scholarly journals FTIR and Raman Spectral Research on Metamorphism and Deformation of Coal

2012 ◽  
Vol 2012 ◽  
pp. 1-8 ◽  
Author(s):  
Xiaoshi Li ◽  
Yiwen Ju ◽  
Quanlin Hou ◽  
Zhuo Li ◽  
Junjia Fan
Keyword(s):  
Structural Evolution ◽  
Tectonic Stress ◽  
Ductile Deformation ◽  
Frictional Heat ◽  
Structural Defects ◽  
Tectonic Deformation ◽  
Macromolecular Structure ◽  
Brittle Deformation ◽  
Metamorphic Stage ◽  
The Stability

Under different metamorphic environments, coal will form different types of tectonically deformed coal (TDC) by tectonic stress and even the macromolecular structure can be changed. The structure and composition evolution of TDC have been investigated in details using Fourier transform infrared spectroscopy and Raman spectroscopy. The ductile deformation can generate strain energy via increase of dislocation in molecular structure of TDC, and it can exert an obvious influence on degradation and polycondensation. The brittle deformation can generate frictional heat energy and promote the metamorphism and degradation, but less effect on polycondensation. Furthermore, degradation affects the structural evolution of coal in lower metamorphic stage primarily, whereas polycondensation is the most important controlling factor in higher metamorphic stage. Tectonic deformation can produce secondary structural defects in macromolecular structure of TDC. Under the control of metamorphism and deformation, the small molecules which break and fall off from the macromolecular structure of TDC are replenished and embedded into the secondary structural defects preferentially and form aromatic rings by polycondensation. These processes improved the stability of macromolecular structure greatly. It is easier for ductile deformation to induce secondary structural defects than in brittle deformation.

Macromolecular Structural Responses of Coking Coal to Stress–Strain Environments Based on High-Resolution Transmission Electron Microscopy

2021 ◽  
Vol 21 (1) ◽  
pp. 772-780
Author(s):  
Liang Guo ◽  
Zhenghui Qu ◽  
Zhiwen Xue ◽  
Hao Li ◽  
Bicheng Zhang ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Transmission Electron Microscopy ◽  
High Resolution ◽  
Tectonic Stress ◽  
Tectonic Deformation ◽  
Macromolecular Structure ◽  
Stress Strain ◽  
Coking Coal ◽  
Lattice Fringe ◽  
Transmission Electron

In China, most coal seams have experienced multiple phases of tectonics, which increase the complexity of the coal porosity. The responses of macromolecular structures to stress–strain environments are the key to understanding the complexity of coal porosity caused by tectonism. This study investigated the macromolecular structural response of coking coal to different stress–strain environments. The calculation and analysis of high-resolution transmission electron microscopy (HRTEM) test results for six coking coals with different deformation types and degrees were performed. The results showed that the macromolecular structure of coking coal has different responses to stress– strain environments. The lattice fringe length, curvature, and d002 parameters are not prominently governed by certain principles increasing shear and toughness. Furthermore, the lattice fringe tends to be consistent with the deformation. However, the lattice fringe during ductile deformation in the main direction is arranged nearly parallel on the plane. In shear deformation, the lattice fringes are arranged parallel in the principal direction. This phenomenon is caused by the directional screening of the macromolecular structure of coking coal by stress. Under the action of tectonic stress, the structure hindering tectonic stress is destroyed, and the structure grows in other directions gradually under the promotion of tectonic stress. As a result, the direction of the whole lattice fringe gradually converges under stress screening after tectonic stress is applied. Therefore, the direction tends to be consistent with the strengthening of the deformation. The response of the other parameters is slow, showing the coexistence of the old and new orders of direction. The directivity of the macromolecular structure of coal is an important index for reflecting the types and degrees of tectonic deformation.

scholarly journals Structural Characteristics and Physical Properties of Tectonically Deformed Coals

2012 ◽  
Vol 2012 ◽  
pp. 1-14 ◽  
Author(s):  
Yiwen Ju ◽  
Zhifeng Yan ◽  
Xiaoshi Li ◽  
Quanlin Hou ◽  
Wenjing Zhang ◽  
...  
Keyword(s):  
Physical Properties ◽  
Structural Characteristics ◽  
Nitrogen Adsorption ◽  
Ductile Deformation ◽  
Structural Deformation ◽  
Macromolecular Structure ◽  
Brittle Deformation ◽  
Adsorption Method ◽  
Pore Characteristics ◽  
Paramagnetic Resonance

Different mechanisms of deformation could make different influence on inner structure and physical properties of tectonically deformed coal (TDC) reservoirs. This paper discusses the relationship between macromolecular structure and physical properties of the Huaibei-Huainan coal mine areas in southern North China. The macromolecular structure and pore characteristics are systematically investigated by using techniques such as X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), electron paramagnetic resonance (EPR), nuclear magnetic resonance (NMR), and low-temperature nitrogen adsorption method. The results suggest that under the directional stress, basic structural units (BSU) arrangement is closer, and the orientation becomes stronger from brittle deformed coal to ductile deformed coal. Structural deformation directly influences the macromolecular structure of coal, which results in changes of pore structure. The nanoscale pores of the cataclastic coal structure caused by the brittle deformation are mainly mesopores, and the proportion of mesopores volume in ductile deformed coal diminishes rapidly. So the exploration and development potential of coalbed gas are good in reservoirs such as schistose structure coal, mortar structure coal and cataclastic structure coal. It also holds promise for a certain degree of brittle deformation and wrinkle structure coal of low ductile deformation or later superimposed by brittle deformation.

Chemical and boron isotopic variations of deformed tourmaline in the Laojunshan metamorphic dome, Southwest China: Implication for magmatic-hydrothermal evolution during exhumation

2021 ◽  
Author(s):  
Wei Li ◽  
Shuyun Cao ◽  
Eizo Nakamura ◽  
Tsutomu Ota ◽  
Tak Kunihiro ◽  
...  
Keyword(s):  
Southwest China ◽  
Structural Evolution ◽  
Potassium Feldspar ◽  
Ductile Deformation ◽  
Brittle Deformation ◽  
Great Opportunity ◽  
Fine Grained ◽  
Multi Stage ◽  
Isotopic Variations ◽  
Hydrothermal Veins

<p>Multi-stage tourmalines are widely developed in granitic gneisses and hydrothermal veins from the Laojunshan metamorphic dome, Southwest China. These tourmalines exhibit variable petrographic characteristics and microstructures by ductile deformation to brittle deformation, which offers a great opportunity to understand the fluid and structural evolution during exhumation of the Laojunshan metamorphic dome. Three types of tourmalines have been recognized, including disseminated tourmaline distributed in granitic gneisses (Tur-G), elongated and broken tourmalines in quartz veins (Tur-QV), needle-columnar and fine-grained tourmaline with micro-shear zone in tourmaline veins (Tur-TV). All the tourmalines belong to the alkali group representing dravite-schorl solid solution series. The former two types belong to schorl and the latte type contains more Mg-rich components. Models of occurrence and chemical varieties including Al-occupation at the Y-site suggest that the Tur-G type and Tur-QV type tourmalines crystallized from magmatic fluids and the Tur-TV type tourmalines are hydrothermal origin. Hydrothermal tourmalines are characterized by higher Mg/(Mg + Fe) ratios, more pronounced positive Eu anomalies, higher Li, Sr, HREE contents and lower Na/(Na + Ca) ratios, lower Nb, Zr, Hf, LREE contents compared with magmatic tourmalines. The increase of Mg/(Mg+Fe) ratios from the Tur-QV to Tur-TV type tourmalines is associated with the crystallization of Fe-rich mineral during hydrothermal stage. In the Tur-QV types, the decrease of Mg/(Mg+Fe) ratios and increase of Al and LREE contents from core to rim suggest the contamination from surrounding strata. The δ<sup>11</sup>B values of Tur-G, Tur-QV, Tur-TV type tourmalines are ranging from -13~-7.9‰, -15.5~-7.5‰, -18.6~-11.6‰ respectively, which suggests that the boron was mainly derived from granitic melt and exsolved hydrothermal fluid. Boron isotopic variations of tourmaline are mainly controlled by temperature and exsolved fluid. All the results of observations from outcrop to thin section scales and chemical analysis indicate the formation of disseminated tourmaline distributed in granitic gneisses (Tur-G) should have been associated with late stage of magma evolution before regional exhumation, while tourmalines in hydrothermal veins (Tur-QV and Tur-TV) have been formed by the magmatic-hydrothermal events during exhumation of Laojunshan metamorphic dome. The primary tourmalines experienced shearing and fracturing, and then were replaced by chlorite, potassium feldspar and epidote. The ductile-brittle deformation of tourmalines was produced by progressive strain localization accompanied by the alkaline, B-undersaturated fluids, indicating episodes of brittle fracturing, possibly as a consequence of faulting at depths and subsequent fluid flow during exhumation of the dome.</p>

scholarly journals Fault reactivation and strain partitioning across the brittle-ductile transition

Geology ◽  
2019 ◽  
Vol 47 (12) ◽  
pp. 1127-1130 ◽  
Author(s):  
Gabriel G. Meyer ◽  
Nicolas Brantut ◽  
Thomas M. Mitchell ◽  
Philip G. Meredith
Keyword(s):  
Fault Slip ◽  
Fault Reactivation ◽  
Ductile Deformation ◽  
Tectonic Deformation ◽  
Gradual Change ◽  
Bulk Rock ◽  
Total Deformation ◽  
Bulk Strain ◽  
Brittle Ductile Transition ◽  
Ductile Flow

Abstract The so-called “brittle-ductile transition” is thought to be the strongest part of the lithosphere, and defines the lower limit of the seismogenic zone. It is characterized not only by a transition from localized to distributed (ductile) deformation, but also by a gradual change in microscale deformation mechanism, from microcracking to crystal plasticity. These two transitions can occur separately under different conditions. The threshold conditions bounding the transitions are expected to control how deformation is partitioned between localized fault slip and bulk ductile deformation. Here, we report results from triaxial deformation experiments on pre-faulted cores of Carrara marble over a range of confining pressures, and determine the relative partitioning of the total deformation between bulk strain and on-fault slip. We find that the transition initiates when fault strength (σf) exceeds the yield stress (σy) of the bulk rock, and terminates when it exceeds its ductile flow stress (σflow). In this domain, yield in the bulk rock occurs first, and fault slip is reactivated as a result of bulk strain hardening. The contribution of fault slip to the total deformation is proportional to the ratio (σf − σy)/(σflow − σy). We propose an updated crustal strength profile extending the localized-ductile transition toward shallower regions where the strength of the crust would be limited by fault friction, but significant proportions of tectonic deformation could be accommodated simultaneously by distributed ductile flow.

scholarly journals Numerical Analyses on the Stability of a Deep Coalmine Roadway Passing through a Fault Zone: A Case Study of the Gugui Coalfield in China

Energies ◽  
2021 ◽  
Vol 14 (8) ◽  
pp. 2114
Author(s):  
Yongshui Kang ◽  
Congcong Hou ◽  
Jingyi Liu ◽  
Zhi Geng ◽  
Jianben Chen ◽  
...  
Keyword(s):  
Fault Zone ◽  
Distinct Element ◽  
Three Dimensional ◽  
Tectonic Stress ◽  
Three Dimensional Model ◽  
Support Strategy ◽  
Failure Theory ◽  
Calculation Results ◽  
Pass Through ◽  
The Stability

Massive deformation often occurs when deep coalmine roadways pass through a fault zone due to the poor integrity of rock mass and high tectonic stress. To study deformation characteristics of the surrounding rock in the fault zone of a coalmine, a roadway passing through the FD1041 fault zone in China’s Gugui coalfield was investigated in this research. The geo-stress characteristics of this fault zone were analyzed based on the Mohr failure theory. Furthermore, a three-dimensional model for the experimental roadway in the FD1041 fault zone was built and calculated by a numerical program based on the distinct element method. Stability conditions of the roadway, using several types of support methods, were calculated and compared. Calculation results indicated that pre-grouting provides favorable conditions for the stability of a roadway in a fault zone. Finally, an optimized support strategy was proposed and implemented in the experimental roadway. Monitored results demonstrated that the optimized support strategy is appropriate for this fault zone.

Structural Evolution Upon Annealing of Multi-Layer Si/Fe Thin Films Prepared by Magnetron Sputtering

2007 ◽  
Vol 561-565 ◽  
pp. 1161-1164
Author(s):  
Xiao Na Li ◽  
Bing Hu ◽  
Chuang Dong ◽  
Xin Jiang
Keyword(s):  
Thin Films ◽  
Magnetron Sputtering ◽  
Room Temperature ◽  
Structural Evolution ◽  
Radio Frequency Magnetron Sputtering ◽  
Transmission Electron ◽  
Direct Band ◽  
The Stability ◽  
Sputtering System

Fe/Si multi-layer films were fabricated on Si (100) substrates utilizing radio frequency magnetron sputtering system. Si/β-FeSi2 structure was found in the films after the deposition. Structural characterization of Fe-silicide sample was performed by transmission electron microscopy, to explore the dependence of the microstructure of β-FeSi2 film on the preparation parameters. It was found that β-FeSi2 particles were formed after the deposition without annealing, whose size is less than 20nm ,with a direct band-gap of 0.94eV in room temperature. After annealing at 850°C, particles grow lager, however the stability of thin films was still good.

New molecular insights into the stability of Ni–Pd hollow nanoparticles

2017 ◽  
Vol 4 (10) ◽  
pp. 1679-1690 ◽  
Author(s):  
Hamed Akbarzadeh ◽  
Esmat Mehrjouei ◽  
Amir Nasser Shamkhali ◽  
Mohsen Abbaspour ◽  
Sirous Salemi ◽  
...  
Keyword(s):  
Molecular Dynamics ◽  
Thermal Behavior ◽  
Molecular Dynamics Simulations ◽  
Structural Evolution ◽  
Hollow Nanoparticles ◽  
The Stability ◽  
Dynamics Simulations

Molecular dynamics simulations were used to investigate the structural evolution and thermal behavior of Ni–Pd hollow nanoparticles.

Growth of 4H-SiC Single Crystals on 6H-SiC Seeds with an Open Backside by PVT Method

2009 ◽  
Vol 615-617 ◽  
pp. 15-18 ◽  
Author(s):  
Emil Tymicki ◽  
Krzysztof Grasza ◽  
Katarzyna Racka ◽  
Marcin Raczkiewicz ◽  
Tadeusz Łukasiewicz ◽  
...  
Keyword(s):  
Single Crystals ◽  
Electron Backscatter Diffraction ◽  
Structural Defects ◽  
X Ray Diffraction ◽  
Force Microscopy ◽  
Optical Scanning ◽  
Atomic Force ◽  
The Stability ◽  
Backscatter Diffraction ◽  
Source Materials

4H-SiC single crystals grown by the seeded physical vapour transport method have been investigated. These crystals were grown on 6H-SiC seeds. The influence of the seed temperature, form and granulation of SiC source materials on the stability and efficiency of the 4H polytype growth have been investigated. A new way of the seed mounting - with an open backside - has been used. Crystals obtained were free of structural defects in the form of hexagonal voids. The crystalline structure of SiC crystals was investigated by EBSD (Electron Backscatter Diffraction) and X-Ray diffraction methods. Moreover, defects in crystals and wafers cut from these crystals were examined by optical, scanning electron and atomic force microscopy combined with KOH etching.

Entropy of Nanostructures

2017 ◽  
pp. 600-614
Author(s):  
Ottorino Ori ◽  
Franco Cataldo ◽  
Mihai V. Putz
Keyword(s):  
Mechanical Properties ◽  
Free Energy ◽  
Gibbs Free Energy ◽  
Defect Formation ◽  
Vacancy Concentration ◽  
Structural Evolution ◽  
Point Of View ◽  
Structural Defects ◽  
Formation Mechanisms ◽  
Topological Invariants

Recent advances in graphene studies deal with the influence of structural defects on graphene chemical, electrical, magnetic and mechanical properties. Here the complex mechanisms leading to the formation of clusters of vacancies in 2D honeycomb HD lattices are described by a pure topological point of view, aiming to correlate the variation of specific topological invariants, sensible to vacancy concentration, to the structural evolution of the defective networks driven by the topo-thermodynamical Gibbs free energy. Interesting predictions on defect formation mechanisms add details on the topological mechanisms featured by the graphenic structures with defects. Future roles of bondonic particles in defective HD materials are also envisaged.

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