scholarly journals Preparation of Single- and Few-Layer Graphene Sheets Using Co Deposition on SiC Substrate

2011 ◽  
Vol 2011 ◽  
pp. 1-7 ◽  
Author(s):  
Cun Li ◽  
Dandan Li ◽  
Jingjing Yang ◽  
Xiaopeng Zeng ◽  
Wenxia Yuan

Single- and few-layer graphene sheets were fabricated by selective chemical reactions between Co film and SiC substrate. A rapid cooling process was employed. The number of layers and crystallinity of graphene sheets were controlled by process parameters. The formation mechanism of graphene was highly sensitive to carbon diffusion. Free carbon precipitated and then moved across the product layer that was composed mainly of cobalt-silicides. The graphene layer formed homogeneously on the surface and then transferred to the other substrate. This could provide a method for high-quality fabrication of wafer-sized graphene sheets.

Nanoscale ◽  
2015 ◽  
Vol 7 (22) ◽  
pp. 10021-10029 ◽  
Author(s):  
Jessica C. Spear ◽  
James P. Custer ◽  
James D. Batteas

Graphene's lack of conformity to rough surfaces impacts its frictional properties, depending on the number of layers and substrate bonding.


2018 ◽  
Vol 6 (22) ◽  
pp. 10331-10339 ◽  
Author(s):  
Panpan Chang ◽  
Kazuki Matsumura ◽  
Jizong Zhang ◽  
Jie Qi ◽  
Chengyang Wang ◽  
...  

2D porous carbon nanosheets (PCNs) occupy the foreground in the field of electric double-layer capacitors (EDLCs).


Materials ◽  
2019 ◽  
Vol 12 (24) ◽  
pp. 4032
Author(s):  
Lianlian Liu ◽  
Niclas Solin ◽  
Olle Inganäs

Humic acid (HA) is a biopolymer formed from degraded plants, making it a ubiquitous, renewable, sustainable, and low cost source of biocarbon materials. HA contains abundant functional groups, such as carboxyl-, phenolic/alcoholic hydroxyl-, ketone-, and quinone/hydroquinone (Q/QH2)-groups. The presence of Q/QH2 groups makes HA redox active and, accordingly, HA is a candidate material for energy storage. However, as HA is an electronic insulator, it is essential to combine it with conductive materials in order to enable fabrication of HA electrodes. One of the lowest cost types of conductive materials that can be considered is carbon-based conductors such as graphite. Herein, we develop a facile method allowing the biocarbon to meet carbon; HA (in the form of a sodium salt) is mixed with graphite by a solvent-free mechanochemical method involving ball milling. Few-layer graphene sheets are formed and the HA/graphite mixtures can be used to fabricate HA/graphite hybrid material electrodes. These electrodes exhibit a conductivity of up to 160 S·m−1 and a discharge capacity as large as 20 mAhg−1. Our study demonstrates a novel methodology enabling scalable fabrication of low cost and sustainable organic electrodes for application as supercapacitors.


ChemSusChem ◽  
2013 ◽  
Vol 6 (5) ◽  
pp. 732-732
Author(s):  
Viviane Schwartz ◽  
Wujun Fu ◽  
Yu-Tung Tsai ◽  
Harry M. Meyer ◽  
Adam J. Rondinone ◽  
...  

2014 ◽  
Vol 2 (37) ◽  
pp. 15298-15302 ◽  
Author(s):  
Farid Ouhib ◽  
Abdelhafid Aqil ◽  
Jean-Michel Thomassin ◽  
Cédric Malherbe ◽  
Bernard Gilbert ◽  
...  

We report a simple approach for the production of polymer functionalized graphene for Li-ion battery anodes.


2010 ◽  
Vol 2010 ◽  
pp. 1-5 ◽  
Author(s):  
Weifeng Zhao ◽  
Furong Wu ◽  
Hang Wu ◽  
Guohua Chen

A top-down method was developed for producing colloidal dispersions of graphene sheets. Graphite nanosheets comprising hundreds of carbon layers were dispersed and gently ball-milled to exfoliate into graphene in a variety of organic solvents. After 30 hours of the shear-force-dominated grinding and a subsequent 4000 r.p.m. of centrifugation, single- and few-layer graphene sheets were readily prepared and homogeneously and stably suspended in the good solvent medium which possesses a surface tension value close to 40 mJm−2, such as inN,N-dimethylformamide, at a concentration up to 0.08 mg ml−1, achieving a yield higher than 32.0 wt%. The graphene materials in the colloidal suspension were characterized using scanning and transmission electron microscopy and atomic force microscopy.


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