A Model for PEM Fuel Cell Impedance: Oxygen Flow in the Channel Triggers Spatial and Frequency Oscillations of the Local Impedance

2015 ◽  
Vol 162 (9) ◽  
pp. F1068-F1077 ◽  
Author(s):  
Andrei Kulikovsky ◽  
Olga Shamardina
RSC Advances ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 6764-6765
Author(s):  
Tatyana Reshetenko ◽  
Andrei Kulikovsky

Correction for ‘Nafion film transport properties in a low-Pt PEM fuel cell: impedance spectroscopy study’ by Tatyana Reshetenko et al., RSC Adv., 2019, 9, 38797–38806, DOI: 10.1039/C9RA07794D.


2016 ◽  
Vol 163 (5) ◽  
pp. F319-F326 ◽  
Author(s):  
A. A. Kulikovsky

Energies ◽  
2020 ◽  
Vol 13 (9) ◽  
pp. 2372 ◽  
Author(s):  
Adam Polak

This paper presents an alternative approach to the flow control of an oxidizer in a proton exchange membrane (PEM) fuel cell system in which pure oxygen is the gas supplied to the cathode channel of the stack. The proposed oxygen flow control is implemented based on information about the current drawn from the fuel cell stack and the voltage variation in the stack. This information and a fuzzy-logic-based control algorithm are used to increase oxygen utilization in a PEM fuel cell system without a recirculation system in relation to the control, in which the oxygen flow rate is determined only in proportion to the current drawn from the stack. To verify the validity of the adopted assumptions, simulation tests of the proposed fuzzy control algorithm were conducted, for which parameters were adopted arbitrarily and determined with help of genetic algorithms. For simulation research, the proposed empirical mathematical model was used, which describes the mathematical relationship between voltage variation in the stack and the stoichiometry of oxygen flow through the cathode of a fuel cell stack. The simulation results confirm that the proposed control method leads to an increase in the oxygen utilization in the system without oxygen recirculation compared to an open system with cathode stoichiometry set to a constant level.


Author(s):  
Taehee Han ◽  
Tessa A. Haagenson ◽  
Hossein Salehfar ◽  
Samir Dahal ◽  
Mike D. Mann

In this study, an efficient method of approximating individual fuel cell impedances in a stack is proposed and experimentally verified. Two different proton exchange membrane (PEM) fuel cell stacks (600 W with 24 cells and 1.2 kW with 47 cells) were used to develop and verify the method. Both PEM fuel cell stacks were operated using room air and pure hydrogen (99.999%). Impedance and current - voltage (I-V) data were collected for stack and individual cell levels under various operating conditions. The experimental result shows that the individual cell impedance is directly proportional to the corresponding cell voltage. Therefore individual cell impedance can be accurately estimated by performing only stack impedance and individual cell voltage measurements.


2014 ◽  
Vol 39 (5) ◽  
pp. 2224-2235 ◽  
Author(s):  
O. Shamardina ◽  
M.S. Kondratenko ◽  
A.V. Chertovich ◽  
A.A. Kulikovsky

RSC Advances ◽  
2019 ◽  
Vol 9 (66) ◽  
pp. 38797-38806 ◽  
Author(s):  
Tatyana Reshetenko ◽  
Andrei Kulikovsky

A model for PEM fuel cell impedance taking into account oxygen transport through the Nafion film covering Pt/C aggolmerates is developed and used for fitting experimental spectra of a low-Pt cell.


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