Inhibiting Localized Corrosion of Aluminum and Aluminum Alloy by Rare Earth Metal Compounds: Behaviors and Characteristics Observed Using an Electrochemically Integrated Multi-Electrode Array

2013 ◽  
Vol 160 (4) ◽  
pp. C147-C158 ◽  
Author(s):  
Yongjun Tan ◽  
Tie Liu
Author(s):  
M. N. Bochkarev ◽  
A. A. Trifonov ◽  
G. A. Razuvaev ◽  
M. A. Ilatovskaya ◽  
V. B. Shur

CORROSION ◽  
2002 ◽  
Vol 58 (11) ◽  
pp. 953-960 ◽  
Author(s):  
M. Forsyth ◽  
K. Wilson ◽  
T. Behrsing ◽  
C. Forsyth ◽  
G. B. Deacon ◽  
...  

2019 ◽  
Vol 74 (6) ◽  
pp. 497-506 ◽  
Author(s):  
Felix C. Goerigk ◽  
Svetlana Schander ◽  
Makram Ben Hamida ◽  
Dong-Hee Kang ◽  
Florian Ledderboge ◽  
...  

AbstractThe rare earth metal(III) chloride oxidoarsenates(III) with the composition RE5Cl3[AsO3]4 (RE = La–Nd, Sm) could be synthesized via solid-state methods through the reaction of arsenic sesquioxide (As2O3) with the corresponding rare earth metal compounds (La2O3, CeO2 + metallic Ce, Pr6O11, Nd2O3 or metallic Sm) using several chloride-containing fluxing agents in evacuated silica glass ampoules. The compounds build up non-isotypic crystal structures in the monoclinic space groups C2/c for RE = La–Pr, and P2/c for RE = Nd and Sm. All rare earth metal(III) cations exhibit coordination numbers of eight. While (RE1)3+ and (RE2)3+ are only surrounded by oxygen atoms in the form of distorted square antiprisms or prisms, (RE3)3+ is coordinated square antiprismatically by four oxygen atoms and four chloride anions. Although the coordination polyhedra in both structures differ only marginally, their connection patterns show more pronounced differences. This regards especially the (RE)3+ cations and results from different site symmetries of the (Cl1)− anions. All As3+ lone-pair cations are coordinated by three oxygen atoms to form ψ1-tetrahedral [AsO3]3− complex anions with their non-binding (lone) electron pairs pointing into empty channels along [010].


2011 ◽  
Vol 123 (47) ◽  
pp. 11423-11425 ◽  
Author(s):  
Yingdong Lv ◽  
Xin Xu ◽  
Yaofeng Chen ◽  
Xuebing Leng ◽  
Maxim V. Borzov

2012 ◽  
Vol 549 ◽  
pp. 770-773 ◽  
Author(s):  
Hong Bo Li ◽  
Xing Jun Su ◽  
Chun Jie Li ◽  
Tian Sheng Li ◽  
Hui Xu

Based on the experiment,the forming properties of Aluminum alloy in liquid forging was studied by adding rare-earth metal Y (Yttrium) modificatior and ternary modificatior(25% NaF +62% NaCl +13% KCl).The structure and mechanical properties of the prepared samples under two modifications were compared.The results showed that the rare-earth metal Y can modificatior liquid aluminum alloy forging a comprehensive mechanical properties of a substantial increase, the use of rare-earth metal Y (Yttrium)modificatior was better than ternary modificatior.


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