scholarly journals Reversible and Irreversible Expansion of Lithium-ion Batteries Under a Wide Range of Stress Factors

2021 ◽  
Author(s):  
Peyman Mohtat ◽  
Suhak Lee ◽  
Anna G. Stefanopoulou ◽  
Jason B. Siegel
Keyword(s):  
Lithium Ion Batteries ◽  
Negative Electrode ◽  
Lithium Ion ◽  
Stress Factors ◽  
Battery Management ◽  
Thickness Change ◽  
Depth Of Discharge ◽  
Wide Range ◽  
Power Limits ◽  
Cell Thickness

Lithium-ion batteries cell thickness changes as they degrade. These changes in thickness consist of a reversible intercalation-induced expansion and an irreversible expansion. In this work, we study the cell expansion evolution under variety of conditions such as temperature, charging rate, depth of discharge, and pressure.A specialized ?fixture was used to keep the cells at a constant pressure during cycling, while measuring the thickness change both within a cycle and the cumulative growth over many cycles. The changes in positive and negative electrode capacity and stoichiometric range can be diagnosed from the evolution of the reversible expansion. The changes in the reversible expansion if combined with the voltage, lead to a higher-confi?dence estimation of cell health parameters important for lifetime prediction and adoptive battery management such as asymmetric charge/discharge power limits. This study raises the importance of monitoring the expansion for enabling advanced and more-informed health diagnostics of lithium-ion batteries.

Lithium-ion Battery Degradation Mechanisms and Failure Analysis Methodology

2012 ◽  
Author(s):  
Bhanu Sood ◽  
Lucas Severn ◽  
Michael Osterman ◽  
Michael Pecht ◽  
Anton Bougaev ◽  
...  
Keyword(s):  
Failure Analysis ◽  
Lithium Ion Batteries ◽  
Elevated Temperatures ◽  
Failure Process ◽  
Lithium Ion ◽  
Degradation Mechanisms ◽  
Analysis Methodology ◽  
Depth Of Discharge ◽  
Battery Degradation ◽  
Non Destructive

Abstract A review of the prevalent degradation mechanisms in Lithium ion batteries is presented. Degradation and eventual failure in lithium-ion batteries can occur for a variety of dfferent reasons. Degradation in storage occurs primarily due to the self-discharge mechanisms, and is accelerated during storage at elevated temperatures. The degradation and failure during use conditions is generally accelerated due to the transient power requirements, the high frequency of charge/discharge cycles and differences between the state-of-charge and the depth of discharge influence the degradation and failure process. A step-by-step methodology for conducting a failure analysis of Lithion batteries is presented. The failure analysis methodology is illustrated using a decision-tree approach, which enables the user to evaluate and select the most appropriate techniques based on the observed battery characteristics. The techniques start with non-destructive and non-intrusive steps and shift to those that are more destructive and analytical in nature as information about the battery state is gained through a set of measurements and experimental techniques.

scholarly journals Electrochemical study on nickel aluminum layered double hydroxides as high-performance electrode material for lithium-ion batteries based on sodium alginate binder

2021 ◽  
Author(s):  
Xinyue Li ◽  
Marco Fortunato ◽  
Anna Maria Cardinale ◽  
Angelina Sarapulova ◽  
Christian Njel ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Electrode Material ◽  
Photoelectron Spectroscopy ◽  
Negative Electrode ◽  
Lithium Ion ◽  
Electrochemical Study ◽  
Ex Situ ◽  
Potential Range ◽  
X Ray ◽  
Storage Mechanism

AbstractNickel aluminum layered double hydroxide (NiAl LDH) with nitrate in its interlayer is investigated as a negative electrode material for lithium-ion batteries (LIBs). The effect of the potential range (i.e., 0.01–3.0 V and 0.4–3.0 V vs. Li+/Li) and of the binder on the performance of the material is investigated in 1 M LiPF6 in EC/DMC vs. Li. The NiAl LDH electrode based on sodium alginate (SA) binder shows a high initial discharge specific capacity of 2586 mAh g−1 at 0.05 A g−1 and good stability in the potential range of 0.01–3.0 V vs. Li+/Li, which is better than what obtained with a polyvinylidene difluoride (PVDF)-based electrode. The NiAl LDH electrode with SA binder shows, after 400 cycles at 0.5 A g−1, a cycling retention of 42.2% with a capacity of 697 mAh g−1 and at a high current density of 1.0 A g−1 shows a retention of 27.6% with a capacity of 388 mAh g−1 over 1400 cycles. In the same conditions, the PVDF-based electrode retains only 15.6% with a capacity of 182 mAh g−1 and 8.5% with a capacity of 121 mAh g−1, respectively. Ex situ X-ray photoelectron spectroscopy (XPS) and ex situ X-ray absorption spectroscopy (XAS) reveal a conversion reaction mechanism during Li+ insertion into the NiAl LDH material. X-ray diffraction (XRD) and XPS have been combined with the electrochemical study to understand the effect of different cutoff potentials on the Li-ion storage mechanism. Graphical abstract The as-prepared NiAl-NO3−-LDH with the rhombohedral R-3 m space group is investigated as a negative electrode material for lithium-ion batteries (LIBs). The effect of the potential range (i.e., 0.01–3.0 V and 0.4–3.0 V vs. Li+/Li) and of the binder on the material’s performance is investigated in 1 M LiPF6 in EC/DMC vs. Li. Ex situ X-ray photoelectron spectroscopy (XPS) and ex situ X-ray absorption spectroscopy (XAS) reveal a conversion reaction mechanism during Li+ insertion into the NiAl LDH material. X-ray diffraction (XRD) and XPS have been combined with the electrochemical study to understand the effect of different cutoff potentials on the Li-ion storage mechanism. This work highlights the possibility of the direct application of NiAl LDH materials as negative electrodes for LIBs.

scholarly journals Determination of the Distribution of Relaxation Times by Means of Pulse Evaluation for Offline and Online Diagnosis of Lithium-Ion Batteries

Batteries ◽  
2021 ◽  
Vol 7 (2) ◽  
pp. 36
Author(s):  
Erik Goldammer ◽  
Julia Kowal
Keyword(s):  
Lithium Ion Batteries ◽  
Electrochemical Impedance ◽  
Sampling Rate ◽  
Relaxation Times ◽  
Low Frequency ◽  
Lithium Ion ◽  
Battery Management ◽  
Time Constants ◽  
Time Domain Data ◽  
Aging Study

The distribution of relaxation times (DRT) analysis of impedance spectra is a proven method to determine the number of occurring polarization processes in lithium-ion batteries (LIBs), their polarization contributions and characteristic time constants. Direct measurement of a spectrum by means of electrochemical impedance spectroscopy (EIS), however, suffers from a high expenditure of time for low-frequency impedances and a lack of general availability in most online applications. In this study, a method is presented to derive the DRT by evaluating the relaxation voltage after a current pulse. The method was experimentally validated using both EIS and the proposed pulse evaluation to determine the DRT of automotive pouch-cells and an aging study was carried out. The DRT derived from time domain data provided improved resolution of processes with large time constants and therefore enabled changes in low-frequency impedance and the correlated degradation mechanisms to be identified. One of the polarization contributions identified could be determined as an indicator for the potential risk of plating. The novel, general approach for batteries was tested with a sampling rate of 10 Hz and only requires relaxation periods. Therefore, the method is applicable in battery management systems and contributes to improving the reliability and safety of LIBs.

scholarly journals Battery Stress Factor Ranking for Accelerated Degradation Test Planning Using Machine Learning

Energies ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 723
Author(s):  
Saurabh Saxena ◽  
Darius Roman ◽  
Valentin Robu ◽  
David Flynn ◽  
Michael Pecht
Keyword(s):  
Machine Learning ◽  
Lithium Ion Batteries ◽  
Lithium Ion ◽  
Consumer Electronics ◽  
Stress Factors ◽  
Test Time ◽  
Capacity Fade ◽  
Maximum Acceleration ◽  
Accelerated Degradation ◽  
Qualification Testing

Lithium-ion batteries power numerous systems from consumer electronics to electric vehicles, and thus undergo qualification testing for degradation assessment prior to deployment. Qualification testing involves repeated charge–discharge operation of the batteries, which can take more than three months if subjected to 500 cycles at a C-rate of 0.5C. Accelerated degradation testing can be used to reduce extensive test time, but its application requires a careful selection of stress factors. To address this challenge, this study identifies and ranks stress factors in terms of their effects on battery degradation (capacity fade) using half-fractional design of experiments and machine learning. Two case studies are presented involving 96 lithium-ion batteries from two different manufacturers, tested under five different stress factors. Results show that neither the individual (main) effects nor the two-way interaction effects of charge C-rate and depth of discharge rank in the top three significant stress factors for the capacity fade in lithium-ion batteries, while temperature in the form of either individual or interaction effect provides the maximum acceleration.

Negative Electrode Comprised of Nanostructured CuO for Advanced Lithium Ion Batteries

2017 ◽  
Vol 28 (3) ◽  
pp. 1595-1604 ◽  
Author(s):  
Manab Kundu ◽  
Gopalu Karunakaran ◽  
Evgeny Kolesnikov ◽  
Mikhail V. Gorshenkov ◽  
Denis Kuznetsov
Keyword(s):  
Lithium Ion Batteries ◽  
Negative Electrode ◽  
Lithium Ion

Recent progress in rechargeable lithium batteries with organic materials as promising electrodes

2016 ◽  
Vol 4 (19) ◽  
pp. 7091-7106 ◽  
Author(s):  
Jian Xie ◽  
Qichun Zhang
Keyword(s):  
Lithium Ion Batteries ◽  
Lithium Batteries ◽  
Recent Progress ◽  
Electrode Materials ◽  
Negative Electrode ◽  
Lithium Ion ◽  
Positive Electrode ◽  
Rechargeable Lithium Batteries ◽  
Organic Electrode ◽  
Negative Electrode Materials

Different organic electrode materials in lithium-ion batteries are divided into three types: positive electrode materials, negative electrode materials, and bi-functional electrode materials, and are further discussed.

Electrochemical Properties of Carbon-Coated NbO2 as a Negative Electrode for Lithium-Ion Batteries

2016 ◽  
Vol 724 ◽  
pp. 87-91 ◽  
Author(s):  
Chang Su Kim ◽  
Yong Hoon Cho ◽  
Kyoung Soo Park ◽  
Soon Ki Jeong ◽  
Yang Soo Kim
Keyword(s):  
Electrochemical Properties ◽  
Lithium Ion Batteries ◽  
Ball Milling ◽  
Carbon Coating ◽  
Electrochemical Impedance ◽  
Active Material ◽  
Negative Electrode ◽  
Lithium Ion ◽  
Transfer Resistance ◽  
Carbon Coated

We investigated the electrochemical properties of carbon-coated niobium dioxide (NbO2) as a negative electrode material for lithium-ion batteries. Carbon-coated NbO2 powders were synthesized by ball-milling using carbon nanotubes as the carbon source. The carbon-coated NbO2 samples were of smaller particle size compared to the pristine NbO2 samples. The carbon layers were coated non-uniformly on the NbO2 surface. The X-ray diffraction patterns confirmed that the inter-layer distances increased after carbon coating by ball-milling. This lead to decreased charge-transfer resistance, confirmed by electrochemical impedance spectroscopy, allowing electrons and lithium-ions to quickly transfer between the active material and electrolyte. Electrochemical performance, including capacity and initial coulombic efficiency, was therefore improved by carbon coating by ball-milling.

TG-MS analysis of solid electrolyte interphase (SEI) on graphite negative-electrode in lithium-ion batteries

2006 ◽  
Vol 161 (2) ◽  
pp. 1275-1280 ◽  
Author(s):  
Liwei Zhao ◽  
Izumi Watanabe ◽  
Takayuki Doi ◽  
Shigeto Okada ◽  
Jun-ichi Yamaki
Keyword(s):  
Solid Electrolyte ◽  
Lithium Ion Batteries ◽  
Solid Electrolyte Interphase ◽  
Negative Electrode ◽  
Lithium Ion ◽  
Ms Analysis
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