Anti-Corrosion Properties of a TCP Pretreatment Conversion Coating on Aluminum Alloy 2024-T3 during Moist SO2Atmospheric Testing: Effects of Galvanic Coupling

2017 ◽  
Vol 164 (4) ◽  
pp. C135-C147 ◽  
Author(s):  
Brandon W. Whitman ◽  
Liangliang Li ◽  
Greg M. Swain
Keyword(s):  
Aluminum Alloy ◽  
Conversion Coating ◽  
Galvanic Coupling ◽  
Corrosion Properties ◽  
Testing Effects ◽  
Aluminum Alloy 2024

Galvanic Coupling of Doped Polyaniline and Aluminum Alloy 2024-T3

2000 ◽  
Vol 147 (6) ◽  
pp. 2143 ◽  
Author(s):  
Stuart F. Cogan ◽  
Michael D. Gilbert ◽  
Gerhard L. Holleck ◽  
Julia Ehrlich ◽  
Michael H. Jillson
Keyword(s):  
Aluminum Alloy ◽  
Galvanic Coupling ◽  
Doped Polyaniline ◽  
Aluminum Alloy 2024

Corrosion Protection of Aluminum Alloy 2024-T3 by Vanadate Conversion Coatings

CORROSION ◽  
2004 ◽  
Vol 60 (3) ◽  
pp. 284-296 ◽  
Author(s):  
H. Guan ◽  
R. G. Buchheit
Keyword(s):  
Aluminum Alloy ◽  
Corrosion Protection ◽  
Inductively Coupled Plasma ◽  
Electrochemical Impedance ◽  
Salt Spray ◽  
Conversion Coating ◽  
Self Healing ◽  
Pitting Potential ◽  
X Ray ◽  
Aluminum Alloy 2024

Abstract In this paper, the formation, chemistry, morphology, and corrosion protection of a new type of inorganic conversion coating is described. This coating, referred to as a vanadate conversion coating (VCC), forms on aluminum alloy substrates in a matter of minutes during simple immersion in aqueous vanadate-based solutions at ambient temperatures. VCCs are yellow in color and conformal across the surface of aluminum alloy 2024-T3 (AA2024-T3 [UNS A92024]) substrates. Auger electron sputter depth profiles and x-ray absorption near-edge spectroscopy show that VCCs formed by a 3-min immersion are 300 nm to 500 nm thick and consist of a mixture of vanadium oxides and other components in the coating bath. In anodic polarization experiments conducted in aerated chloride solutions, VCCs increase the pitting potential and decrease the rate of oxygen reduction. When characterized by electrochemical impedance spectroscopy, VCCs demonstrate a low-frequency impedance between 1 MΩ-cm2 and 2 MΩ-cm2 after 24 h exposure to aerated 0.5 M sodium chloride (NaCl) solutions. In salt spray testing conducted according to ASTM B117, VCCs suppress formation of large pits for more than 168 h. VCCs also appear to be self-healing. Analysis of solution in contact with VCCs by inductively coupled plasma emission spectroscopy indicates that vanadate is released into solution upon exposure. Vanadium deposits were identified by x-ray microchemical analysis on a bare alloy substrate held in close proximity to a vanadate conversion-coated surface, and corrosion resistance of this bare surface was observed to increase during exposure. An important component of VCC formation appears to involve inorganic polymerization of V5+, which leads to the buildup of a film that passivates the surface and inhibits corrosion.

scholarly journals Application of Commercial Surface Pretreatments on the Formation of Cerium Conversion Coating (CeCC) over High-Strength Aluminum Alloys 2024-T3 and 7075-T6

Metals ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 930
Author(s):  
Juan Jesús Alba-Galvín ◽  
Leandro González-Rovira ◽  
Francisco Javier Botana ◽  
Maria Lekka ◽  
Francesco Andreatta ◽  
...  
Keyword(s):  
Electrochemical Impedance ◽  
Salt Spray ◽  
Aluminum Matrix ◽  
Optical Emission ◽  
High Strength ◽  
Chemical Conversion ◽  
Conversion Coating ◽  
Neutral Salt ◽  
Corrosion Properties ◽  
Surface Pretreatment

The selection of appropriate surface pretreatments is one of the pending issues for the industrial application of cerium-based chemical conversion coatings (CeCC) as an alternative for toxic chromate conversion coating (CrCC). A two-step surface pretreatment based on commercial products has been successfully used here to obtain CeCC on AA2024-T3 and AA7075-T6. Specimens processed for 1 to 15 min in solutions containing CeCl3 and H2O2 have been studied by scanning electron microscopy coupled with energy-dispersive X-ray analysis (SEM-EDX), glow discharge optical emission spectroscopy (GDOES), potentiodynamic linear polarization (LP), electrochemical impedance spectroscopy (EIS), and neutral salt spray (NSS) tests. SEM-EDX showed that CeCC was firstly observed as deposits, followed by a general coverage of the surface with the formation of cracks where the coating was getting thicker. GDOES confirmed an increase of the CeCC thickness as the deposition proceed, the formation of CeCC over 7075 being faster than over 2024. There was a Ce-rich layer in both alloys and an aluminum oxide/hydroxide layer on 7075 between the upper Ce-rich layer and the aluminum matrix. According to LP and EIS, CeCC in all samples offered cathodic protection and comparable degradation in chloride-containing media. Finally, the NSS test corroborated the anti-corrosion properties of the CeCC obtained after the commercial pretreatments employed.

An Experimental Investigation of the Yield Loci of 1100-0 Aluminum, 70:30 Brass, and an Overaged 2024 Aluminum Alloy After Various Prestrains

1986 ◽  
Vol 108 (4) ◽  
pp. 313-320 ◽  
Author(s):  
D. E. Helling ◽  
A. K. Miller ◽  
M. G. Stout
Keyword(s):  
Aluminum Alloy ◽  
Small Strain ◽  
Yield Locus ◽  
Material Behavior ◽  
Shear Stresses ◽  
2024 Aluminum Alloy ◽  
Yield Loci ◽  
Aluminum Alloy 2024 ◽  
Von Mises ◽  
Normal And Shear Stresses

The multiaxial yield behaviors of 1100-0 aluminum, 70:30 brass, and an overaged 2024 aluminum alloy (2024-T7) have been investigated for a variety of prestress histories involving combinations of normal and shear stresses. Von Mises effective prestrains were in the range of 1.2–32%. Prestress paths were chosen in order to investigate the roles of prestress and prestrain direction on the nature of small-strain offset (ε = 5 × 10−6) yield loci. Particular attention was paid to the directionality, i.e., translation and distortion, of the yield locus. A key result, which was observed in all three materials, was that the final direction of the prestrain path strongly influences the distortions of the yield loci. Differences in the yield locus behavior of the three materials were also observed: brass and the 2024-T7 alloy showed more severe distortions of the yield locus and a longer memory of their entire prestrain history than the 1100-0 aluminum. In addition, more “kinematic” translation of the subsequent yield loci was observed in brass and 2024-T7 than in 1100-0 aluminum. The 2024-T7 differed from the other materials, showing a yield locus which decreased in size subsequent to plastic straining. Finally, the implications of these observations for the constitutive modeling of multiaxial material behavior are discussed.

Sign in / Sign up

Export Citation Format

Share Document