Electrodeposition of Bismuth Telluride Thermoelectric Films from Chloride-Free Ethylene Glycol Solutions

2013 ◽  
Vol 160 (4) ◽  
pp. D196-D201 ◽  
Author(s):  
Minxian Wu ◽  
Hai P. Nguyen ◽  
Ruud J. M. Vullers ◽  
Philippe M. Vereecken ◽  
Koen Binnemans ◽  
...  
2012 ◽  
Vol 68 ◽  
pp. 9-17 ◽  
Author(s):  
Hai P. Nguyen ◽  
Minxian Wu ◽  
Jiale Su ◽  
Ruud J.M. Vullers ◽  
Philippe M. Vereecken ◽  
...  

2019 ◽  
Vol 10 (10) ◽  
Author(s):  
Anton Bonartsev ◽  
Vera Voinova ◽  
Elizaveta Akoulina ◽  
Andrey Dudun ◽  
Irina Zharkova ◽  
...  

2020 ◽  
pp. 48-55
Author(s):  
M.E. Sharanda ◽  
◽  
E.A. Bondarenko ◽  

Ethylene glycol and propylene glycol are important representatives of polyols. On an industrial scale, they are obtained from petrochemical raw materials. Within a decade, significant efforts were made for the producing of polyols from biologically renewable raw materials - carbohydrates. The general trend for carbohydrate hydrogenolysis includes application of liquid-phase process with the use of modified metal-oxide catalysts, at 120-120 ° C and pressure of 3MPa or above. So high pressure is used for the reason to increase hydrogen solubility, and also due to the high partial pressure of low boiling solvents. We supposed that usage of high boiling solvents could allow hydrogenolysis to be performed at the lower pressure. Ethylene glycol and propylene glycol are of particular interest as such kind of solvent since they are both the main products of glucose hydrogenolysis. In this work, the process of hydrogenolysis of glucose and fructose over Cu / MgO-ZrO2 catalyst have been studied at temperature range of 160-200 °C and a pressure of 0.1-0.3 MPa in a flow reactor. The solvents were simultaneously the target products of the reaction - ethylene glycol and / or propylene glycol. Gas chromatography and 13C NMR were used for the reaction products identification. It was found that the solubility of glucose in propylene glycol is 21 % by weight, and in ethylene glycol 62% by weight. It was pointed out that the process of hydrogenolysis can take place at a pressure close to atmospheric. Under these conditions, the conversion of hexoses reaches 96-100 %. The reaction products are preferably propylene glycol and ethylene glycol. The total selectivity for C3-2 polyols is 90-94 %, that is higher than in the hydrogenolysis of glucose in aqueous solution.


Author(s):  
Michael A. Henry ◽  
John F. Maddox ◽  
Sushil Bhavnani ◽  
Roy W. Knight ◽  
James Pool

Author(s):  
A. A. Gorbatovskiy

The article presents results of strength tests of bismuth telluride prismatic samples obtained by growing crystals. These crystals have semiconductor properties and are used in the heat machines, the run-ability of which largely depends on the strength of crystals. Data available in the literature are significantly different from each other. It has been shown that, the most consistent strength tests results are obtained in case of bend testing. The measurement results of the elasticity modulus and tensile strength are given. For tests, an INSTRON testing machine with maximum direct stress of the 1000 H was used.


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