scholarly journals Application of Silver Conducting Glasses to Solid State Batteries and Sensors

1990 ◽  
Vol 14 (2) ◽  
pp. 81-94 ◽  
Author(s):  
Liu Jun ◽  
J. Portier ◽  
B. Tanguy ◽  
J. J. Videau ◽  
M. Ait Allal ◽  
...  
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
Solid State ◽  
Reference Electrode ◽  
Silver Ion ◽  
Ionic Conducting ◽  
Solid State Batteries ◽  
Electrochemical Devices ◽  
Ion Conducting ◽  
Mis Structures

Fast silver ion conducting glasses as electrochemical devices have been tested. A silver iodine battery using a silver ionic conducting glass (AgPO3-Ag2S-AgI) has been studied. The interaction of some gases (O2CI2, H2S) with the electrochemical chains: Pt/Sb2S3-AgI (glass)/Ag and Pt/AgCl (thin film)/Sb2S3- AgI (glass)/Ag has been investigated. Finally, the behavior of thin films of Ag2S3-Ag2S-CdS glasses as sensitive membranes for Cd detection in solution has been tested on MIS structures Au/Si/SiO2/ Membrane/Cd in solution/Reference electrode.

scholarly journals Thin film oxide-ion conducting electrolyte for near room temperature applications

2019 ◽  
Vol 7 (45) ◽  
pp. 25772-25778 ◽  
Author(s):  
Iñigo Garbayo ◽  
Francesco Chiabrera ◽  
Nerea Alayo ◽  
José Santiso ◽  
Alex Morata ◽  
...  
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
Solid State ◽  
Room Temperature ◽  
Bismuth Vanadate ◽  
Ionic Conductors ◽  
Electrochemical Devices ◽  
Ion Conducting ◽  
Oxide Ion ◽  
Temperature Applications

Stabilized bismuth vanadate thin films are presented here as superior oxide ionic conductors, for application in solid state electrochemical devices operating near room temperature.

Li2CO3 thin films fabricated by sputtering techniques: the role of temperature on their properties

CrystEngComm ◽  
2014 ◽  
Vol 16 (27) ◽  
pp. 6033-6038 ◽  
Author(s):  
Lander Rojo ◽  
Irene Castro-Hurtado ◽  
María C. Morant-Miñana ◽  
Gemma G. Mandayo ◽  
Enrique Castaño
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
Solid State ◽  
Electrochemical Devices

This work present the first steps of thin film solid state electrochemical devices development based on Li2CO3.

Fast Lithium-Ion Conducting Thin-Film Electrolytes Integrated Directly on Flexible Substrates for High-Power Solid-State Batteries

2011 ◽  
Vol 23 (47) ◽  
pp. 5663-5667 ◽  
Author(s):  
Jon F. Ihlefeld ◽  
Paul G. Clem ◽  
Barney L. Doyle ◽  
Paul G. Kotula ◽  
Kyle R. Fenton ◽  
...  
Keyword(s):  
Thin Film ◽  
Solid State ◽  
High Power ◽  
Lithium Ion ◽  
Flexible Substrates ◽  
Solid State Batteries ◽  
Ion Conducting

Silver Ion Conducting Electrolytes and Silver Solid-State Batteries

2015 ◽  
pp. 779-818
Author(s):  
Kevin Kirshenbaum ◽  
Roberta A. DiLeo ◽  
Kenneth J. Takeuchi ◽  
Amy C. Marschilok ◽  
Esther S. Takeuchi
Keyword(s):  
Solid State ◽  
Silver Ion ◽  
Solid State Batteries ◽  
Ion Conducting

scholarly journals Solid State NMR Spectroscopy a Valuable Technique for Structural Insights of Advanced Thin Film Materials: A Review

Nanomaterials ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1494
Author(s):  
Mustapha El Hariri El Nokab ◽  
Khaled O. Sebakhy
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
Solid State ◽  
Solid State Nmr ◽  
Pulse Sequences ◽  
3D Structure ◽  
Spectroscopic Techniques ◽  
Film Research ◽  
Versatile Technique ◽  
Work Done

Solid-state NMR has proven to be a versatile technique for studying the chemical structure, 3D structure and dynamics of all sorts of chemical compounds. In nanotechnology and particularly in thin films, the study of chemical modification, molecular packing, end chain motion, distance determination and solvent-matrix interactions is essential for controlling the final product properties and applications. Despite its atomic-level research capabilities and recent technical advancements, solid-state NMR is still lacking behind other spectroscopic techniques in the field of thin films due to the underestimation of NMR capabilities, availability, great variety of nuclei and pulse sequences, lack of sensitivity for quadrupole nuclei and time-consuming experiments. This article will comprehensively and critically review the work done by solid-state NMR on different types of thin films and the most advanced NMR strategies, which are beyond conventional, and the hardware design used to overcome the technical issues in thin-film research.

scholarly journals Radio frequency magnetron sputtering of Li7La3Zr2O12 thin films for solid-state batteries

2016 ◽  
Vol 307 ◽  
pp. 684-689 ◽  
Author(s):  
S. Lobe ◽  
C. Dellen ◽  
M. Finsterbusch ◽  
H.-G. Gehrke ◽  
D. Sebold ◽  
...  
Keyword(s):  
Thin Films ◽  
Solid State ◽  
Magnetron Sputtering ◽  
Radio Frequency ◽  
Radio Frequency Magnetron ◽  
Radio Frequency Magnetron Sputtering ◽  
Solid State Batteries

scholarly journals PEO Infiltration of Porous Garnet-Type Lithium-Conducting Solid Electrolyte Thin Films

Ceramics ◽  
2021 ◽  
Vol 4 (3) ◽  
pp. 421-436
Author(s):  
Aamir Iqbal Waidha ◽  
Vanita Vanita ◽  
Oliver Clemens
Keyword(s):  
Thin Films ◽  
Solid State ◽  
Ionic Conductivity ◽  
Electrochemical Impedance ◽  
Three Dimensional ◽  
Lithium Ion ◽  
Interfacial Resistance ◽  
Composite Electrolytes ◽  
Ion Conducting ◽  
Polymer Infiltration

Composite electrolytes containing lithium ion conducting polymer matrix and ceramic filler are promising solid-state electrolytes for all solid-state lithium ion batteries due to their wide electrochemical stability window, high lithium ion conductivity and low electrode/electrolyte interfacial resistance. In this study, we report on the polymer infiltration of porous thin films of aluminum-doped cubic garnet fabricated via a combination of nebulized spray pyrolysis and spin coating with subsequent post annealing at 1173 K. This method offers a simple and easy route for the fabrication of a three-dimensional porous garnet network with a thickness in the range of 50 to 100 µm, which could be used as the ceramic backbone providing a continuous pathway for lithium ion transport in composite electrolytes. The porous microstructure of the fabricated thin films is confirmed via scanning electron microscopy. Ionic conductivity of the pristine films is determined via electrochemical impedance spectroscopy. We show that annealing times have a significant impact on the ionic conductivity of the films. The subsequent polymer infiltration of the porous garnet films shows a maximum ionic conductivity of 5.3 × 10−7 S cm−1 at 298 K, which is six orders of magnitude higher than the pristine porous garnet film.

PROPERTIES OF ALL-SOLID-STATE LITHIUM-ION RECHARGEABLE BATTERIES DEPOSITED BY RF MAGNETRON SPUTTERING

2013 ◽  
Vol 27 (22) ◽  
pp. 1350156 ◽  
Author(s):  
R. J. ZHU ◽  
Y. REN ◽  
L. Q. GENG ◽  
T. CHEN ◽  
L. X. LI ◽  
...  
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
Solid State ◽  
Magnetron Sputtering ◽  
Coulombic Efficiency ◽  
Electronic Conductivity ◽  
Lithium Ion ◽  
Rf Magnetron Sputtering ◽  
Rechargeable Batteries ◽  
Voltage Range

Amorphous V 2 O 5, LiPON and Li 2 Mn 2 O 4 thin films were fabricated by RF magnetron sputtering methods and the morphology of thin films were characterized by scanning electron microscopy. Then with these three materials deposited as the anode, solid electrolyte, cathode, and vanadium as current collector, a rocking-chair type of all-solid-state thin-film-type Lithium-ion rechargeable battery was prepared by using the same sputtering parameters on stainless steel substrates. Electrochemical studies show that the thin film battery has a good charge–discharge characteristic in the voltage range of 0.3–3.5 V, and after 30 cycles the cell performance turned to become stabilized with the charge capacity of 9 μAh/cm2, and capacity loss of single-cycle of about 0.2%. At the same time, due to electronic conductivity of the electrolyte film, self-discharge may exist, resulting in approximately 96.6% Coulombic efficiency.

scholarly journals Fabrication and Testing of All-solid-state Nanoscale Lithium Batteries Using LiPON for Electrolytes

2018 ◽  
Vol 53 ◽  
pp. 01008
Author(s):  
Feihu Tan ◽  
XiaoPing Liang ◽  
Feng Wei ◽  
Jun Du
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
Solid State ◽  
Magnetron Sputtering ◽  
Specific Capacity ◽  
Rf Magnetron Sputtering ◽  
Open Circuit ◽  
Working Pressure ◽  
Thin Film Battery ◽  
A Current

The amorphous LiPON thin film was obtained by using the crystalline Li3PO4 target and the RF magnetron sputtering method at a N2 working pressure of 1 Pa. and then the morphology and composition of LiPON thin films are analysed by SEM and EDS. SEM shows that the film was compact and smooth, while EDS shows that the content of N in LiPON thin film was about 17.47%. The electrochemical properties of Pt/LiPON/Pt were analysed by EIS, and the ionic conductivity of LiPON thin films was 3.8×10-7 S/cm. By using the hard mask in the magnetron sputtering process, the all-solid-state thin film battery with Si/Ti/Pt/LiCoO2/LiPON/Li4Ti5O12/Pt structure was prepared, and its electrical properties were studied. As for this thin film battery, the open circuit voltage was 1.9 V and the first discharge specific capacity was 34.7 μAh/cm2·μm at a current density of 5 μA/cm-2, indicating that is promising in all-solidstate thin film batteries.

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