Highly Efficient Fluorine (F) Doped Transition Metal Non-Oxide Pnictide (TMN) Based Electro-Catalyst for Oxygen Evolution Reaction in Alkaline Water Electrolysis

2020 ◽  
Author(s):  
Ioannis Spanos ◽  
Justus Masa ◽  
Aleksandar Zeradjanin ◽  
Robert Schlögl

AbstractThere is an ongoing debate on elucidating the actual role of Fe impurities in alkaline water electrolysis, acting either as reactivity mediators or as co-catalysts through synergistic interaction with the main catalyst material. This perspective summarizes the most prominent oxygen evolution reaction (OER) mechanisms mostly for Ni-based oxides as model transition metal catalysts and highlights the effect of Fe incorporation on the catalyst surface in the form of impurities originating from the electrolyte or co-precipitated in the catalyst lattice, in modulating the OER reaction kinetics, mechanism and stability. Graphic Abstract


2014 ◽  
Vol 11 (1) ◽  
pp. 107-112 ◽  
Author(s):  
Qi-Zhi Xu ◽  
Yu-Zhi Su ◽  
Hao Wu ◽  
Hui Cheng ◽  
Yun-Ping Guo ◽  
...  

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