scholarly journals Contribution of Dissolved Oxygen to Methylene Blue Decomposition by Hybrid Advanced Oxidation Processes System

2012 ◽  
Vol 2012 ◽  
pp. 1-6 ◽  
Author(s):  
Heon Lee ◽  
Sung Hoon Park ◽  
Byung Hoon Kim ◽  
Sun-Jae Kim ◽  
Sang-Chai Kim ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Dissolved Oxygen ◽  
Advanced Oxidation Processes ◽  
Reaction Rate ◽  
Organic Pollutant ◽  
High Concentration ◽  
Decomposition Rate Constant ◽  
Experimental Conditions ◽  
Solution Treated ◽  
Do Concentration

Experimental results of photocatalysis under high dissolved oxygen (DO) concentration conditions are reported. Methylene blue was used as the organic pollutant to be degraded by a novel microwave/UV/DO/TiO2photocatalyst hybrid system. The degradation rate increased with TiO2nanoparticle dosages and DO concentration. However, inhibition of photocatalysis due to bubbles produced by DO generator was also observed. When the DO generator was used to increase the DO concentration in the pollutant solution treated by the microwave-assisted UV-TiO2photocatalysis, the decomposition rate constant was highest among all the experimental conditions tested in this study. This result demonstrated that high concentration of DO can enhance the photocatalytic reaction rate by causing a synergistic effect of constituent techniques.

Applications of Advanced Oxidation Processes in Palm Oil Mill Effluent Treatment

2019 ◽  
pp. 123-149
Author(s):  
Azmi Aris ◽  
Muhammad Noor Hazwan Jusoh ◽  
Nurul Shakila Ahmad Abdul Wahab
Keyword(s):  
Hydroxyl Radicals ◽  
Palm Oil ◽  
Advanced Oxidation Processes ◽  
Advanced Oxidation ◽  
Effluent Treatment ◽  
Palm Oil Mill Effluent ◽  
High Concentration ◽  
Experimental Conditions ◽  
Oxidation Processes ◽  
Palm Oil Mill

This chapter presents a review on limited studies that have been conducted using advanced oxidation processes (AOPs) in treating biologically treated palm oil mill effluent. Palm oil mill effluent is the byproducts of palm oil production that is normally treated using a series of biological processes. However, despite being treated for a long period of retention time, the effluent still possesses high concentration of organics, nutrients, and highly colored, and will pollute the environment if not treated further. Advanced oxidation processes that utilized hydroxyl radicals as their oxidizing agents have the potential of further treating the biologically treated POME. Fenton oxidation, photocatalysis, and cavitation are the main AOPs that have been studied in polishing the biologically treated POME. Depending on the experimental conditions, the removal of organics, in terms of COD, TOC, and color, could reach up to more than 90%. Nevertheless, each of this process has its own limitations and further studies are needed to overcome these limitations.

scholarly journals Synthesis of a MnO2/Fe3O4/diatomite nanocomposite as an efficient heterogeneous Fenton-like catalyst for methylene blue degradation

2018 ◽  
Vol 9 ◽  
pp. 1940-1950 ◽  
Author(s):  
Zishun Li ◽  
Xuekun Tang ◽  
Kun Liu ◽  
Jing Huang ◽  
Yueyang Xu ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Cost Efficiency ◽  
Reaction Rate ◽  
Organic Pollutant ◽  
Layer By Layer ◽  
Heterogeneous Fenton ◽  
Fast Reaction ◽  
Methylene Blue Degradation ◽  
Ph Range ◽  
Fast Reaction Rate

Heterogeneous Fenton-like catalysts with the activation of peroxymonosulfate (PMS), which offer the advantages of fast reaction rate, wide functional pH range and cost efficiency, have attracted great interest in wastewater treatment. In this study, a novel magnetic MnO2/Fe3O4/diatomite nanocomposite is synthesized and then used as heterogeneous Fenton-like catalyst to degrade the organic pollutant methylene blue (MB) with the activation of PMS. The characterization results show that the Fe3O4 nanoparticles and nanoflower-like MnO2 are evenly distributed layer-by-layer on the surface of diatomite, which can be readily magnetically separated from the solution. The as-prepared catalyst, compared with other Fenton-like catalysts, shows a superb MB degradation rate of nearly 100% in 45 min in the pH range of 4 to 8 and temperature range of 25 to 55 °C. Moreover, the nanocomposite shows a good mineralization rate of about 60% in 60 min and great recyclability with a recycle efficiency of 86.78% after five runs for MB. The probable mechanism of this catalytic system is also proposed as a synergistic effect between MnO2 and Fe3O4.

scholarly journals Electron generation in water induced by magnetic effect and its impact on dissolved oxygen concentration

2021 ◽  
Vol 31 (1) ◽  
Author(s):  
Augustine Chung Wei Yap ◽  
Hwang Sheng Lee ◽  
Joo Ling Loo ◽  
Nuruol Syuhadaa Mohd
Keyword(s):  
Water Quality ◽  
Hydrogen Bonding ◽  
Dissolved Oxygen ◽  
Electron Density ◽  
Water Flow ◽  
Magnetic Effect ◽  
Water Quality Control ◽  
Electron Generation ◽  
Magnetic Effects ◽  
Do Concentration

AbstractpH, oxidation-reduction potential (ORP) and dissolved oxygen (DO) concentration are important parameters in water quality surveillance and treatment. The changes of these parameters are associated with electron density in water. Several techniques including electrolysis and catalysis which require redox reactions and electron exchange are employed to improve these parameters. In recent years, studies reported that magnetic effects can impart considerable changes on the pH, ORP and DO concentration of water. However, the correlation between electron density and magnetic effects on these parameters has yet to be disclosed despite the fact that increased electron density in water could improve water’s reductive properties, heat capacity and hydrogen bonding characteristics. In this study, the magnetic effects on pH, ORP and DO concentration were investigated using different magnets arrangements and water flow rates based on reversed electric motor principle. Results showed that the improvement of pH, ORP and DO concentration from 5.40–5.42 to 5.58–5.62 (+ 3.5%), 392 to 365 mV (− 6.9%), and 7.30 to 7.71 mg L− 1 (+ 5.6%), respectively were achieved using combined variables of non-reversed polarity magnet arrangement (1000–1500 G magnetic strength) and water flow rate of 0.1–0.5 mL s− 1. Such decrement in ORP value also corresponded to 8.0 × 1013 number of electron generation in water. Furthermore, Raman analysis revealed that magnetic effect could strengthen the intermolecular hydrogen bonding of water molecules and favor formation of smaller water clusters. The findings of this study could contribute to potential applications in aquaculture, water quality control and treatment of cancer attributed to free radical induced-oxidative stress.

scholarly journals Limnology of Merbok estuary, Kedah, Malaysia

2015 ◽  
Vol 41 (1) ◽  
pp. 13-19
Author(s):  
Kaniz Fatema ◽  
Wan Maznah Wan Omar ◽  
Mansor Mat Isa
Keyword(s):  
Water Quality ◽  
Dissolved Oxygen ◽  
Suspended Solids ◽  
Total Suspended Solids ◽  
Quality Parameters ◽  
The Other ◽  
Wet Season ◽  
Hand Temperature ◽  
Do Concentration ◽  
Merbok Estuary

Water quality in three different stations of Merbok estuary was investigated limnologically from October, 2010 to September, 2011. Water temperature, transparency and total suspended solids (TSS) varied from 27.45 - 30.450C, 7.5 - 120 cm and 10 -140 mg/l, respectively. Dissolved Oxygen (DO) concentration ranged from 1.22-10.8 mg/l, while salinity ranged from 3.5-35.00 ppt. pH and conductivity ranged from 6.35 - 8.25 and 40 - 380 ?S/cm, respectively. Kruskal Wallis H test shows that water quality parameters were significantly different among the sampling months and stations (p<0.05). This study revealed that DO, salinity, conductivity and transparency were higher in wet season and TSS was higher in dry season. On the other hand, temperature and pH did not follow any seasonal trends.Bangladesh J. Zool. 41(1): 13-19, 2013

Automated sequencing batch bioreactor under extreme peaks of 4-chlorophenol

2003 ◽  
Vol 47 (10) ◽  
pp. 175-181 ◽  
Author(s):  
G. Buitrón ◽  
M.-E. Schoeb ◽  
J. Moreno
Keyword(s):  
Dissolved Oxygen ◽  
Metabolic Activity ◽  
Automated System ◽  
Stable Operation ◽  
High Concentration ◽  
Batch Bioreactor ◽  
On Line ◽  
The Moment ◽  
And Control ◽  
System Operating

The operation of a sequencing batch bioreactor is evaluated when high concentration peaks of a toxic compound (4-chlorophenol, 4CP) are introduced into the reactor. A control strategy based on the dissolved oxygen concentration, measured on line, is utilized. To detect the end of the reaction period, the automated system search for the moment when the dissolved oxygen has passed by a minimum, as a consequence of the metabolic activity of the microorganisms and right after to a maximum due to the saturation of the water (similar to the self-cycling fermentation, SCF, strategy). The dissolved oxygen signal was sent to a personal computer via data acquisition and control using MATLAB and the SIMULINK package. The system operating under the automated strategy presented a stable operation when the acclimated microorganisms (to an initial concentration of 350 mg 4CP/L), were exposed to a punctual concentration peaks of 600 mg 4CP/L. The 4CP concentrations peaks superior or equals to 1,050 mg/L only disturbed the system from a short to a medium term (one month). The 1,400 mg/L peak caused a shutdown in the metabolic activity of the microorganisms that led to the reactor failure. The biomass acclimated with the SCF strategy can partially support the variations of the toxic influent since, at the moment in which the influent become inhibitory, there is a failure of the system.

Reoxygenation Rate for Airlift Inner Circulation Reactor

2013 ◽  
Vol 726-731 ◽  
pp. 1926-1929
Author(s):  
Ke Wu Pi ◽  
Min Xia ◽  
Shi Shi ◽  
Qu Xiao
Keyword(s):  
Dissolved Oxygen ◽  
Aeration Rate ◽  
Airlift Reactor ◽  
Liquid Level ◽  
Aeration Tank ◽  
Do Concentration

Airlift inner circulation reactor (AICR) consisting of beaker and built-in aeration tank was introduced in this paper. The Dissolved oxygen recovery (RDO) was highly influenced by the ratios of the height of built-in aeration tank to the height of liquid level in reactor (Rh/H), the diameter of built-in aeration tank to the diameter of the reactor (Rd/D) and aeration rate (QN). Average RDO of 24.25 m.gm-3.s-s and DO concentration of 8.97mg.l-1 were obtained at Rd/D=0.47, Rh/H=0.68 and QN =1.0m3.m-3.min-1 for aerating 370s at 17°C. The total transferred oxygen in 4L deoxidized water reached 35.89mg, which had an increase by 11.15% than that of the traditional airlift reactor (AR). The DO concentration was 88.33-9.34mg.l-1 for AICR, but it’s only 7.71-8.58mg.l-1 for AR.

Photocatalytic Degradation of Methylene Blue over Co-Ag3VO4 under Visible Light Irradiation

2011 ◽  
Vol 335-336 ◽  
pp. 1385-1390 ◽  
Author(s):  
Shuo Wiei Zhao ◽  
Hui Xu ◽  
Hua Ming Li ◽  
Yuan Guo Xu
Keyword(s):  
Methylene Blue ◽  
Photocatalytic Activity ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Absorption Edge ◽  
Diffuse Reflectance Spectroscopy ◽  
Dye Degradation ◽  
Light Irradiation ◽  
Experimental Conditions ◽  
X Ray

In order to improve the photocatalytic activity, Co was successfully loaded into Ag3VO4 by using impregnation process. The samples were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), energy-dispersive X-ray spectroscopy (EDS) and diffuse reflectance spectroscopy (DRS). The XRD and SEM–EDS analyses revealed that Co ion was dispersed on Ag3VO4. The DRS results indicated that the absorption edge of the Co–Ag3VO4 catalyst shifted to longer wavelength. The enhanced photocatalytic activity of Co–Ag3VO4 for Methylene Blue(MB) dye degradation under visible light irradiation was due to its wider absorption edge and higher separation rate of photo-generated electron and holes. In the experimental conditions, it is demonstrated that the MB was effectively degraded by more than 95% within 40 min when the Co–Ag3VO4 catalyst was calcined at 300°C with 1 wt.% Co content.

Schistosoma mansoni: tail loss in relation to permeability changes during cercaria–schistosomulum transformation

Parasitology ◽  
1975 ◽  
Vol 71 (1) ◽  
pp. 9-18 ◽  
Author(s):  
R. E. Howells ◽  
S. E. Gerken ◽  
F. J. Pinto-Ramalho ◽  
U. Kawazoe ◽  
G. Gazzinelli ◽  
...  
Keyword(s):  
Amino Acids ◽  
Methylene Blue ◽  
Schistosoma Mansoni ◽  
Body Region ◽  
Experimental Conditions ◽  
General Body ◽  
Tail Loss ◽  
Permeability Changes ◽  
Extensive Lesion ◽  
Scanning Electron

The hind-body region of Schistosoma mansoni cercariae observed in the scanning electron microscope demonstrates various stages of contraction which may be compared with those of living larvae which are secreting the acetabular gland contents.No evidence for an extensive lesion was found in cercarial bodies which had shed their tails under experimental conditions. Experiments on the permeability of the larvae to sodium fluoride, methylene blue and amino acids demonstrated that tail loss significantly affects the permeability of the bodies although the effect is greater immediately after decaudation than at later times. Subsequent increases in permeability may be correlated with a change in the general body surface.

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