽  
Sol Gel ◽  
Acid Base ◽  
Direct Transformation ◽  
Acid Base Titration ◽  
Optimal Reaction Condition ◽  
Superacid Catalyst ◽  
Average Size ◽  
Optimal Reaction ◽  
Xrd And Tem

The newly sulfated nanosolid superacid TiO2/SO4 prepared by sol-gel method was broadly characterized by acid base titration, XRD and TEM, which identified that the superfine solid TiO2/SO4 showing good dispersibility with average size of 27 nm belongs to kind of crystalline nanoparticles. With the help of the catalyst TiO2/SO4, the optimal reaction condition for direct transformation of pyrazole and nitrosonitric acid into 3, 5-Dinitropyrazole was n (pyrazol)=0.10 mol, m (TiO2/SO4 )＝1.5g, V(n-octannol)＝90mL, and V(nitrosonitric acid)＝50mL. Moreover, the optimal yield of the catalytic reaction reached up to 59.4% when the reaction time is 7 hours. The nanosolid superacid catalyst is still of high activity after regenerating eight times by calcination at 600。C.

The influence of β-cyclodextrin on acid–base and tautomeric equilibrium of fluorescein dyes in aqueous solution

2010 ◽  
Vol 345 (13) ◽  
pp. 1882-1890 ◽  
Author(s):  
Larisa N. Bogdanova ◽  
Nikolay O. Mchedlov-Petrossyan ◽  
Natalya A. Vodolazkaya ◽  
Alexander V. Lebed
Keyword(s):  
Aqueous Solution ◽  
Tautomeric Equilibrium ◽  
Acid Base ◽  
Fluorescein Dyes
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