Free-Standing Molybdenum Disulfide Composite Film Electrode for High Performance and Waterproof Flexible Supercapacitor

2019 ◽  
Vol 166 (10) ◽  
pp. A2158-A2164 ◽  
Author(s):  
Yihe Wang ◽  
Ruofei Hu ◽  
Guochen Ji ◽  
Junping Zheng
MRS Advances ◽  
2019 ◽  
Vol 4 (41-42) ◽  
pp. 2299-2305
Author(s):  
Le Yu ◽  
Shixi Zhao ◽  
Qilong Wu ◽  
Xiaoxiao Zheng ◽  
Yifeng Wang ◽  
...  

ABSTRACTThe research of high-performance flexible supercapacitors is urgent due to the rapid development of wearable and portable electronics. The key challenge is the preparation of flexible electrodes with high areal capacitance since electrodes are the most important part of supercapacitors. Compared to those conventional electrodes loading with typical flexible substrates such as textile, PET, paper et al, free-standing electrodes have many advantages such as more efficient capacity contribution, solidly embedded active materials and thinner thickness. Herein, we have successfully fabricated a novel sandwich-like structure free-standing MoO3-rGO (reduced graphene oxide) composite film electrode for flexible supercapacitors using simple vacuum filtration method followed by HI reduction process. The obtained MoO3-rGO composite film electrode shows excellent electrochemical performance, whose areal specific capacitance reaches 8972 mF·cm-2 (1.5 mA·cm-2). Here, MoO3 provides pseudocapacitance and rGO provides double-layer capacitance. After cycling for 2000 cycles, the capacity retention is 86.7%, showing good cycle stability. Besides, the as-prepared composite film has good flexibility and will not break easily during following bending, rolling, folding or twisting steps. This study has been approved to be an important step for the high-performance electrode design for free-standing flexible supercapacitors.


2018 ◽  
Vol 20 (11) ◽  
Author(s):  
Jialu Gao ◽  
Yu Ma ◽  
Jianbo Li ◽  
Jinchen Fan ◽  
Penghui Shi ◽  
...  

2015 ◽  
Vol 3 (33) ◽  
pp. 17165-17171 ◽  
Author(s):  
Huailong Li ◽  
Ying He ◽  
Vladimir Pavlinek ◽  
Qilin Cheng ◽  
Petr Saha ◽  
...  

A facile two-step strategy is adopted to construct a free-standing composite paper of MnO2 nanoflake/polyaniline (PANI) nanorod hybrid nanostructures on reduced graphene oxide (RGO) for flexible supercapacitor electrode application.


2019 ◽  
Vol 4 (31) ◽  
pp. 9165-9173 ◽  
Author(s):  
Ms. Le Yu ◽  
Shi‐Xi Zhao ◽  
Yi‐Feng Wang ◽  
Qi‐long Wu ◽  
Ms. Xiao‐Xiao Zheng ◽  
...  

2014 ◽  
Vol 2 (31) ◽  
pp. 12340-12347 ◽  
Author(s):  
Haosen Fan ◽  
Ning Zhao ◽  
Hao Wang ◽  
Jian Xu ◽  
Feng Pan

A facile method was successfully established to construct 3D conductive network-based free-standing polyaniline/reduced graphene oxide/carbon nanotube ternary hybrid film, in which a 3D conductive network was synergistically assembled by MWNTs and GO.


Nanoscale ◽  
2019 ◽  
Vol 11 (6) ◽  
pp. 2812-2822 ◽  
Author(s):  
Dedong Jia ◽  
Degang Jiang ◽  
Yiwei Zheng ◽  
Hua Tan ◽  
Xueying Cao ◽  
...  

The NiCo-LDH nanosheet arrays are strongly anchored on moderately oxidized RGO through C–O–metal bonds to construct a hierarchical composite film electrode for flexible high-performance supercapacitors.


2018 ◽  
Vol 531 ◽  
pp. 513-522 ◽  
Author(s):  
Cheng Ma ◽  
Songju Ruan ◽  
Jitong Wang ◽  
Donghui Long ◽  
Wenming Qiao ◽  
...  

2015 ◽  
Vol 299 ◽  
pp. 347-355 ◽  
Author(s):  
Shiyong Wang ◽  
Li Ma ◽  
Mengyu Gan ◽  
Shenna Fu ◽  
Wenqin Dai ◽  
...  

Nanomaterials ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 650 ◽  
Author(s):  
Xing Li ◽  
Yongshun Bai ◽  
Mingshan Wang ◽  
Guoliang Wang ◽  
Yan Ma ◽  
...  

Silicon is the one of the most promising anode material alternatives for next-generation lithium-ion batteries. However, the low electronic conductivity, unstable formation of solid electrolyte interphase, and the extremely high volume expansion (up to 300%) which results in pulverization of Si and rapid fading of its capacity have been identified as primary reasons for hindering its application. In this work, we put forward to introduce dual carbonaceous materials synergetic protection to overcome the drawbacks of the silicon anode. The silicon nanoparticle was coated by pyrolysed carbon, and meanwhile anchored on the surface of reduced graphene oxide, to form a self-standing film composite (C@Si/rGO). The C@Si/rGO film electrode displays high flexibility and an ordered porous structure, which could not only buffer the Si nanoparticle expansion during lithiation/delithiation processes, but also provides the channels for fast electron transfer and lithium ion transport. Therefore, the self-standing C@Si/rGO film electrode shows a high reversible capacity of 1002 mAh g−1 over 100 cycles and exhibits much better rate capability, validating it as a promising anode for constructing high performance lithium-ion batteries.


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