scholarly journals Performance of Different Carbon Electrode Materials: Insights into Stability and Degradation under Real Vanadium Redox Flow Battery Operating Conditions

2017 ◽  
Vol 164 (7) ◽  
pp. A1608-A1615 ◽  
Author(s):  
Olga Nibel ◽  
Susan M. Taylor ◽  
Alexandra Pătru ◽  
Emiliana Fabbri ◽  
Lorenz Gubler ◽  
...  
2014 ◽  
Vol 44 (8) ◽  
pp. 1280-1288 ◽  
Author(s):  
QingMing ZHOU ◽  
XiongWei WU ◽  
YuPing WU ◽  
Jun LIU ◽  
YuanFu XIONG ◽  
...  

2015 ◽  
Vol 2 (6) ◽  
pp. 872-876 ◽  
Author(s):  
Yong Il Cho ◽  
Se Jun Park ◽  
Ho Jung Hwang ◽  
Jin Goo Lee ◽  
Yu Kwon Jeon ◽  
...  

2013 ◽  
Vol 136 (2) ◽  
Author(s):  
Victor Yu ◽  
Dongmei Chen

The vanadium redox flow battery (VRFB) is an attractive grid scale energy storage option, but high operating cost prevents widespread commercialization. One way of mitigating cost is to optimize system performance, which requires an accurate model capable of predicting cell voltage under different operating conditions such as current, temperature, flow rate, and state of charge. This paper presents a lumped isothermal VRFB model based on principles of mass transfer and electrochemical kinetics that can predict transient performance with respect to the aforementioned operating conditions. The model captures two important physical phenomena: (1) mass transfer at the electrode surface and (2) vanadium crossover through the membrane. Mass transfer effects increase the overpotential and thus reduce the battery output voltage during discharge. Vanadium crossover causes a concentration imbalance between the two half-cells that negatively affects the voltage response particularly after long term cycling. Further analysis on the system linearity is conducted to assess the feasibility of using a linear control design methodology.


Carbon ◽  
2010 ◽  
Vol 48 (11) ◽  
pp. 3079-3090 ◽  
Author(s):  
Lu Yue ◽  
Weishan Li ◽  
Fengqiang Sun ◽  
Lingzhi Zhao ◽  
Lidan Xing

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