scholarly journals Synthesis and Structural Characterization of a Metal Cluster and a Coordination Polymer Based on the [Mn6(μ4-O)2]10+Unit

2010 ◽  
Vol 2010 ◽  
pp. 1-7 ◽  
Author(s):  
Eleni E. Moushi ◽  
Anastasios J. Tasiopoulos ◽  
Manolis J. Manos
Keyword(s):  
Coordination Polymer ◽  
Structural Characterization ◽  
Room Temperature ◽  
Metal Cluster ◽  
Zigzag Chain ◽  
Manganese Carboxylate

A new 1-D coordination polymer [M(CMe(O]2.5O (12.5O and the cluster [M((CPh (py(MeCN)(O)]2MeCN (22MeCN) are reported. Both compounds were synthesized by room temperature reactions of [M(-O)(CR(L()] (R = Me, L =  = py, (12.5O; R = Ph, L = py,  = O,22MeCN) in the presence of 3-hydroxymethylpyridine (3hmpH) in acetonitrile. The structures of these complexes are based on hexanuclear mixed-valent manganese carboxylate clusters containing the [(-O structural core. (12.5O consists of zigzag chain polymers constructed from [M(CMe(O] repeating units linked through acetate ligands, whereas22MeCN comprises a discrete M-benzoate cluster.

Synthesis and structural characterization of a binary metal cluster and a coordination polymer based on the mercury Bis(phenylselenolate) unit

Polyhedron ◽  
2012 ◽  
Vol 43 (1) ◽  
pp. 170-175 ◽  
Author(s):  
Ana B. Lago ◽  
Ernesto S. Lang ◽  
Bárbara Tirloni ◽  
Ezequiel M. Vázquez-López
Keyword(s):  
Coordination Polymer ◽  
Structural Characterization ◽  
Metal Cluster ◽  
Binary Metal

Structural Systematics of Rare Earth Complexes. VII. Crystal Structure of Bis(2,2'/6',2␛-Terpyridinium) Octaaquaterbium(III) Heptachloride Hydrate

1994 ◽  
Vol 47 (2) ◽  
pp. 391 ◽  
Author(s):  
CJ Kepert ◽  
BW Skeleton ◽  
AH White
Keyword(s):  
Crystal Structure ◽  
Rare Earth ◽  
Single Crystal ◽  
Structural Characterization ◽  
Title Compound ◽  
Room Temperature ◽  
Chloride Ions ◽  
Full Matrix ◽  
X Ray

The room-temperature single-crystal X-ray structural characterization of the title compound (tpyH2)2[Tb(OH2)8]Cl7.~2⅓H2O is recorded. Crystals are triclinic, Pī , a 17.063(5), b 16.243(3), c 7.878(3) Ǻ, α 84.78(2), β 84.39(3), γ 87.81(2)°, Z = 2 formula units; 3167 'observed' diffractometer reflections were refined by full-matrix least-squares procedures to a residual of 0.057. Notable features of interest of the compound are the 'chelation' of chloride ions by the terpyridinium cations , and the existence of a free [Tb(OH2)8]2+ cation in the presence of an abundance of chloride ions.

scholarly journals Synthesis and structural characterization of a single-crystal to single-crystal transformable coordination polymer

2014 ◽  
Vol 43 (4) ◽  
pp. 1519-1523 ◽  
Author(s):  
Yuyang Tian ◽  
Phoebe K. Allan ◽  
Catherine L. Renouf ◽  
Xiang He ◽  
Laura J. McCormick ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Structural Characterization

scholarly journals Synthesis and structural characterization of transition metal dithiolene derivatives containing divalent metals as counter-cations

CrystEngComm ◽  
2019 ◽  
Vol 21 (9) ◽  
pp. 1423-1432 ◽  
Author(s):  
Oscar Castillo ◽  
Esther Delgado ◽  
Diego Hernández ◽  
Elisa Hernández ◽  
Avelino Martín ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Transition Metal ◽  
Structural Characterization ◽  
Metal Cations ◽  
Magnetic Behaviour ◽  
Divalent Metal ◽  
Divalent Metals ◽  
Divalent Metal Cations ◽  
1D Coordination Polymer

Complexes containing [Fe2(SC6H2Cl2S)4]2− or [Ni(SC6H2Cl2S)2]− entities and divalent metal cations as well as an 1D-coordination polymer K/Zn have been obtained and their magnetic behaviour studied.

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