The Speciation of Mg and Al in Chloride-Containing Mg Battery Electrolyte Solutions

Author(s):  
Yan Zhang ◽  
Aditya Narayanan ◽  
Frieder Mugele ◽  
Martien A. Cohen Stuart ◽  
Michel H.G. Duits

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E. Zinigrad ◽  
L. Asraf ◽  
H.E. Gottlieb ◽  
M. Sprecher ◽  
...  

2017 ◽  
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Yuliya Shilina ◽  
Baruch Ziv ◽  
Joseph M. Ziegelbauer ◽  
Shalom Luski ◽  
...  

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Karena W. Chapman ◽  
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Kamila M. Wiaderek ◽  
Olaf J. Borkiewicz ◽  
...  

2018 ◽  
Vol 25 (2) ◽  
pp. 537-542 ◽  
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Didem Ketenoglu ◽  
Georg Spiekermann ◽  
Manuel Harder ◽  
Erdinc Oz ◽  
Cevriye Koz ◽  
...  

The effects of varying LiPF6salt concentration and the presence of lithium bis(oxalate)borate additive on the electronic structure of commonly used lithium-ion battery electrolyte solvents (ethylene carbonate–dimethyl carbonate and propylene carbonate) have been investigated. X-ray Raman scattering spectroscopy (a non-resonant inelastic X-ray scattering method) was utilized together with a closed-circle flow cell. Carbon and oxygenK-edges provide characteristic information on the electronic structure of the electrolyte solutions, which are sensitive to local chemistry. Higher Li+ion concentration in the solvent manifests itself as a blue-shift of both the π* feature in the carbon edge and the carbonyl π* feature in the oxygen edge. While these oxygenK-edge results agree with previous soft X-ray absorption studies on LiBF4salt concentration in propylene carbonate, carbonK-edge spectra reveal a shift in energy, which can be explained with differing ionic conductivities of the electrolyte solutions.


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