Probing Exchangeable Protons in a Nafion Film using Thiazine Dyes

2007 ◽  
Keyword(s):  
Thiazine Dyes ◽  
Nafion Film

scholarly journals Correction: Nafion film transport properties in a low-Pt PEM fuel cell: impedance spectroscopy study

RSC Advances ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 6764-6765
Author(s):  
Tatyana Reshetenko ◽  
Andrei Kulikovsky
Keyword(s):  
Fuel Cell ◽  
Impedance Spectroscopy ◽  
Transport Properties ◽  
Pem Fuel Cell ◽  
Spectroscopy Study ◽  
Cell Impedance ◽  
Impedance Spectroscopy Study ◽  
Nafion Film

Correction for ‘Nafion film transport properties in a low-Pt PEM fuel cell: impedance spectroscopy study’ by Tatyana Reshetenko et al., RSC Adv., 2019, 9, 38797–38806, DOI: 10.1039/C9RA07794D.

scholarly journals Transparent Ion-Exchange Membrane Exhibiting Intense Emission under a Specific pH Condition Based on Polypyridyl Ruthenium(II) Complex with Two Imidazophenanthroline Groups

Membranes ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 400
Author(s):  
Hajime Kamebuchi ◽  
Satoshi Tamaki ◽  
Atsushi Okazawa ◽  
Norimichi Kojima
Keyword(s):  
Ion Exchange ◽  
Emission Intensity ◽  
Density Functional ◽  
Emission Spectra ◽  
Density Functional Theory Calculations ◽  
Ion Exchange Membrane ◽  
Quantum Yields ◽  
Relative Emission Intensity ◽  
Nafion Film ◽  
Exchange Membrane

The development and the photophysical behavior of a transparent ion-exchange membrane based on a pH-sensitive polypyridyl ruthenium(II) complex, [(bpy)2RuII(H2bpib)RuII(bpy)2](ClO4)4 (bpy = 2,2′-bipyridine, H2bpib = 1,4-bis([1,10]phenanthroline[5,6-d]-imidazol-2-yl)benzene), are experimentally and theoretically reported. The emission spectra of [(bpy)2RuII(H2bpib)RuII(bpy)2]@Nafion film were observed between pH 2 and pH 11 and showed the highest relative emission intensity at pH 5 (λmaxem = 594.4 nm). The relative emission intensity of the film significantly decreased down to 75% at pH 2 and 11 compared to that of pH 5. The quantum yields (Φ) and lifetimes (τ) showed similar correlations with respect to pH, Φ = 0.13 and τ = 1237 ns at pH 5, and Φ = 0.087 and τ = 1014 ns and Φ = 0.069 and τ = 954 ns at pH 2 and pH 11, respectively. These photophysical data are overall considerably superior to those of the solution, with the radiative- (kr) and non-radiative rate constants (knr) at pH 5 estimated to be kr = 1.06 × 105 s−1 and knr = 7.03 × 105 s−1. Density functional theory calculations suggested the contribution of ligand-to-ligand- and intraligand charge transfer to the imidazolium moiety in Ru-H3bpib species, implying that the positive charge on the H3bpib ligand works as a quencher. The Ru-Hbpib species seems to enhance non-radiative deactivation by reducing the energy of the upper-lying metal-centered excited state. These would be responsible for the pH-dependent “off-on-off” emission behavior.

How does processing in supercritical carbon dioxide influence the Nafion film properties?

2021 ◽  
Author(s):  
Anton S. Simonov ◽  
Elena P. Kharitonova ◽  
Daniil A. Fedosov ◽  
Boris A. Kolozhvari ◽  
Marat O. Gallyamov
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Film Properties ◽  
Nafion Film ◽  
Supercritical Carbon

ChemInform Abstract: Oxygen Reduction at Nafion Film-Coated Platinum Electrodes: Transport and Kinetics.

ChemInform ◽  
1988 ◽  
Vol 19 (51) ◽  
Author(s):  
D. R. LAWSON ◽  
L. D. WHITELEY ◽  
C. R. MARTIN ◽  
M. N. SZENTIRMAY ◽  
J. I. SONG
Keyword(s):  
Oxygen Reduction ◽  
Platinum Electrodes ◽  
Nafion Film

scholarly journals Cyclic Voltammetric Investigations of Thiazine Dyes on Modified Electrodes

2013 ◽  
Vol 2013 ◽  
pp. 1-7 ◽  
Author(s):  
Amitabha Chakraborty ◽  
Shamsuzzaman Ahamed ◽  
Subrata Pal ◽  
Swapan K. Saha
Keyword(s):  
Diffusion Coefficient ◽  
Modified Electrode ◽  
Glassy Carbon ◽  
Electrochemical Behavior ◽  
Modified Electrodes ◽  
Electron Hopping ◽  
Cyclic Voltammetric ◽  
Peak Current ◽  
Quantitative Characteristics ◽  
Thiazine Dyes

Electrochemical behavior of five progressively alkylated thiazine dyes has been investigated at glassy carbon/montmorillonite and glassy carbon/zeolite electrodes. Quantitative characteristics, associated with the positions of peak potentials (Ea and Ec) and current ratios (ia/ic), are measured with scan rates. The peak current observed in the modified electrodes is dependent on both the porosity and nature and number of sites involved in partitioning the complex into film. The values of diffusion coefficient for different dyes have been calculated from electrochemical data. It is suggested that in clay-modified electrode along with physical diffusion the process of electron hopping seems to be most likely.

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