Thermal Degradation of Solid Electrolyte Interphase (SEI) Layers by Phosphorus Pentafluoride (PF5) Attack

2017 ◽  
Vol 164 (12) ◽  
pp. A2418-A2425 ◽  
Author(s):  
Jongjung Kim ◽  
Jae Gil Lee ◽  
Hyun-seung Kim ◽  
Tae Jin Lee ◽  
Hosang Park ◽  
...  
Keyword(s):  
Thermal Degradation ◽  
Solid Electrolyte ◽  
Solid Electrolyte Interphase ◽  
Phosphorus Pentafluoride

Communication—A Phosphorus Pentafluoride Scavenger to Suppress Solid Electrolyte Interphase Damage at Moderately Elevated Temperature

2017 ◽  
Vol 164 (14) ◽  
pp. A3699-A3701 ◽  
Author(s):  
Jongjung Kim ◽  
Hyun-seung Kim ◽  
Jae Gil Lee ◽  
Hyejeong Jeong ◽  
Ji Heon Ryu ◽  
...  
Keyword(s):  
Elevated Temperature ◽  
Solid Electrolyte ◽  
Solid Electrolyte Interphase ◽  
Phosphorus Pentafluoride

Unveiling the Formation of Solid Electrolyte Interphase and its Temperature Dependence in “Water-in-Salt” Supercapacitors

2021 ◽  
Vol 13 (3) ◽  
pp. 3979-3990
Author(s):  
Ting Quan ◽  
Eneli Härk ◽  
Yaolin Xu ◽  
Ibbi Ahmet ◽  
Christian Höhn ◽  
...  
Keyword(s):  
Solid Electrolyte ◽  
Temperature Dependence ◽  
Solid Electrolyte Interphase

Reactivity and Evolution of Ionic Phases in the Lithium Solid–Electrolyte Interphase

2021 ◽  
pp. 877-885
Author(s):  
Rui Guo ◽  
Dongniu Wang ◽  
Lucia Zuin ◽  
Betar M. Gallant
Keyword(s):  
Solid Electrolyte ◽  
Solid Electrolyte Interphase

scholarly journals Probing the Na metal solid electrolyte interphase via cryo-transmission electron microscopy

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Bing Han ◽  
Yucheng Zou ◽  
Zhen Zhang ◽  
Xuming Yang ◽  
Xiaobo Shi ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Transmission Electron Microscopy ◽  
Solid Electrolyte ◽  
Solid Electrolyte Interphase ◽  
Metal Electrode ◽  
Liquid Electrolyte ◽  
Battery Materials ◽  
Cryogenic Transmission Electron Microscopy ◽  
Transmission Electron ◽  
Fluoroethylene Carbonate

AbstractCryogenic transmission electron microscopy (cryo-TEM) is a valuable tool recently proposed to investigate battery electrodes. Despite being employed for Li-based battery materials, cryo-TEM measurements for Na-based electrochemical energy storage systems are not commonly reported. In particular, elucidating the chemical and morphological behavior of the Na-metal electrode in contact with a non-aqueous liquid electrolyte solution could provide useful insights that may lead to a better understanding of metal cells during operation. Here, using cryo-TEM, we investigate the effect of fluoroethylene carbonate (FEC) additive on the solid electrolyte interphase (SEI) structure of a Na-metal electrode. Without FEC, the NaPF6-containing carbonate-based electrolyte reacts with the metal electrode to produce an unstable SEI, rich in Na2CO3 and Na3PO4, which constantly consumes the sodium reservoir of the cell during cycling. When FEC is used, the Na-metal electrode forms a multilayer SEI structure comprising an outer NaF-rich amorphous phase and an inner Na3PO4 phase. This layered structure stabilizes the SEI and prevents further reactions between the electrolyte and the Na metal.

scholarly journals A chemically consistent graph architecture for massive reaction networks applied to solid-electrolyte interphase formation

2021 ◽  
Author(s):  
Samuel M. Blau ◽  
Hetal D Patel ◽  
Evan Walter Clark Spotte-Smith ◽  
Xiaowei Xie ◽  
Shyam Dwaraknath ◽  
...  
Keyword(s):  
Energy Storage ◽  
Solid Electrolyte ◽  
Chemical Reaction ◽  
Solid Electrolyte Interphase ◽  
Chemical Reaction Networks ◽  
Reaction Networks ◽  
Mechanistic Understanding

Modeling reactivity with chemical reaction networks could yield fundamental mechanistic understanding that would expedite the development of processes and technologies for energy storage, medicine, catalysis, and more. Thus far, reaction...

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