Reaction of Adsorbed CO with Methanol and Ethanol on Pt Electrode: Estimation of Rate Constants

2020 ◽  
Author(s):  
Keisuke Iida ◽  
Yoshiharu Mukouyama
Keyword(s):  
Rate Constants ◽  
High Performance ◽  
Methyl Formate ◽  
Present Report ◽  
Ethyl Formate ◽  
Infrared Absorption Spectroscopy ◽  
Pt Electrode ◽  
Surface Enhanced ◽  
Langmuir Hinshelwood Mechanism ◽  
Adsorbed Co

It is well accepted that adsorbed CO (COad) on Pt electrode reacts with water (or oxygenated species). We have recently found that COad also reacts with methanol and ethanol to form methyl formate (COad + CH3OH → HCOOCH3) and ethyl formate (COad + C2H5OH → HCOOC2H5), respectively, by using surface-enhanced infrared absorption spectroscopy and high-performance liquid chromatography. In the present report, we estimate the rate constants of the reactions by considering that the reactions proceed via Langmuir-Hinshelwood mechanism. The rate constants are estimated to be in the order of 0.1 s-1.

Determining intrinsic stark tuning rates of adsorbed CO on copper surfaces

2021 ◽  
Author(s):  
Xiaoxia Chang ◽  
Haocheng Xiong ◽  
Yifei Xu ◽  
Yaran Zhao ◽  
Qi Lu ◽  
...  
Keyword(s):  
Absorption Spectroscopy ◽  
Infrared Absorption ◽  
Infrared Absorption Spectroscopy ◽  
Effective Strategy ◽  
Copper Surfaces ◽  
Tuning Rate ◽  
Surface Enhanced ◽  
Dynamical Coupling ◽  
Adsorbed Co ◽  
The Impact

This work reports a general and effective strategy of determining the intrinsic Stark tuning rate by removing the impact of the dynamical coupling of adsorbed CO on the Cu surface with surface enhanced infrared absorption spectroscopy (SEIRAS).

scholarly journals SERS Biosensor Based on Engineered 2D-Aperiodic Nanostructure for In-Situ Detection of Viable Brucella Bacterium in Complex Matrix

Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 886
Author(s):  
Massimo Rippa ◽  
Riccardo Castagna ◽  
Domenico Sagnelli ◽  
Ambra Vestri ◽  
Giorgia Borriello ◽  
...  
Keyword(s):  
High Performance ◽  
Foodborne Pathogen ◽  
Surface Enhanced Raman Spectroscopy ◽  
High Performing ◽  
Sensing Platform ◽  
Food Detection ◽  
Raman Enhancement ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
In Situ Detection

Brucella is a foodborne pathogen globally affecting both the economy and healthcare. Surface Enhanced Raman Spectroscopy (SERS) nano-biosensing can be a promising strategy for its detection. We combined high-performance quasi-crystal patterned nanocavities for Raman enhancement with the use of covalently immobilized Tbilisi bacteriophages as high-performing bio-receptors. We coupled our efficient SERS nano-biosensor to a Raman system to develop an on-field phage-based bio-sensing platform capable of monitoring the target bacteria. The developed biosensor allowed us to identify Brucella abortus in milk by our portable SERS device. Upon bacterial capture from samples (104 cells), a signal related to the pathogen recognition was observed, proving the concrete applicability of our system for on-site and in-food detection.

The second virial coefficients of mixed polar vapours

1959 ◽  
Vol 249 (1258) ◽  
pp. 414-426 ◽  
Keyword(s):  
Methyl Acetate ◽  
Virial Coefficient ◽  
Methyl Formate ◽  
Second Virial Coefficient ◽  
Virial Coefficients ◽  
Ethyl Formate ◽  
Carbonyl Oxygen ◽  
Second Virial Coefficients ◽  
Theoretical Significance ◽  
Boyle’S Law

The second virial coefficients of binary mixtures of chloroform with methyl formate, n -propyl formate, methyl acetate, ethyl acetate and diethylamine have been measured in a ‘Boyle’s law apparatus’ at temperatures between 50 and 95 °C. The measured values are consistently higher than predicted by the theory of corresponding states, and a quantitative interpretation is proposed, based on the hypothesis that the esters and amine are partially dimerized and are involved in association with the chloroform by hydrogen bonding. A linear relation is shown to exist between the heats and entropies of association for the various mixtures, and the theoretical significance of this is discussed. There is some evidence that hydrogen bonds are formed through the alkoxyl oxygen by formate esters and through the carbonyl oxygen by acetate esters. The paper includes data on the second virial coefficient for the pure esters and for ethyl formate and methyl propionate.

Surfactant-assisted electroless deposition of silver nanoparticles on Ge crystal for ultra-sensitive detection by surface-enhanced infrared absorption spectroscopy

RSC Advances ◽  
2015 ◽  
Vol 5 (26) ◽  
pp. 20390-20395 ◽  
Author(s):  
Gadupudi Purna Chandra Rao ◽  
Vairaperumal Tharmaraj ◽  
Jyisy Yang
Keyword(s):  
Silver Nanoparticles ◽  
Absorption Spectroscopy ◽  
Infrared Absorption ◽  
Electroless Deposition ◽  
Sensitive Detection ◽  
Infrared Absorption Spectroscopy ◽  
Highly Sensitive ◽  
Surface Enhanced ◽  
Surfactant Assisted

Fabrication of highly sensitive substrates for SEIRA measurements via assistance of surfactant to electrolessly deposit silver nanoparticles on Ge crystal.

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