Electrodeposition of Pd-Based Binary Catalysts on Carbon Paper Via Surface-Limited Redox-Replacement Reactions for Oxygen Reduction Reaction

2010 ◽  
Vol 12 (6) ◽  
pp. 745-748 ◽  
Author(s):  
Rosa Rego ◽  
Cristina Oliveira ◽  
Amado Velázquez ◽  
Pere-Lluís Cabot

2015 ◽  
Vol 40 (46) ◽  
pp. 16734-16744 ◽  
Author(s):  
Rapelang G. Motsoeneng ◽  
Remegia M. Modibedi ◽  
Mkhulu K. Mathe ◽  
Lindiwe E. Khotseng ◽  
Kenneth I. Ozoemena

2011 ◽  
Vol 26 (4) ◽  
pp. 262-270 ◽  
Author(s):  
Jun-sheng ZHENG ◽  
Xi-zhao WANG ◽  
Rong FU ◽  
Ping LI ◽  
Dai-jun YANG ◽  
...  

2014 ◽  
Vol 128 ◽  
pp. 406-411 ◽  
Author(s):  
Remegia M. Modibedi ◽  
Mkhulu K. Mathe ◽  
Rapelang G. Motsoeneng ◽  
Lindiwe E. Khotseng ◽  
Kenneth I. Ozoemena ◽  
...  

NANO ◽  
2018 ◽  
Vol 13 (01) ◽  
pp. 1850006 ◽  
Author(s):  
Zhongliang Deng ◽  
Qingfeng Yi ◽  
Yuanyuan Zhang ◽  
Huidong Nie ◽  
Guang Li ◽  
...  

In this study, we report the findings that the C–N composites containing Ni and Co (Ni1Co1/C–N, Ni3Co1/C–N, Ni6Co1/C–N, Ni9Co1/C–N, Ni[Formula: see text]Co0/C–N and Ni0Co[Formula: see text]/C–N) can be produced by direct pyrolysis of the NiCo-doped polyaniline (PANI) precursors in N2 atmosphere at 800[Formula: see text]C and show efficient electroactivity for oxygen reduction reaction (ORR) in alkaline media. Distribution and compositions of the catalysts were characterized by SEM, TEM, EDS and XRD techniques. The catalysts were loaded on carbon paper to prepare gas diffusion electrodes, in which electrocatalytic activity for ORR in alkaline media was investigated by voltammetric techniques. The ORR current density on these carbon paper-supported NiCo/C–N catalysts exhibits a linear increase with the negative shift of ORR potential. The ORR onset potential is around [Formula: see text]0.2[Formula: see text]V (versus Ag/AgCl) in alkaline media. Among the prepared catalysts, the catalyst Ni6Co1/C–N presents the largest ORR current density, which is 68.5[Formula: see text]mA[Formula: see text]cm[Formula: see text]@[Formula: see text]0.8[Formula: see text]V (versus Ag/AgCl) in alkaline media. Moreover, Ni6Co1/C–N catalyst also presents good electrocatalytic activity stability for ORR.


Sign in / Sign up

Export Citation Format

Share Document