Evaluation of Electron Transfer in Electrochemical System Based on Immobilized Gold Nanoparticles and Glucose Oxidase

2017 ◽  
Vol 164 (4) ◽  
pp. G45-G49 ◽  
Author(s):  
Arunas Ramanavicius ◽  
Natalija German ◽  
Almira Ramanaviciene
Keyword(s):  
Gold Nanoparticles ◽  
Electron Transfer ◽  
Glucose Oxidase ◽  
Electrochemical System

Synthesis of gold nanoparticles supported on functionalized nanosilica using deep eutectic solvent for an electrochemical enzymatic glucose biosensor

2017 ◽  
Vol 5 (34) ◽  
pp. 7072-7081 ◽  
Author(s):  
Siva Kumar-Krishnan ◽  
M. Guadalupe-Ferreira García ◽  
E. Prokhorov ◽  
M. Estevez-González ◽  
Ramiro Pérez ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
Electron Transfer ◽  
Glucose Oxidase ◽  
Direct Electron Transfer ◽  
Deep Eutectic Solvent ◽  
Glucose Biosensor ◽  
Enzymatic Biosensor

Synthesis of AuNPs supported on nanosilica, mediated by deep eutectic solvent (DES), for efficient immobilization of glucose oxidase (GOx) and enhanced direct electron transfer in an enzymatic biosensor.

Effect of Gold Nanoparticles on the Structure and Electron-Transfer Characteristics of Glucose Oxidase Redox Polyelectrolyte-Surfactant Complexes

2014 ◽  
Vol 20 (41) ◽  
pp. 13366-13374 ◽  
Author(s):  
M. Lorena Cortez ◽  
Waldemar Marmisollé ◽  
Diego Pallarola ◽  
Lía I. Pietrasanta ◽  
Daniel H. Murgida ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
Electron Transfer ◽  
Glucose Oxidase ◽  
Transfer Characteristics

scholarly journals Electrochemical Response of Glucose Oxidase Adsorbed on Laser-Induced Graphene

Nanomaterials ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1893
Author(s):  
Sónia O. Pereira ◽  
Nuno F. Santos ◽  
Alexandre F. Carvalho ◽  
António J. S. Fernandes ◽  
Florinda M. Costa
Keyword(s):  
Electron Transfer ◽  
Glucose Oxidase ◽  
Ph Dependence ◽  
High Surface ◽  
High Surface Area ◽  
Cost Effective ◽  
Great Promise ◽  
Glucose Detection ◽  
Half Wave ◽  
Electrochemical Transducers

Carbon-based electrodes have demonstrated great promise as electrochemical transducers in the development of biosensors. More recently, laser-induced graphene (LIG), a graphene derivative, appears as a great candidate due to its superior electron transfer characteristics, high surface area and simplicity in its synthesis. The continuous interest in the development of cost-effective, more stable and reliable biosensors for glucose detection make them the most studied and explored within the academic and industry community. In this work, the electrochemistry of glucose oxidase (GOx) adsorbed on LIG electrodes is studied in detail. In addition to the well-known electroactivity of free flavin adenine dinucleotide (FAD), the cofactor of GOx, at the expected half-wave potential of −0.490 V vs. Ag/AgCl (1 M KCl), a new well-defined redox pair at 0.155 V is observed and shown to be related to LIG/GOx interaction. A systematic study was undertaken in order to understand the origin of this activity, including scan rate and pH dependence, along with glucose detection tests. Two protons and two electrons are involved in this reaction, which is shown to be sensitive to the concentration of glucose, restraining its origin to the electron transfer from FAD in the active site of GOx to the electrode via direct or mediated by quinone derivatives acting as mediators.

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