Electrosynthesis and Characterization of Four Electrochromic Polymers Based on Carbazole and Indole-6-Carboxylic Acid and Their Applications in High-Contrast Electrochromic Devices

2014 ◽  
Vol 161 (14) ◽  
pp. D782-D790 ◽  
Author(s):  
Chung-Wen Kuo ◽  
Tar-Hwa Hsieh ◽  
Chi-Kang Hsieh ◽  
Jian-Wei Liao ◽  
Tzi-Yi Wu
2016 ◽  
Vol 26 (29) ◽  
pp. 5239-5239
Author(s):  
Mauro Sassi ◽  
Matteo M. Salamone ◽  
Riccardo Ruffo ◽  
Giorgio E. Patriarca ◽  
Claudio M. Mari ◽  
...  

Inorganics ◽  
2018 ◽  
Vol 6 (3) ◽  
pp. 76 ◽  
Author(s):  
Yasunobu Egawa ◽  
Chihiro Fukumoto ◽  
Koichiro Mikami ◽  
Nobuhiro Takeda ◽  
Masafumi Unno

Carboxylic acid chlorides are useful substrates in organic chemistry. Many germanium analogues of carboxylic acid chloride have been synthesized so far. Nevertheless, all of the reported germathioacid chlorides use bidentate nitrogen ligands and contain germanium-nitrogen bonds. Our group synthesized germathioacid chloride, Ge(S)Cl{C6H3-2,6-Tip2}(Im-i-Pr2Me2), using N-heterocyclic carbene (Im-i-Pr2Me2). As a result of density functional theory (DFT) calculation, it was found that electrons are localized on sulfur, and the germanium-sulfur bond is a single bond with a slight double bond property.


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