scholarly journals Electronic Structure of BiFe1−xMnxO3Thin Films Investigated by X-Ray Absorption Spectroscopy

2012 ◽  
Vol 2012 ◽  
pp. 1-7 ◽  
Author(s):  
Abduleziz Ablat ◽  
Emin Muhemmed ◽  
Cheng Si ◽  
Jiaou Wang ◽  
Haijie Qian ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Absorption Spectroscopy ◽  
Causal Relation ◽  
Structural Phase ◽  
X Ray Diffraction ◽  
Doping Amount ◽  
X Ray ◽  
Mn Content ◽  
Mn Substitution ◽  
X Ray Absorption

Multiferroic polycrystalline BiFe1-xMnxO3(0≤x≤0.3) thin films have been prepared on the Pt(111)/Ti/SiO2/Si(100) substrates by pulsed laser deposition method. The influence of Mn substitution on the electronic structure and magnetic properties has been studied. X-ray diffraction spectroscopy shows that Mn substitution slightly modulates crystal structure of the BiFe1-xMnxO3system within the same structural phase. According to FeLedge X ray absorption spectroscopy, Fe ions are found to be formally trivalent for doping amountxin BiFe1-xMnxO3. The enhanced magnetization by increasing Mn content is attributed to an alternation degree of hybridization between Fe 3d-O 2pand Mn 3d-O 2porbitals, basing on the carefully examined FeLand OKedge X-ray absorption spectroscopy. The crystal structural and the electronic structural results show a causal relation between them by demonstrating intrinsic mutual dependence between respective variations.

Effect of Mn substitution on electronic structure of Ca9Y(PO4)7:Eu2+, Mn2+ phosphor determined by X-ray absorption spectroscopy

2011 ◽  
Vol 515 (4-6) ◽  
pp. 245-248 ◽  
Author(s):  
Y.R. Lu ◽  
C.H. Huang ◽  
T.M. Chen ◽  
J.H. Lin ◽  
Y.R. Ma ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Absorption Spectroscopy ◽  
X Ray ◽  
Mn Substitution ◽  
X Ray Absorption

The Relative Merits of Oxides of Hafnium, Cerium and Thorium as Surrogates for Plutonium Oxide in Calcium Phosphate Ceramics

2009 ◽  
Vol 1193 ◽  
Author(s):  
B. L. Metcalfe ◽  
S. K. Fong ◽  
L. A. Gerrard ◽  
I. W. Donald ◽  
E. S. Welch ◽  
...  
Keyword(s):  
Calcium Phosphate ◽  
Calcination Temperature ◽  
Cerium Oxide ◽  
Absorption Spectroscopy ◽  
Hafnium Oxide ◽  
Intermediate Level ◽  
X Ray Diffraction ◽  
X Ray ◽  
X Ray Absorption ◽  
Additional Phase

AbstractThe choice of surrogate for plutonium oxide for use during the initial stages of research into the immobilization of intermediate level pyrochemical wastes containing plutonium andamericium oxides in a calcium phosphate host has been investigated by powder X-ray diffraction and X-ray absorption spectroscopy. Two non-radioactive surrogates, hafnium oxide and cerium oxide, together with radioactive thorium oxide were compared. Similarities in behaviour were observed for all three surrogates when calcined at the lowest temperature, 750°C but differences became more pronounced as the calcination temperature was increased to 950°C. Although some reaction occurred between all the surrogates and the host to form a substituted whitlockite phase, increasing the temperature led to a significant increase in the cerium reaction and the formation of an additional phase, monazite. Additionally it was observed that the cerium became increasingly trivalent at higher temperatures.

Electronic structure and magnetic states inLa1−xSrxCoO3studied by photoemission and x-ray-absorption spectroscopy

1997 ◽  
Vol 56 (3) ◽  
pp. 1290-1295 ◽  
Author(s):  
T. Saitoh ◽  
T. Mizokawa ◽  
A. Fujimori ◽  
M. Abbate ◽  
Y. Takeda ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Absorption Spectroscopy ◽  
X Ray ◽  
Magnetic States ◽  
X Ray Absorption

scholarly journals Mechanism of pressure induced amorphization of SnI4: A combined x-ray diffraction—x-ray absorption spectroscopy study

2020 ◽  
Vol 153 (6) ◽  
pp. 064501
Author(s):  
Emiliano Fonda ◽  
Alain Polian ◽  
Toru Shinmei ◽  
Tetsuo Irifune ◽  
Jean-Paul Itié
Keyword(s):  
Absorption Spectroscopy ◽  
Spectroscopy Study ◽  
X Ray Diffraction ◽  
X Ray ◽  
X Ray Absorption

Chromium Environment within Cr-Doped BaAl2O4: Correlation of X-ray Diffraction and X-ray Absorption Spectroscopy Investigations

2015 ◽  
Vol 54 (23) ◽  
pp. 11127-11135 ◽  
Author(s):  
Martina Vrankić ◽  
Biserka Gržeta ◽  
Dirk Lützenkirchen-Hecht ◽  
Sanja Bosnar ◽  
Ankica Šarić
Keyword(s):  
Absorption Spectroscopy ◽  
X Ray Diffraction ◽  
X Ray ◽  
X Ray Absorption
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