Surface Area Increase of Silicon Alloys in Li-Ion Full Cells Measured by Isothermal Heat Flow Calorimetry

2017 ◽  
Vol 164 (9) ◽  
pp. A2277-A2282 ◽  
Author(s):  
L. J. Krause ◽  
T. Brandt ◽  
V. L. Chevrier ◽  
L. D. Jensen
Molecules ◽  
2020 ◽  
Vol 25 (19) ◽  
pp. 4561
Author(s):  
Sang Youp Hwang ◽  
Gi Bbum Lee ◽  
Ji Hyun Kim ◽  
Bum Ui Hong ◽  
Jung Eun Park

Spent activated carbon (SAC) usually exhibits a low specific surface area due to its high ash contents. In this study, pre-treatments, such as heat and acid treatments, were optimized to improve this feature. The heat pre-treatment did not reduce the ash content, nor did it increase the surface area. Because metallic ions adsorbed in SACs turn into ash upon the heat treatment. In the acid pre-treatment, the volatiles and fixed carbon were increased with decreasing ash contents. In this study, it was found that the surface area increase was correlated with the ratio between fixed carbon and ash. Among the pre-treatment methods, the combined heat and acid pre-treatment method highly increased the ratio, and therefore led to the surface area increase. Additionally, the acid pre-treatment was carried out using different types of acid (organic and inorganic acids) solutions to further improve the surface areas. The organic acid treatment caused a significant structural collapse compared to the inorganic acid treatment, decreasing the surface area. In particular, H3PO4 effectively removed ashes adsorbed on the activated carbon surface and regenerated the exhausted activated carbon. Both the heat and acid pre-treatments before chemical activation resulted in the positive effects such as strong desorption of pollutants and ashes within the internal structure of the activated carbon. Therefore, the regeneration introduced in this study is methodically the best method to regenerate SAC and maintain a stable structure.


2020 ◽  
Vol 10 (2) ◽  
pp. 685 ◽  
Author(s):  
Alexander E. Ashikhmin ◽  
Nikita A. Khomutov ◽  
Maxim V. Piskunov ◽  
Vyacheslav A. Yanovsky

Using high-speed video recording, we establish the following regimes of hydrodynamic interaction of a biodiesel micro-emulsion fuel droplet with a heated wall: deposition (including drop spreading and receding), drop hydrodynamic breakup, and rebound. Collision regime maps are plotted using a set of dimensionless criteria: Weber number We = 470–1260, Ohnesorge number Oh = 0.146–0.192, and Reynolds number Re = 25–198. The scenarios of droplet hydrodynamic disintegration are studied for transient and film boiling. We also estimate the disintegration characteristics of a biodiesel micro-emulsion droplet (mean diameter of child droplets, their number, and evaporation surface area increase due to breakup). The study establishes the effect of water proportion on the micro-emulsion composition (8–16 vol.%), heating temperature (300–500 °C), droplet size (1.8–2.8 mm), droplet velocity (3–4 m/s), rheological properties of the examined compositions, and emulsifier concentration (10.45 vol.% and 20 vol.%) on the recorded characteristics. The results show that the initial liquid surface area can be increased 2–19 times. The paper analyzes ways to control the process. The hydrodynamic disintegration characteristics of a biodiesel micro-emulsion fuel droplet are compared using 2D and 3D recording.


1973 ◽  
Vol 46 (1) ◽  
pp. 192-203 ◽  
Author(s):  
R. A. Klyne ◽  
B. D. Simpson ◽  
M. L. Studebaker

Abstract 1. The various tint tests correlate with each other—it does not make much difference which of the three procedures is used. The discrimination between similar blacks is comparable. Specific surface areas obtained by the three methods are comparable and differences appear to be due to experimental errors. (Compare Figures 5–7). 2. Surface areas larger than some 90 to 100 m2/g cannot be reliably determined from tint strength measurements alone. 3. Structure exerts a pronounced effect on tint strength of furnace blacks, especially above 90 to 100 m2/g. Porosity and/or composition are apparently also variables which affect tinting strength. 4. Densichron reflectance on the dry carbon black can be used to estimate specific surface areas up to about 140 m2/g; but, since theabsoluteerrorincreases as the specific surface area increases, this method loses some of its reliability at values above about 110 m2/g. The relative error in reflectance determinations does not vary greatly over the furnace-black range. Densichron reflectance is influenced by composition, evidently due to composition-related differences in optical properties of the carbons. 5. In CTAB adsorption measurements, titration errors and handling errors tend to be rather constant for blacks of different surface area. Hence, CTAB permits better discrimination among blacks of small particle size. 6. The errors in Densichron reflectance surface area increase with specific surface area. Hence, the deviations between CTAB and reflectance surface area which are due to experimental error increase with the surface area of the sample.


Author(s):  
Igor Kyrychenko ◽  
Oleksandr Rieznikov ◽  
Yuri Rukavishnikov ◽  
Anton Knyshenko

Currently, there are about 150 manufacturers of mobile elevating work platforms (MEWP), which are constantly designing and implementing new machines with advanced capabilities. Along with the improvement of hoisting equipment, the support devices of the MEWP are also improved. Therefore, there is a need to investigate the coefficient of increase of the support surface area after the deployment of a mobile hoist for different types of support devices. Goal. The aim of this work is to study how the coefficient of increase of the support surface area after the deployment of the support device depends on the length of the support projecting for different designs of support devices used in MEWP. Methodology. Analytical methods of studying the designs with variable geometrical parameters were used in the work. To obtain the dependences of the coefficient of increase of the support surface area after the deployment of the support device on the length of the support projecting, the methods of mathematical modeling employing computer technology were used. Results. The analysis of the dependences of the coefficient of the support surface area increase after the deployment of the support device on the length of the support projecting showed that the use of the considered support devices enlarges the coefficient of increase of the support surface area from 1.9 with angular supports to 3.4 for Spider type support devices. Originality. It is proposed to consider the coefficient of increase of the support surface area, which enables to take into account the lengths and angles of the supports when determining the support surface area. Practical value. With the results of the study it is possible to choose the type of support device and its geometric parameters at the design stage which will


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