scholarly journals Diffraction Measurements and Equilibrium Parameters

2011 ◽  
Vol 2011 ◽  
pp. 1-14 ◽  
Author(s):  
Victor A. Sipachev

Structural studies are largely performed without taking into account vibrational effects or with incorrectly taking them into account. The paper presents a first-order perturbation theory analysis of the problem. It is shown that vibrational effects introduce errors on the order of 0.02 Å or larger (sometimes, up to 0.1-0.2 Å) into the results of diffraction measurements. Methods for calculating the mean rotational constants, mean-square vibrational amplitudes, vibrational corrections to internuclear distances, and asymmetry parameters are described. Problems related to low-frequency motions, including torsional motions that transform into free rotation at low excitation levels, are discussed. The algorithms described are implemented in the program available from the author (free).

2014 ◽  
Vol 2014 ◽  
pp. 1-5 ◽  
Author(s):  
Yunusa Olufadi ◽  
Cem Kadilar

We suggest an estimator using two auxiliary variables for the estimation of the unknown population variance. The bias and the mean square error of the proposed estimator are obtained to the first order of approximations. In addition, the problem is extended to two-phase sampling scheme. After theoretical comparisons, as an illustration, a numerical comparison is carried out to examine the performance of the suggested estimator with several estimators.


1969 ◽  
Vol 37 (3) ◽  
pp. 529-563 ◽  
Author(s):  
S. C. Crow

Recorded pressure signatures of supersonic aircraft often show intense, spiky perturbations superimposed on a basicN-shaped pattern. A first-order scattering theory, incorporating both inertial and thermal interactions, is developed to explain the spikes. Scattering from a weak shock is studied first. The solution of the scattering equation is derived as a sum of three terms: a phase shift corresponding to the singularity found by Lighthill; a small local compression or rarefaction; a surface integral over a paraboloid of dependence, whose focus is the observation point and whose directrix is the shock. The solution is found to degenerate at the shock into the result given by ray acoustics, and the surface integral is identified with the scattered waves that make up the spikes. The solution is generalized for arbitrary wave-forms by means of a superposition integral. Eddies in the Kolmogorov inertial subrange are found to be the main source of spikes, and Kolmogorov's similarity theory is used to show that, for almost all timestafter a sonic-bang shock passes an observation point, the mean-square pressure perturbation equals$(\Delta p)^2 (t_c/t)^{\frac{7}{6}}$, where Δpis the pressure jump across the shock andtcis a critical time predicted in terms of meteorological conditions. For an idealized model of the atmospheric boundary layer,tcis calculated to be about 1 ms, a figure consistent with the qualitative data currently available. The mean-square pressure perturbation just behind the shock itself is found to be finite but enormous, according to first-order scattering theory. It is conjectured that a second-order theory might explain the shock thickening that actually occurs.


1970 ◽  
Vol 26 (2) ◽  
pp. 260-262 ◽  
Author(s):  
G. S. Pawley ◽  
B. T. M. Willis

The analysis in part I is generalized to any crystal containing rigid molecules which undergo anisotropic translational and librational motion about a site fixed by symmetry. The treatment is correct to terms in (ui 2)2 and (ωi 2)2, where (ui 2) is the mean-square translational displacement of the molecule along the ith axis and (ωi 2) is the mean-square angular libration about the same axis. The first-order treatment to terms in (ui 2) and (ωi 2) is shown to be equivalent to the rigid-body theory in current use.


2014 ◽  
Vol 889-890 ◽  
pp. 662-665
Author(s):  
Huan Xin Peng ◽  
Wen Kai Wang ◽  
Bin Liu

In order to improve the accuracy and the convergence rate of distributed consensus under quantized communication, in the paper, based on adaptive quantization scheme, we propose the pseudo two-hop distributed consensus algorithm. By analyses and simulations, Results show that the pseudo two-hop distributed consensus algorithm based on adaptive quantization can reach an average consensus, and its convergence rate is higher than that of the first-order adaptive quantized distributed consensus algorithm, moreover, the mean square errors are smaller within the finite steps.


1975 ◽  
Vol 15 (06) ◽  
pp. 487-494 ◽  
Author(s):  
J.A. Pinkster

Abstract The influence of the low-frequency-wave-drifting force on the motions of moored vessels and the loads in the mooring system is demonstrated from results of model tests in irregular waves. The origin of the wave drifting force is discussed and methods for calculating the mean drifting force are reviewed. To facilitate calculation of the low-frequency-wave drifting force on an object in irregular waves, an existing method using the mean drifting force in regular waves is generalized. The results of calculations using the method introduced in this paper are compared with previously published test results. Finally, some remarks are added concerning effects that have not been accounted for in existing calculation methods. Introduction A vessel moored at sea in stationary conditions with regard to waves, wind, and current is subjected to forces that tend to shift it from the desired position. For a given vessel and position in the position. For a given vessel and position in the horizontal plane, the motions depend on both the mooring system and the external forces acting on the vessel. In steady conditions, the forces caused by a constant wind and current are constant quantities for a given heading angle of the vessel. The forces caused by a stationary irregular sea are of an irregular nature and may be split into two parts: first-order oscillatory forces with wave parts: first-order oscillatory forces with wave frequency, and second-order, slowly varying forces with frequencies much lower than the wave frequency.The first-order oscillatory wave forces on a vessel cause the well known ship motions whose frequencies equal the frequencies present in the spectrum of the irregular waves. These are the linear motions of surge, sway, and heave and the three angular motions of roll, pitch, and yaw. In general, the first-order wave forces are proportional to the wave height, as are the ensuing motions. The magnitude of the linear oscillatory motions is in the order of the height of the waves.The second-order wave forces, perhaps better known as the wave drifting forces, have been shown to be proportional to the square of the wave height. These forces, though small in magnitude, are the cause of the low-frequency, large-amplitude, horizontal motions sometimes observed in large vessels moored in irregular waves. Tests run in irregular waves in wave tanks of the Netherlands Ship Model Basin revealed a number of properties and effects of the low-frequency-wave properties and effects of the low-frequency-wave drifting force that are discussed here using the results of two test programs.The first of these programs concerns tests run with the model of a 125,000-cu m LNG carrier moored in head seas with an ideal linear mooring system. The second program deals with a 300,000-DWT VLCC moored with a realistic nonlinear bow hawser to a single-buoy mooring in waves, wind, and current coming from different directions.The results of the tests with the LNG carrier are shown in Figs. 1 through 3, while the results of the tests with the 300,000-DWT VLCC are shown in Fig. 4. All results are given in full-scale values. Fig. 1 shows the wave trace and the surge motion of the LNG carrier to a base of time. SPEJ P. 487


2016 ◽  
Vol 41 (4) ◽  
pp. 731-739 ◽  
Author(s):  
Dariusz Bismor ◽  
Marek Pawelczyk

AbstractThe Least Mean Square (LMS) algorithm and its variants are currently the most frequently used adaptation algorithms; therefore, it is desirable to understand them thoroughly from both theoretical and practical points of view. One of the main aspects studied in the literature is the influence of the step size on stability or convergence of LMS-based algorithms. Different publications provide different stability upper bounds, but a lower bound is always set to zero. However, they are mostly based on statistical analysis. In this paper we show, by means of control theoretic analysis confirmed by simulations, that for the leaky LMS algorithm, a small negative step size is allowed. Moreover, the control theoretic approach alows to minimize the number of assumptions necessary to prove the new condition. Thus, although a positive step size is fully justified for practical applications since it reduces the mean-square error, knowledge about an allowed small negative step size is important from a cognitive point of view.


1966 ◽  
Vol 33 (1) ◽  
pp. 187-191 ◽  
Author(s):  
A. H. Gray

The first-passage problem in a random vibrational system is solved by means of approximations which convert the problem to a first-order one-dimensional Markov process. Laplace transforms are used to evaluate the mean square time to failure.


Author(s):  
Lovleen Kumar Grover ◽  
Amanpreet Kaur

In this paper, we improve the efficiency of  Koyuncu et al (2014)’s estimator of population mean of sensitive variable by replacing Traditional Randomized response technique with Optional Randomized response technique as suggested by Gupta et al (2014). The mean square error of proposed estimator is obtained, up to first order of approximation, and is compared with mean square error of various existing estimators theoretically as well as numerically.


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