scholarly journals Relationship between Rheological Behaviour and Final Structure ofAl2O3and YSZ Foams Produced by Replica

2012 ◽  
Vol 2012 ◽  
pp. 1-9 ◽  
Author(s):  
S. Y. Gómez ◽  
O. A. Alvarez ◽  
J. A. Escobar ◽  
J. B. Rodrigues Neto ◽  
C. R. Rambo ◽  
...  
Keyword(s):  
Mechanical Performance ◽  
Raw Materials ◽  
Rheological Behaviour ◽  
Rheological Parameters ◽  
Ceramic Structure ◽  
Ceramic Foams ◽  
Different Types ◽  
Binder Type ◽  
Ceramic Suspensions ◽  
Ceramic Thickness

Using rheological parameters of ceramic suspensions, it is possible to taylor the structure of the ceramic foams produced by replica. This method consists in the impregnation of a polymeric flexible template (polyurethane foam) with a ceramic suspension (slurry) containing the appropriate additives, followed by burning out organic compounds and additives and sintering the ceramic structure. In this work, ceramic foams were produced by the replica method from Al2O3and 3% Y2O3-ZrO2. Rheological parameters of the ceramic suspensions were investigated to improve the mechanical performance of final structures. Different types and quantities of raw materials were combined in order to select the formulations for ceramic foams. The parameters that have a significant influence on the process are the binder type and the amount of solids. Significant changes on the hysteresis area of the suspensions resulted in a lower density of macrodefects in the material. Likewise, when the shear rate viscosity is enhanced, the thickness of the struts increased proportionally. Lastly, when the hysteresis area magnitude and the ceramic thickness increased, the material with higher uniformity was internally densified, and the stress concentration of the internal defects was smoothed

scholarly journals Effect of Moisture on the Behaviour of an Extruded Clay Paste

2013 ◽  
Vol 554-557 ◽  
pp. 2230-2236
Author(s):  
Jérémie Vignes ◽  
Fabrice Schmidt ◽  
Gilles Dusserre ◽  
Jean Frédéric Dalmasso
Keyword(s):  
Inverse Analysis ◽  
Linear Models ◽  
Raw Materials ◽  
Industrial Process ◽  
Rheological Behaviour ◽  
Rheological Parameters ◽  
Compression Tests ◽  
State Of Stress ◽  
Constitutive Parameters ◽  
Force Displacement

In the industrial process, the moisture of the clay sheet obtained by extrusion and pressed to form a tile varies in time. It depends on the nature and the mixing of the raw materials during the production. In order to model and undersand the influence of the moisture on the pressing step, it is necessary to determine the parameters of the rheological and tribological laws. A study of the rheological behaviour, based on free compression tests on cylinder samples, allowed to use an elasto-visco-plastic behaviour for the extruded clay paste. The different constitutive parameters were estimated by an inverse analysis based on the experimental force/displacement curves. The identification was performed with the optimisation algorithm implemented in the commercial software Forge® 2009. The influence of the water content in the paste on the rheological parameters was identified and fitted using linear models. The friction factor was measured from tests on a rectilign tribometer. To understand the influence of the moisture, we simulated a compression test, using Forge® involving the shaping of a tile lug. This geometry is representative of the state of stress during the pressing of the tile, in an area currently sujected to defects. The numerical model show that an increase of eighteen percent of the moisture allows to decrease by half the pressing force.

scholarly journals Valorization of vinasse as binder modifier in asphalt mixtures

DYNA ◽  
2015 ◽  
Vol 82 (194) ◽  
pp. 52-56
Author(s):  
MARIA JOSE MARTINEZ-ECHEVARRIA ROMERO ◽  
Gema García-Travé ◽  
Mª Carmen Rubio-Gámez ◽  
Fernando Moreno-Navarro ◽  
Domingo Pérez-Mira
Keyword(s):  
Plastic Deformation ◽  
Mechanical Performance ◽  
Raw Materials ◽  
Asphalt Mixtures ◽  
Industrial Processes ◽  
Construction Sector ◽  
Moisture Sensitivity ◽  
Asphalt Mixes ◽  
Technical Research ◽  
Different Types

The reutilization of waste generated by industrial processes has become a majorenvironmental objective in scientific and technical research. In the construction sector, there is a broad range of techniques for the exploitation of different types of waste, which can then be used as a replacement for raw materials. This paper presents the results of a study of vinasse, a by-product of biomass ethanol, andanalyzes its viability as a bitumen modifier in asphalt mixes. For this purpose, four AC-16S asphalt mixes were evaluated for moisture sensitivity, plastic deformation, stiffness, and fatigue. The mix formulas were the following: (Mix 1) 50/70 bitumen; (Mix 2) 50/70 bitumen modified with 10% vinasse; (Mix 3) rubber bitumen; (Mix 4) rubber bitumen modified with 10% vinasse. The results of this study showed that bitumen modified with vinasse improved the mechanical performance of the AC-16S mix and also contributed to the valorization of vinasse waste.

PU composites based on different types of textile fibers

2021 ◽  
pp. 002199832110316
Author(s):  
Nuno Gama ◽  
B Godinho ◽  
Ana Barros-Timmons ◽  
Artur Ferreira
Keyword(s):  
Thermal Conductivity ◽  
Raw Materials ◽  
Natural Fibers ◽  
Tensile Modulus ◽  
High Water ◽  
Textile Fibers ◽  
Synthetic Fibers ◽  
Hydrophilic Nature ◽  
Different Types ◽  
Recycled Composites

In this study polyurethane (PU) residues were mixed with residues of textile fibers (cotton, wool and synthetic fibers up to 70 wt/wt) to produce 100% recycled composites. In addition, the effect of the type of fiber on the performance of the ensuing composites was evaluated. The presence of fibers showed similar effect on the density, reducing the density in the 5.5-9.0% range. In a similar manner, the addition of fillers decreased their thermal conductivity. The 70 wt/wt wool composite presented 38.1% lower thermal conductivity when compared to the neat matrix, a reduction that was similar for the other type of fibers. Moreover, the presence of fillers yields stiffer materials, especially in the case of the Wool based composites, which with 70 wt/wt of filler content increased the tensile modulus of the ensuing material 3.4 times. This was attributed to the aspect ratio and stiffness of this type of fiber. Finally, the high-water absorption and lower thermal stability observed, especially in the case of the natural fibers, was associated with the hydrophilic nature of fibers and porosity of composites. Overall, the results suggest that these textile-based composites are suitable for construction and automotive applications, with the advantage of being produced from 100% recycled raw-materials, without compromised performance.

scholarly journals Crushed Bricks: Demolition Waste as a Sustainable Raw Material for Geopolymers

2021 ◽  
Vol 13 (14) ◽  
pp. 7572
Author(s):  
Gigliola D’Angelo ◽  
Marina Fumo ◽  
Mercedes del Rio Merino ◽  
Ilaria Capasso ◽  
Assunta Campanile ◽  
...  
Keyword(s):  
Energy Consumption ◽  
Building Materials ◽  
Mechanical Performance ◽  
Raw Materials ◽  
Construction Material ◽  
Raw Material ◽  
The European Union ◽  
Total Energy Consumption ◽  
Demolition Waste ◽  
Crushed Brick

Demolition activity plays an important role in the total energy consumption of the construction industry in the European Union. The indiscriminate use of non-renewable raw materials, energy consumption, and unsustainable design has led to a redefinition of the criteria to ensure environmental protection. This article introduces an experimental plan that determines the viability of a new type of construction material, obtained from crushed brick waste, to be introduced into the construction market. The potential of crushed brick waste as a raw material in the production of building precast products, obtained by curing a geopolymeric blend at 60 °C for 3 days, has been exploited. Geopolymers represent an important alternative in reducing emissions and energy consumption, whilst, at the same time, achieving a considerable mechanical performance. The results obtained from this study show that the geopolymers produced from crushed brick were characterized by good properties in terms of open porosity, water absorption, mechanical strength, and surface resistance values when compared to building materials produced using traditional technologies.

scholarly journals Analytical Rheology of Honey: A State-of-the-Art Review

Foods ◽  
2021 ◽  
Vol 10 (8) ◽  
pp. 1709
Author(s):  
Célia Faustino ◽  
Lídia Pinheiro
Keyword(s):  
Sugar Content ◽  
Rheological Behaviour ◽  
Principal Component ◽  
Rheological Parameters ◽  
Experimental Conditions ◽  
Thixotropic Behaviour ◽  
Ancient Times ◽  
Medicinal Properties ◽  
Complex Relationships ◽  
Temperature Time

Honey has been used as a nutraceutical product since ancient times due to its nutritional and medicinal properties. Honey rheology influences its organoleptic properties and is relevant for processing and quality control. This review summarizes the rheological behaviour of honeys of different botanical source(s) and geographical locations that has been described in the literature, focusing on the relation between rheological parameters, honey composition (moisture, water activity, sugar content, presence of colloidal matter) and experimental conditions (temperature, time, stress, shear rate). Both liquid and crystallized honeys have been addressed. Firstly, the main mathematical models used to describe honey rheological behaviour are presented highlighting moisture and temperature effects. Then, rheological data from the literature regarding distinct honey types from different countries is analysed and results are compared. Although most honeys are Newtonian fluids, interesting shear-thinning and thixotropic as well as anti-thixotropic behaviour have been described for some types of honey. Rheological parameters have also been successfully applied to identify honey adulteration and to discriminate between different honey types. Several chemometric techniques have also been employed to obtain the complex relationships between honey physicochemical and rheological properties, including partial least squares (PLS), principal component analysis (PCA) and artificial neural networks (ANN).

scholarly journals Modified Nanoclays/Straw Fillers as Functional Additives of Natural Rubber Biocomposites

Polymers ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 799
Author(s):  
Justyna Miedzianowska ◽  
Marcin Masłowski ◽  
Przemysław Rybiński ◽  
Krzysztof Strzelec
Keyword(s):  
Natural Rubber ◽  
Raw Materials ◽  
Research Work ◽  
Damping Properties ◽  
Main Research ◽  
Functional Additives ◽  
Different Types ◽  
Elastomeric Materials ◽  
Research Goal ◽  
The Impact

Increasingly, raw materials of natural origin are used as fillers in polymer composites. Such biocomposites have satisfactory properties. To ensure above-average functional properties, modifications of biofillers with other materials are also used. The presented research work aimed to produce and characterize elastomeric materials with a straw-based filler and four different types of montmorillonite. The main research goal was to obtain improved functional parameters of vulcanizates based on natural rubber. A series of composites filled with straw and certain types of modified and unmodified nano-clays in various ratios and amounts were prepared. Then, they were subjected to a series of tests to assess the impact of the hybrids used on the final product. It has been shown that the addition of optimal amounts of biofillers can, inter alia, increase the tensile strength of the composite, improve damping properties, extend the burning time of the material and affect the course of vulcanization or cross-linking density.

Research on Properties of Low Grade Cement-Based Composite Materials Modified by Silica Fume

2012 ◽  
Vol 174-177 ◽  
pp. 751-756
Author(s):  
Zi Fang Xu ◽  
Ming Xu Zhang ◽  
Jin Hua Li
Keyword(s):  
Silica Fume ◽  
Mechanical Performance ◽  
Raw Materials ◽  
Cement Matrix ◽  
Hardened Cement ◽  
Low Grade ◽  
X Ray ◽  
Matrix Microstructure ◽  
Nano Powder ◽  
Strength And Durability

In order to notably improve the mechanical properties and durability of low-grade cement-based material, superfine silica fume was used to modify the cement-based composite based on special perfomance and effects of nano powder. The mechanical performance and durability were investigated.Then the phase compositions,microstructure and morphologies of as-received cement-based composite were studied by X-ray Diffractometer、TGA-DTA and SEM. The results show that： the best formula of raw materials is 1:1:0.025:0.015, and hydration can be accelerated and increasing of hydration products is observed after modification. In the hardened cement matrix, microstructure is very compacted and C-S-H gel forms densed structure, so the structure defect is notably reduced. This means that both strength and durability of cement-based composite are notably improved by the addition of superfine silica fume.

Adhesives for the Installation of Cast Basalt Elements on Metal and Comparison of Properties when Using Different Types of Fillers

2021 ◽  
Vol 898 ◽  
pp. 35-41
Author(s):  
Jakub Hodul ◽  
Tomáš Žlebek ◽  
Lenka Mészárosová ◽  
Aleš Jakubík ◽  
Rostislav Drochytka
Keyword(s):  
Construction Industry ◽  
Raw Materials ◽  
Physical And Mechanical Properties ◽  
Mineral Admixtures ◽  
Maximum Efficiency ◽  
Organic Additives ◽  
Metal Base ◽  
Secondary Raw Materials ◽  
Ecological Benefit ◽  
Different Types

The polymeric adhesives for the installation of basalt elements on a metal base are designed primarily for environments with increased chemical and mechanical stress. They are composed of polymer resins (epoxy, polyurethane) as binders, as well as organic additives and mineral admixtures that mainly fulfill the function of filler. In all sectors of today's construction industry, maximum efficiency in the production of materials is required for sustainability purposes, which, however, must never be at the expense of the quality or the required performance. Due to these requirements, great emphasis is placed on the maximum use of secondary raw materials. Talc is used as the primary filler for polymer adhesives. Sawdust, tire rubber, and fly ash are used as secondary raw materials. The use of these in building supplies can positively affect some physical and mechanical properties of polymeric adhesives. Also, the use of secondary raw materials has the above-mentioned ecological benefit. Basic properties, such as bulk density and adhesion to both metallic and basalt elements, were monitored. The details of the cohesion of the adhesive with the bonded material, as well as the distribution of secondary raw materials in the polymer matrix, were assessed microscopically.

Hierarchical Design and Nanomechanics of the Calcified Byssus of Anomia simplex

2009 ◽  
Vol 1187 ◽  
Author(s):  
Jakob R Eltzholtz ◽  
Marie Krogsgaard ◽  
Henrik Birkedal
Keyword(s):  
Electron Microscopy ◽  
Mechanical Properties ◽  
Scanning Electron Microscopy ◽  
Mechanical Performance ◽  
Blue Mussel ◽  
Hierarchical Design ◽  
Reduced Modulus ◽  
Different Types ◽  
Microscopy Images ◽  
Scanning Electron

AbstractBiology has evolved several strategies for attachment of sedentary animals. In the bivalves, byssi abound and the best known example being the protein-based byssus of the blue mussel and other Mytilidae. In contrast the bivalve Anomia sp. has a single calcified thread. The byssus is hierarchical in design and contains several different types of structures as revealed by scanning electron microscopy images. The mechanical properties of the byssus are probed by nanoindentation. It is found that the mineralized part of the byssus is very stiff with a reduced modulus of about 67 GPa and a hardness of ˜3.7 GPa. This corresponds to a modulus roughly 20% smaller than that of pure calcite and a hardness that is about 20% larger than pure calcite. The results reveal the importance of microstructure on mechanical performance.

scholarly journals Live-Scale Testing of Granular Materials Stabilized with Alkali-Activated Waste Glass and Carbide Lime

2021 ◽  
Vol 11 (23) ◽  
pp. 11286
Author(s):  
Marina Paula Secco ◽  
Débora Thaís Mesavilla ◽  
Márcio Felipe Floss ◽  
Nilo Cesar Consoli ◽  
Tiago Miranda ◽  
...  
Keyword(s):  
Portland Cement ◽  
Mechanical Performance ◽  
Raw Materials ◽  
Sodium Hydroxide Solution ◽  
Fine Sand ◽  
Field Application ◽  
Natural Soil ◽  
In Situ Tests ◽  
Alkali Activated

The increasingly strong search for alternative materials to Portland cement has resulted in the development of alkali-activated cements (AAC) that are very effective at using industrial by-products as raw materials, which also contributes to the volume reduction in landfilled waste. Several studies targeting the development of AAC—based on wastes containing silicon and calcium—for chemical stabilization of soils have demonstrated their excellent performance in terms of durability and mechanical performance. However, most of these studies are confined to a laboratory characterization, ignoring the influence and viability of the in situ construction process and, also important, of the in situ curing conditions. The present work investigated the field application of an AAC based on carbide lime and glass wastes to stabilize fine sand acting as a superficial foundation. The assessment was supported on the unconfined compressive strength (UCS) and initial shear modulus (G0) of the developed material, and the field results were compared with those prepared in the laboratory, up to 120 days curing. In situ tests were also developed on the field layers (with diameters of 450 and 900 mm and thickness of 300 mm) after different curing times. To establish a reference, the mentioned precursors were either activated with a sodium hydroxide solution or hydrated with water (given the reactivity of the lime). The results showed that the AAC-based mixtures developed greater strength and stiffness at a faster rate than the water-based mixtures. Specimens cured under controlled laboratory conditions showed better results than the samples collected in the field. The inclusion of the stabilized layers clearly increased the load-bearing capacity of the natural soil, while the different diameters produced different failure mechanisms, similar to those found in Portland cement stabilization.

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